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US4140645A Expired / Lapsed US ⏱️ 0.0 years remaining

Glasses and glass-ceramics suitable for induction heating

Assignee: Corning Glass Works
•
Filing: 1978-06-12
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Granted: 1979-02-20
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Expires: 1998-06-12
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Abstract

Abstract The instant invention relates to the production of glass and glass-ceramic compositions containing a ferrimagnetic crystal phase throughout which respond thermally to fields generated by induction coils. Magnetite (Fe 3 O 4 ) is the preferred ferrimagnetic crystal phase because of its high permeability and low resistivity (˜10 -4 ohm-cm) at room temperature as well as the relative low cost of iron when compared with other ferrimagnetic species. Two general composition areas are of interest: Na 2 O and/or K 2 O-FeO-B 2 O 3 -SiO 2 and Li 2 O-Al 2 O 3 -B 2 O 3 -SiO 2 . Where the coefficient of thermal expansion is sufficiently low to impart good thermal shock resistance, the compositions can be considered for top-of-stove cooking vessels.

Inventors

  • 👤 George H. Beall
  • 👤 Richard F. Reade

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 07:07
CPC Classifications
H; H01; H01F; H01F1/00; H01F1/01; H01F1/03; H01F1/12; H01F1/34; H01F1/36; H01F1/37; C; C03; C03C; C03C10/00; C03C10/0081

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 128 words
A glass article which will demonstrate efficient and uniform heating when placed in an oscillatory magnetic field and containing magnetite crystals dispersed throughout the body thereof, said glass article having an overall composition, expressed in weight percent on the oxide basis as calculated from the batch, selected from the groups (a) 2-10% Na 2 O and/or K 2 O, 5-20% B 2 O 3 , 15-40% FeO, O-32% Al 2 O 3 , and 35-65% SiO 2 ; and (b) 1.5-6% Li 2 O, 10-40% FeO, 10-20% Al 2 O 3 , 45-66% SiO 2 , 0-5% TiO 2 and/or ZrO 2 , and 0-5% B 2 O 3 , at least 1% B 2 O 3 being required when the proportion of FeO is less than 15%.
Claim 2
Dependent Claim 128 words
A glass article which will demonstrate efficient and uniform heating when placed in an oscillatory magnetic field and containing magnetite crystals dispersed throughout the body thereof, said glass article having an overall composition, expressed in weight percent on the oxide basis as calculated from the batch, selected from the groups (a) 2-10% Na 2 O and/or K 2 O, 5-20% B 2 O 3 , 15-40% FeO, O-32% Al 2 O 3 , and 35-65% SiO 2 ; and (b) 1.5-6% Li 2 O, 10-40% FeO, 10-20% Al 2 O 3 , 45-66% SiO 2 , 0-5% TiO 2 and/or ZrO 2 , and 0-5% B 2 O 3 , at least 1% B 2 O 3 being required when the proportion of FeO is less than 15%.
Claim 3
Dependent Claim 130 words
A glass-ceramic article which will demonstrate efficient and uniform heating when placed in an oscillatory magnetic field, said article consisting essentially of crystals dispersed within a glassy matrix, said glass-ceramic article having an overall composition, expressed in weight percent on the oxide basis as calculated from the batch, selected from the groups (a) 2-10% Na 2 O and/or K 2 O, 5-20% B 2 O 3 , 15-40% FeO, 15-32% Al 2 O 3 , and 35-50% SiO 2 ; and (b) 1.5-6% Li 2 O, 10-40% FeO, 10-20% Al 2 O 3 , 45-66% SiO 2 , 0-5% TiO 2 and/or ZrO 2 , and 0-5% B 2 O 3 , at least 1% B 2 O 3 being required when the proportion of FeO is less than 15%.
Claim 4
Dependent Claim 130 words
A glass-ceramic article which will demonstrate efficient and uniform heating when placed in an oscillatory magnetic field, said article consisting essentially of crystals dispersed within a glassy matrix, said glass-ceramic article having an overall composition, expressed in weight percent on the oxide basis as calculated from the batch, selected from the groups (a) 2-10% Na 2 O and/or K 2 O, 5-20% B 2 O 3 , 15-40% FeO, 15-32% Al 2 O 3 , and 35-50% SiO 2 ; and (b) 1.5-6% Li 2 O, 10-40% FeO, 10-20% Al 2 O 3 , 45-66% SiO 2 , 0-5% TiO 2 and/or ZrO 2 , and 0-5% B 2 O 3 , at least 1% B 2 O 3 being required when the proportion of FeO is less than 15%.
Claim 5
Dependent Claim 44 words
A glass-ceramic article according to claim 2 wherein the crystals therein consist essentially of magnetite along with beta-quartz solid solution and/or beta-spodumene solid solution, and said article has a coefficient of thermal expansion (0-300° C.) of less than about 40 ×10 -7 /° C.

References Cited (Backward Citations)

US3193503A Cited
US3694360A Cited
US3741740A Cited
US4042519A Cited
US3926602A Cited
US4043821A Cited
US4083727A Cited
US4083709A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-02-19 1982-08-21 1983-02-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-02-19 1986-08-21 1987-02-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-02-19 1990-08-21 1991-02-20 $7700.00 Window Closed / Lapsed

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