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US4137282A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing water-dispersible film-forming material

Assignee: Eneos Corp
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Filing: 1977-12-05
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Granted: 1979-01-30
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Expires: 1997-12-05
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Abstract

Abstract A process for producing a film-forming material, which comprises graft-polymerizing a monomer having a radical polymerizable ethylenically unsaturated group in the presence of a radical initiator with a butadiene polymer of a low degree of polymerization having a number average molecular weight of 300 to 10,000, a butadiene copolymer of a low degree of polymerization containing not more than 50% by weight of a copolymer component, or a mixture of these, in the form of an aqueous solution, said butadiene polymer or copolymer in aqueous solution or aqueous dispersion containing 0.05 to 0.5 mole, per 100 g of the polymer, of a basic group of the general formula ##STR1## wherein R 1 represents a hydrogen atom, a halogen atom or an organic group containing 1 to 8 carbon atoms; R 2 and R 3 are identical or different and represent an organic group containing 1 to 20 carbon atoms; R 4 represents a hydrogen atom or an organic group containing 1 to 20 carbon atoms; and X represents a hydrogen atom or a bond, and when X is a bond, the carbon atom attached to R 1 and the adjacent carbon atom to which hydrogen is attached may form a part of the main chain.

Inventors

  • 👤 Yutaka Otsuki
  • 👤 Hideo Horii
  • 👤 Yoshihiko Araki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 22:24
CPC Classifications
C; C08; C08C; C08C19/00; C08C19/30; C08C19/34; C08C19/36; C08F; C08F279/00; C08F279/02

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 213 words
A process for producing a film-forming material, which comprises graft-polymerizing in the absence of a surface active agent a monomer having a radical polymerizable ethylenically unsaturated group in the presence of a radical initiator with a butadiene polymer of a low degree of polymerization having a number average molecular weight of 300 to 10,000, a butadiene copolymer of a low degree of polymerization containing not more than 50% by weight of a copolymer component, or a mixture of these, in the form of an aqueous solution, said butadiene polymer or copolymer in aqueous solution or aqueous dispersion containing 0.05 to 0.5 mole, per 100 g of the polymer, of a basic group of the general formula ##STR15## wherein R 1 represents a hydrogen atom, a halogen atom or an organic group containing 1 to 8 carbon atoms; R 2 and R 3 are identical or different and represent an organic group containing 1 to 20 carbon atoms; R 4 represents a hydrogen atom or an organic group containing 1 to 20 carbon atoms; and X represents a hydrogen atom or a bond, and when X is a bond, the carbon atom attached to R 1 and the adjacent carbon atom to which hydrogen is attached may form a part of the main chain.
Claim 2
Dependent Claim 213 words
A process for producing a film-forming material, which comprises graft-polymerizing in the absence of a surface active agent a monomer having a radical polymerizable ethylenically unsaturated group in the presence of a radical initiator with a butadiene polymer of a low degree of polymerization having a number average molecular weight of 300 to 10,000, a butadiene copolymer of a low degree of polymerization containing not more than 50% by weight of a copolymer component, or a mixture of these, in the form of an aqueous solution, said butadiene polymer or copolymer in aqueous solution or aqueous dispersion containing 0.05 to 0.5 mole, per 100 g of the polymer, of a basic group of the general formula ##STR15## wherein R 1 represents a hydrogen atom, a halogen atom or an organic group containing 1 to 8 carbon atoms; R 2 and R 3 are identical or different and represent an organic group containing 1 to 20 carbon atoms; R 4 represents a hydrogen atom or an organic group containing 1 to 20 carbon atoms; and X represents a hydrogen atom or a bond, and when X is a bond, the carbon atom attached to R 1 and the adjacent carbon atom to which hydrogen is attached may form a part of the main chain.
Claim 3
Dependent Claim 54 words
The process of claim 1 wherein the polymer or copolymer of butadiene further contains not more than 0.2 mole, per 100 g of the polymer, of a group of the following formula ##STR16## wherein R 1 and X are as defined, and R 5 represents an organic group containing 1 to 20 carbon atoms.
Claim 4
Dependent Claim 20 words
The process of claim 1 wherein the graft-polymerizable reaction is carried out at a temperature of 200° to 100° C.
Claim 5
Dependent Claim 86 words
The process of claim 1 wherein the radical polymerizable ethylenically unsaturated monomer is a compound of the formula ##STR17## wherein R 1 ' represents a hydrogen atom or a methyl group, and R 2 ' represents an organic group containing 1 to 20 carbon atoms, and/or a compound of the general formula ##STR18## wherein n is an integer of 1 to 4, and R 3 ' represents a hydrogen atom, an alkyl group containing 1 to 10 carbon atom, a vinyl group, or a halogen atom.
Claim 6
Dependent Claim 33 words
The process of claim 1 wherein the amount of the radical polymerizable ethylenically unsaturated monomer is 20 to 500 parts by weight per 100 parts by weight of the butadiene polymer of copolymer.

References Cited (Backward Citations)

US3879358A Cited
US3887653A Cited
US3786116A Cited
US4072536A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-29 1982-07-31 1983-01-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-29 1986-07-31 1987-01-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-29 1990-07-31 1991-01-30 $7700.00 Window Closed / Lapsed

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