US4139485A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Detergent composition
Assignee: Kao Corp
•
Filing: 1977-02-22
•
Granted: 1979-02-13
•
Expires: 1997-02-22
Abstract
Abstract A detergent composition which has a low irritation effect to human skin containing as an active surfactant component one or a mixture of compounds having the formulas <IMAGE> (1) <IMAGE> (2) wherein R is saturated or unsaturated hydrocarbon having 10 to 16 carbon atoms, X1 and X3 are hydrogen, alkali metal, ammonium, alkylammonium or substituted alkylammonium, and X2 is alkali metal, ammonium, alkylammonium or substituted alkylammonium, with the provisos that both X1 and X2 are not alkali metal and that when R has an average carbon atom number of 10, X1 is hydrogen, and wherein the weight ratio of the formula (1) compound(s) : formula (2) compound(s) is from 100:0 to 80:20.
Inventors
- 👤 Genji Imokawa
- 👤 Hisao Tsutsumi
- 👤 Tomihiro Kurosaki
- 👤 Makoto Hayashi
- 👤 Junko Kakuse
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 22:47
CPC Classifications
A; A61; A61Q; A61Q19/00; A61Q19/10; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/55; A61Q5/00; A61Q5/02; C; C11; C11D; C11D1/00; C11D1/02; C11D1/34; C11D1/345
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
164 words
A detergent composition which has a low irritation effect on human skin, in which the organic surfactant component consists essentially of (A) from 100 to 80 weight percent of monoalkyl or monoalkenyl phosphate salt having the formula ##STR13## and (B) the balance of from zero to 20 weight percent is dialkyl or dialkenyl phosphate salt having the formula ##STR14## wherein R is alkyl or alkenyl having an average of from 10 to 16 carbon atoms, X 3 is hydrogen, alkali metal selected from the group consisting of sodium, potassium and lithium, ammonium, alkyl (C 1 to C 3 ) ammonium or hydroxyalkyl (C 1 to C 3 ) ammonium, and X 2 is said alkali metal, ammonium, alkyl (C 1 to C 3 ) ammonium or hydroxyalkyl (C 1 to C 3 ) ammonium, with the provisos: that said salts have a Krafft point of less than 55° C.; and that aqueous solutions of said salts have a pH of from 5 to 9.
Claim 2
Dependent Claim
164 words
A detergent composition which has a low irritation effect on human skin, in which the organic surfactant component consists essentially of (A) from 100 to 80 weight percent of monoalkyl or monoalkenyl phosphate salt having the formula ##STR13## and (B) the balance of from zero to 20 weight percent is dialkyl or dialkenyl phosphate salt having the formula ##STR14## wherein R is alkyl or alkenyl having an average of from 10 to 16 carbon atoms, X 3 is hydrogen, alkali metal selected from the group consisting of sodium, potassium and lithium, ammonium, alkyl (C 1 to C 3 ) ammonium or hydroxyalkyl (C 1 to C 3 ) ammonium, and X 2 is said alkali metal, ammonium, alkyl (C 1 to C 3 ) ammonium or hydroxyalkyl (C 1 to C 3 ) ammonium, with the provisos: that said salts have a Krafft point of less than 55° C.; and that aqueous solutions of said salts have a pH of from 5 to 9.
Claim 3
Dependent Claim
19 words
A detergent composition as claimed in claim 1 in which the weight ratio of A:B is 100:0 to 90:10.
Claim 4
Dependent Claim
18 words
A detergent composition as claimed in claim 1 in which the weight ratio of A:B is substantially 100:0.
Claim 5
Dependent Claim
23 words
A detergent composition as claimed in claim 1 in which R is alkyl having an average of from 10 to 14 carbon atoms.
Claim 6
Dependent Claim
20 words
A detergent composition as claimed in claim 1 in which R is alkenyl having an average of 16 carbon atoms.
Claim 7
Dependent Claim
16 words
A detergent composition according to claim 1 in which said alkali metal is sodium or potassium.
