Hydrocracking process with aqueous ammonia rejuvenated zeolite catalyst comprising non-zeolitic noble metal

Claim 2

A hydrocarbon conversion process which comprises subjecting a hydrocarbon feedstock plus added hydrogen to contact at elevated conversion temperatures with a catalyst comprising about 0.1-3 wt.% of a non-zeolitic Group VIII noble metal supported on a siliceous zeolite carrier having an ion exchange capacity of at least about 0.1 meq/g, and wherein at least 50% of the original zeolitic metal content of said zeolite carrier has been replaced by hydrogen ions and/or polyvalent metal ions, said catalyst having been previously subjected to thermal and/or hydrothermal conditions resulting in a maldistribution of said Group VIII noble metal on said carrier with resultant reduction in hydrogenation activity, and which has thereafter been rejuvenated to substantially its original fresh activity by a process in which aqueous ammonia is used as the sole rejuvenating reagent, said rejuvenation process consisting essentially of: A. contacting said catalyst in an oxidized or sulfided state with a drainable excess of a reagent consisting essentially of a 0.1-30 weight-percent aqueous ammonium hydroxide solution, and correlating the contacting time with the temperature and reagent strength so as to effect a substantial improvement in hydrogenation activity of said catalyst while retaining therein at least about 90 percent of said Group VIII noble metal; B. draining said excess reagent from the catalyst; and C. drying and calcining the separated catalyst at temperatures in the range of about 500°-950° F. while maintaining water vapor partial pressures below about 10 psi.

Claim 3

A process as defined in claim 1 wherein said siliceous zeolite carrier also contains at least about 0.5 weight-percent of residual zeolite sodium ions, at least a portion of said residual zeolitic sodium ions being extracted from the catalyst in step A.

Claim 4

A process as defined in claim 1 wherein said Group VIII noble metal is palladium and/or platinum.

Claim 5

A process as defined in claim 2 wherein said siliceous zeolite carrier is a crystalline molecular sieve.

Claim 6

A process as defined in claim 4 wherein said molecular sieve is Y zeolite and said Group VIII noble metal is palladium.

Claim 7

A process as defined in claim 5 wherein said hydrocarbon conversion process is catalytic hydrocracking.

Claim 8

A process for the hydrocracking of a hydrocarbon feedstock to produce lower boiling hydrocarbons, which comprises subjecting said feedstock in admixture with added hydrogen to hydrocracking conditions of pressure and temperature in contact with a catalyst comprising about 0.1-3 wt.% of a nonzeolitic Group VIII noble metal supported on a Y zeolite base containing at least about 0.5 weight-percent of residual zeolitic sodium ions, but in which at least 50% of the original zeolitic sodium content has been replaced by hydrogen ions and/or polyvalent metal ions, said catalyst having previously been utilized in a hydrocracking process to substantial deactivation and subsequently regenerated by oxidative combustion, and during said previous hydrocracking and/or regeneration having been subjected to thermal and/or hydrothermal conditions resulting in a reduction in hydrogenation activity and/or cracking activity, said catalyst having thereafter been rejuvenated to an activity level higher than that resulting from said oxidative combustion, by a rejuvenation process in which aqueous ammonia is used as the sole rejuvenating reagent, said rejuvenation process consisting essentially of: A. contacting said regenerated catalyst in its oxidized state with a drainable excess of a reagent consisting essentially of a 0.1-30 weight-percent aqueous ammonium hydroxide solution, and correlating the contacting time with the temperature and reagent strength so as to effect a substantial improvement in hydrogenation activity of said catalyst while retaining therein at least about 90 percent of said Group VIII noble metal; B. draining said excess reagent from the catalyst; and C. drying and calcining the separated catalyst at temperatures in the range of about 500-950° F. while maintaining water vapor partial pressures below about 10 psi.

Claim 9

A process for the hydrocracking of a hydrocarbon feedstock to produce lower boiling hydrocarbons, which comprises subjecting said feedstock in admixture with added hydrogen to hydrocracking conditions of pressure and temperature in contact with a catalyst comprising about 0.1-3 wt.% of a nonzeolitic Group VIII noble metal supported on a Y zeolite base containing at least about 0.5 weight-percent of residual zeolitic sodium ions, but in which at least 50% of the original zeolitic sodium content has been replaced by hydrogen ions and/or polyvalent metal ions, said catalyst having previously been utilized in a hydrocracking process to substantial deactivation and subsequently regenerated by oxidative combustion, and during said previous hydrocracking and/or regeneration having been subjected to thermal and/or hydrothermal conditions resulting in a reduction in hydrogenation activity and/or cracking activity, said catalyst having thereafter been rejuvenated to an activity level higher than that resulting from said oxidative combustion, by a rejuvenation process in which aqueous ammonia is used as the sole rejuvenating reagent, said rejuvenation process consisting essentially of: A. contacting said regenerated catalyst in its oxidized state with a drainable excess of a reagent consisting essentially of a 0.1-30 weight-percent aqueous ammonium hydroxide solution, and correlating the contacting time with the temperature and reagent strength so as to effect a substantial improvement in hydrogenation activity of said catalyst while retaining therein at least about 90 percent of said Group VIII noble metal; B. draining said excess reagent from the catalyst; and C. drying and calcining the separated catalyst at temperatures in the range of about 500-950° F. while maintaining water vapor partial pressures below about 10 psi.

Claim 10

A process as defined in claim 7 wherein the contacting time, temperature and reagent strength in step A are correlated so as to effect a substantial removal of said residual zeolitic sodium ions.

Claim 11

A process as defined in claim 8 wherein said Group VIII noble metal is palladium.

Claim 12

A process as defined in claim 8 wherein at least about 20% of said residual zeolitic sodium ions are removed.