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US4139567A
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Method for preparing copolyether glycols
Assignee: EIDP Inc
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Filing: 1978-01-09
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Granted: 1979-02-13
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Expires: 1998-01-09
Abstract
Abstract Copolyether glycols are prepared by copolymerizing alkylene oxides or cyclic acetals and tetrahydrofuran, using (1) a polymeric catalyst which contains sulfonic acid groups; and (2) a chain terminator which is water or an alkanediol.
Inventors
- 👤 Gerfried Pruckmayr
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 18:37
CPC Classifications
B; B01; B01J; B01J31/00; B01J31/02; B01J31/06; B01J31/08; B01J31/10; C; C07; C07C; C07C41/00; C07C41/01; C07C41/02; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/48; C08G18/4854; C08G65/00; C08G65/02; C08G65/04; C08G65/06; C08G65/16; C08G65/20; C08G65/26; C08G65/2642; C08G65/2669; C08G65/2678; C08G65/2684
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
161 words
In a process for preparing a copolyether glycol by copolymerizing an alkylene oxide or a cyclic acetal and tetrahydrofuran using water or an alkanediol as a chain terminator, the improvement comprising using as a catalyst a polymer of monoethylenically unsaturated monomers, the polymer containing groups of the formula ##STR7## where represents the polymer chain or a segment thereof; D is hydrogen, an aliphatic or aromatic hydrocarbon radical of 1 to 10 carbon atoms, a halogen or a segment of the polymer chain; X and Y are hydrogen, an aliphatic or aromatic hydrocarbon radical of 1 to 10 carbon atoms, or fluorine, but at least one of X and Y must be fluorine; R is a linear or branched linking group having up to 40 carbon atoms in the principal chain; and Z is hydrogen, an aliphatic or aromatic hydrocarbon radical of 1 to 10 carbon atoms, or halogen; the polymer being effectively free of functional groups which interfere with the reaction.
Claim 2
Dependent Claim
161 words
In a process for preparing a copolyether glycol by copolymerizing an alkylene oxide or a cyclic acetal and tetrahydrofuran using water or an alkanediol as a chain terminator, the improvement comprising using as a catalyst a polymer of monoethylenically unsaturated monomers, the polymer containing groups of the formula ##STR7## where represents the polymer chain or a segment thereof; D is hydrogen, an aliphatic or aromatic hydrocarbon radical of 1 to 10 carbon atoms, a halogen or a segment of the polymer chain; X and Y are hydrogen, an aliphatic or aromatic hydrocarbon radical of 1 to 10 carbon atoms, or fluorine, but at least one of X and Y must be fluorine; R is a linear or branched linking group having up to 40 carbon atoms in the principal chain; and Z is hydrogen, an aliphatic or aromatic hydrocarbon radical of 1 to 10 carbon atoms, or halogen; the polymer being effectively free of functional groups which interfere with the reaction.
Claim 3
Dependent Claim
14 words
The process of claim 1 wherein the catalyst is a polymer of fluorocarbon monomers.
Claim 4
Dependent Claim
19 words
The process of claim 2 wherein the catalyst is a copolymer of tetrafluoroethylene or chloritrifluoroethylene and R is ##STR8##
Claim 5
Dependent Claim
39 words
The process of claim 3 wherein the catalyst is a hydrolyzed copolymer of tetrafluoroethylene or chlorotrifluoroethylene and a monomer represented by the structure ##STR9## the tetrafluoroethylene or chlorotrifluoroethylene and monomer units being present in weight ratios of 50-75/25-50, respectively.
Claim 6
Dependent Claim
12 words
The process of claim 1 wherein the alkylene oxide is ethylene oxide.
Claim 7
Dependent Claim
12 words
The process of claim 1 wherein the alkylene oxide is propylene oxide.
Claim 8
Dependent Claim
11 words
The process of claim 1 wherein the chain terminator is water.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-02-12 | 1982-08-14 | 1983-02-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-02-12 | 1986-08-14 | 1987-02-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-02-12 | 1990-08-14 | 1991-02-13 | $7700.00 | Window Closed / Lapsed |