Claim 8
Dependent Claim
52 words
A detergent composition according to claim 1 in which said alkyl (C 1 to C 3 ) ammonium is selected from the group consisting of trimethylammonium, triethylammonium, dibutylammonium, butyldimethylammonium and isopropyldimethylammonium and said hydroxyalkyl (C 1 to C 3 ) ammonium is selected from the dimethylmonoethanolammonium, methyldiethanolammonium, monoethanolammonium, diethanolammonium, triethanolammonium and isopropylethanolammonium.
Claim 9
Dependent Claim
23 words
A detergent composition according to claim 1 in which said hydroxyalkyl (C 1 to C 3 ) ammonium is monoethanolammonium, diethanolammonium or triethanolammonium.
Claim 10
Dependent Claim
52 words
A detergent composition consisting essentially of 5.0 to 95.0% of said phosphate salt organic surfactant component as claimed in claim 1, 5 to 50% of water-soluble detergent builder salt, and from 1 to 5% of a water-soluble polymer selected from the group consisting of polyethylene glycol, polyvinyl alcohol, carboxymethyl cellulose and polyacrylate.
Claim 11
Dependent Claim
86 words
A dish washing composition consisting essentially of 1.0 to 40.0% of said phosphate salt organic surfactant component as claimed in claim 1, 0.5 to 20% of a solubilizer selected from the group consisting of sodium para-toluene sulfonate, sodium metaxylene sulfonate, urea, ethanol, isopropyl alcohol, propylene glycol, ethylene glycol, and glycerin, 1 to 20% of a booster selected from the group consisting of water-soluble, synthetic, organic nonionic surfactants, water-soluble, synthetic, organic anionic surfactants and water-soluble, synthetic, organic amphilic surfactants, and 0.1 to 5% of a superfatting agent.
Claim 12
Dependent Claim
22 words
A detergent composition as claimed in claim 1 in which R has an average of 12 carbon atoms derived from coconut oil.
Claim 13
Dependent Claim
17 words
A detergent composition as claimed in claim 11 in which X 2 is triethanolammonium, sodium or potassium.
Claim 14
Independent Claim
176 words
A method of cleaning which comprises applying to a substrate to be cleaned, water and a material consisting essentially of (A) from 100 to 80 weight percent of monoalkyl or monoalkenyl phosphate salt having the formula ##STR15## and (B) the balance of from zero to 20 weight percent is dialkyl or dialkenyl phosphate salt having the formula ##STR16## wherein R is alkyl or alkenyl having an average of from 10 to 16 carbon atoms, X 3 is hydrogen, alkali metal selected from the group consisting of sodium, potassium and lithium, ammonium, alkyl (C 1 to C 3 ) ammonium or hydroxyalkyl (C 1 to C 3 ) ammonium, and X 2 is said alkali metal, ammonium, alkyl (C 1 to C 3 ) ammonium or hydroxyalkyl (C 1 to C 3 ) ammonium, with the provisos: that said salts have a Krafft point of less than 55° C.; and that aqueous solutions of said salts have a pH of from 5 to 9, said material being effective as a water-soluble organic surfactant for cleaning said substrate.
Claim 15
Independent Claim
176 words
A method of cleaning which comprises applying to a substrate to be cleaned, water and a material consisting essentially of (A) from 100 to 80 weight percent of monoalkyl or monoalkenyl phosphate salt having the formula ##STR15## and (B) the balance of from zero to 20 weight percent is dialkyl or dialkenyl phosphate salt having the formula ##STR16## wherein R is alkyl or alkenyl having an average of from 10 to 16 carbon atoms, X 3 is hydrogen, alkali metal selected from the group consisting of sodium, potassium and lithium, ammonium, alkyl (C 1 to C 3 ) ammonium or hydroxyalkyl (C 1 to C 3 ) ammonium, and X 2 is said alkali metal, ammonium, alkyl (C 1 to C 3 ) ammonium or hydroxyalkyl (C 1 to C 3 ) ammonium, with the provisos: that said salts have a Krafft point of less than 55° C.; and that aqueous solutions of said salts have a pH of from 5 to 9, said material being effective as a water-soluble organic surfactant for cleaning said substrate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-02-12 | 1982-08-14 | 1983-02-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-02-12 | 1986-08-14 | 1987-02-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-02-12 | 1990-08-14 | 1991-02-13 | $7700.00 | Window Closed / Lapsed |