Process for continuous preparation of fibrous polymer crystals

Claim 2

A process for preparing continuous filament-like crystals of a crystallizable polymer comprising the steps of: (a) providing a solution of a crystallizable polymer in a container therefor in contact with a rotating surface; (b) rotating said solution while growing a seed crystal of said polymer in the flowing solution and allowing the seed crystal to grow longitudinally with respect to the direction of rotation of said polymer solution; and (c) removing the thus grown polymer in the form of a continuous filament from the polymer solution at a rate substantially equal to the polymer crystal growth rate, wherein: (i) the longitudinal growth takes place at the rotating surface which surface is moving in the direction of the growth of the crystal, and (ii) at least about 15 cm of the filament-like crystal thus produced contacts said surface over a length of at least 15 cm thereof.

Claim 3

Process according to claim 1 wherein said polymer solution is contained in a vessel which also contains a rotating, surface roughened rotor.

Claim 4

Process according to claim 1 wherein the moving surface is slightly roughened.

Claim 5

Process according to claim 1 wherein the longitudinal growth takes place in a Couette flow, in which the filament-like crystal is in contact, over a length of at least 15 cm. with the rotor generating this flow.

Claim 6

Process according to claim 3 wherein the moving surface is sandblasted.

Claim 7

Process according to claim 3 wherein a non-polar polymer is used and the moving surface is non-polar.

Claim 8

Process according to claim 6 wherein the moving surface is silanized.

Claim 9

Process according to claim 1 wherein the crystallizable polymer is a linear polyolefin.

Claim 10

Process according to claim 8 wherein the linear polyolefin is polyethylene.

Claim 11

Process according to claim 8 wherein the linear polyolefine is polypropylene.

Claim 12

Process according to claim 8 wherein the solvent is p-xylene.

Claim 13

Filaments of polyethylene prepared according to the process of claim 9.

Claim 14

In a process for preparing continuous filament-like crystals of a crystallizable polymer comprising the steps of: (a) providing a solution of a crystallizable polymer in a container therefor in contact with a rotating surface; (b) rotating said solution while growing a seed crystal of said polymer in the flowing solution and allowing the seed crystal to grow longitudinally with respect to the direction of rotation of said polymer solution; and (c) removing the thus grown polymer in the form of a continuous filament from the polymer solution the improvement comprising removing said filament at a rate substantially equal to the polymer crystal growth rate, wherein: (i) the longitudinal growth takes place in a Couette flow at a roughened rotor surface generating said flow which surface is moving in the direction of the growth of the crystal, and (ii) at least about 15 cm of the filament-like crystal thus produced contacts said surface over a length of at least 15 cm thereof.

Claim 15

In a process for preparing continuous filament-like crystals of a crystallizable polymer comprising the steps of: (a) providing a solution of a crystallizable polymer in a container therefor in contact with a rotating surface; (b) rotating said solution while growing a seed crystal of said polymer in the flowing solution and allowing the seed crystal to grow longitudinally with respect to the direction of rotation of said polymer solution; and (c) removing the thus grown polymer in the form of a continuous filament from the polymer solution the improvement comprising removing said filament at a rate substantially equal to the polymer crystal growth rate, wherein: (i) the longitudinal growth takes place in a Couette flow at a roughened rotor surface generating said flow which surface is moving in the direction of the growth of the crystal, and (ii) at least about 15 cm of the filament-like crystal thus produced contacts said surface over a length of at least 15 cm thereof.

Claim 16

Process according to claim 13 wherein the ratio of the rotating speed (b) to the rate of removal of the thus grown polymer (c) is less than 50 to 1.

Claim 17

Process according to claim 14 wherein said ratio is 25 to 1.

Claim 18

Process according to claim 15 wherein said ratio is 10 to 1.

Claim 19

A process for preparing continuous polyethylene filament comprising the steps of: (a) providing an ethylene solution in a container therefor and in contact with a rotating, roughened surface; (b) rotating said surface and polyethylene while growing a seed crystal of said polymer in the flowing polyethylene solution and allowing the seed crystal to grow longitudinally with respect to the direction of rotation of the polyethylene solution; and (c) removing the thus grown ethylene polymer in the form of a continuous filament from the polymer solution at a rate substantially equal to the polymer crystal growth rate, wherein: (i) the longitudinal growth takes place at the rotating surface which surface is roughened and moving in the direction of the growth of the crystal, and (ii) at least about 15 cm of the filament-like crystal thus produced contacts said surface over a length of at least 15 cm thereof, thereby producing a polyethylene filament having a weight of between about 0.0001 and 0.0012 mg/cm, a tensile strength of greater than 100 kg/mm 2 , an E-modulus of greater than 220 kg/mm 2 and an elongation at break of less than 25 percent.

Claim 20

A process for preparing continuous polyethylene filament comprising the steps of: (a) providing an ethylene solution in a container therefor and in contact with a rotating, roughened surface; (b) rotating said surface and polyethylene while growing a seed crystal of said polymer in the flowing polyethylene solution and allowing the seed crystal to grow longitudinally with respect to the direction of rotation of the polyethylene solution; and (c) removing the thus grown ethylene polymer in the form of a continuous filament from the polymer solution at a rate substantially equal to the polymer crystal growth rate, wherein: (i) the longitudinal growth takes place at the rotating surface which surface is roughened and moving in the direction of the growth of the crystal, and (ii) at least about 15 cm of the filament-like crystal thus produced contacts said surface over a length of at least 15 cm thereof, thereby producing a polyethylene filament having a weight of between about 0.0001 and 0.0012 mg/cm, a tensile strength of greater than 100 kg/mm 2 , an E-modulus of greater than 220 kg/mm 2 and an elongation at break of less than 25 percent.