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US4136090A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilized copolyetherester compositions

Assignee: EIDP Inc
•
Filing: 1978-03-02
•
Granted: 1979-01-23
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Expires: 1998-03-02
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Abstract

Abstract Copolyetheresters are stabilized against oxidative degradation due to exposure to heat and light by incorporating into the polymer effective concentrations of a phenolic antioxidant and copolymerized hindered amine photostabilizer units having the formula ##STR1## wherein A is ethylene and/or propylene, X is a divalent hydrocarbon radical of 2 to 18 carbon atoms and (n + m) equals 5 to 40, said photostabilizer units being connected to ester units in the copolyetherester through ester linkages.

Inventors

  • 👤 Guenther K. Hoeschele

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 16:39
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/685; C08G63/6854; C08G63/6856

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 221 words
A copolyetherester composition stabilized against oxidative degradation due to exposure to heat and light, said composition consisting essentially of a copolyetherester consisting essentially of a multiplicity of recurring long chain ester units and short chain ester units joined head-to-tail through ester linkages, said long chain ester units being represented by the formula ##STR11## and said short chain ester units being represented by the formula ##STR12## where G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol having a number average molecular weight of about 400-6000 and a carbon to oxygen atomic ratio of about 2.0-4.3; R is a divalent radical remaining after removal of carboxyl groups from an aromatic dicarboxylic acid having a molecular weight less than about 300, and D is a divalent radical remaining after removal of hydroxyl groups from a diol having a molecular weight less than about 250; said short chain ester units amount to about 15-95% by weight of said copolyetherester and effective concentrations of a phenolic antioxidant and copolymerized hindered amine photostabilizer units having the formula ##STR13## wherein A is ethylene and/or propylene, X is a divalent hydrocarbon radical of 2 to 18 carbon atoms and (n + m) equals 5 to 40, said photostabilizer units being connected to ester units in the copolyetherester through ester linkages.
Claim 2
Dependent Claim 221 words
A copolyetherester composition stabilized against oxidative degradation due to exposure to heat and light, said composition consisting essentially of a copolyetherester consisting essentially of a multiplicity of recurring long chain ester units and short chain ester units joined head-to-tail through ester linkages, said long chain ester units being represented by the formula ##STR11## and said short chain ester units being represented by the formula ##STR12## where G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol having a number average molecular weight of about 400-6000 and a carbon to oxygen atomic ratio of about 2.0-4.3; R is a divalent radical remaining after removal of carboxyl groups from an aromatic dicarboxylic acid having a molecular weight less than about 300, and D is a divalent radical remaining after removal of hydroxyl groups from a diol having a molecular weight less than about 250; said short chain ester units amount to about 15-95% by weight of said copolyetherester and effective concentrations of a phenolic antioxidant and copolymerized hindered amine photostabilizer units having the formula ##STR13## wherein A is ethylene and/or propylene, X is a divalent hydrocarbon radical of 2 to 18 carbon atoms and (n + m) equals 5 to 40, said photostabilizer units being connected to ester units in the copolyetherester through ester linkages.
Claim 3
Dependent Claim 13 words
A composition of claim 1 wherein X is 2 or 3 carbon atoms.
Claim 4
Dependent Claim 9 words
A composition of claim 1 wherein A is ethylene.
Claim 5
Dependent Claim 13 words
A composition of claim 1 wherein (n + m) equals 10 to 30.
Claim 6
Dependent Claim 17 words
A composition of claim 1 wherein the phenolic antioxidant is N,N'-hexamethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide, N,N'-trimethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide) or mixtures thereof.
Claim 7
Dependent Claim 22 words
A composition of claim 1 wherein the copolymerized photostabilizer units have the formula ##STR14## where (n + m) equals 10 to 30.
Claim 8
Dependent Claim 18 words
A composition of claim 1 containing up to 50 millimoles of copolymerized photostabilizer units per kilogram of copolyetherester.
Claim 9
Dependent Claim 17 words
A composition of claim 1 containing about 2-20 millimoles of copolymerized photostabilizer units per kilogram of copolyetherester.
Claim 10
Dependent Claim 18 words
A composition of claim 1 containing up to 5% by weight of the copolyetherester of a phenolic antioxidant.
Claim 11
Dependent Claim 17 words
A composition of claim 1 containing about 0.1-2% by weight of the copolyetherester of a phenolic antioxidant.
Claim 12
Dependent Claim 78 words
A process for producing the stabilized copolyetherester composition of claim 1 which comprises reacting said poly(alkylene oxide) glycol, said dicarboxylic acid and said diol in the presence of effective amounts of a phenolic antioxidant that is stable and substantially nonvolatile during polymerization and a copolymerizable hindered amine photostabilizer having the formula ##STR15## wherein A is ethylene and/or propylene, X is a divalent hydrocarbon radical of 2 to 18 carbon atoms, and (n + m) equals 5 to 40.
Claim 13
Dependent Claim 13 words
A process of claim 11 wherein X is 2 or 3 carbon atoms.
Claim 14
Dependent Claim 9 words
A process of claim 11 wherein A is ethylene.
Claim 15
Dependent Claim 13 words
A process of claim 11 wherein (n + m) equals 10 to 30.
Claim 16
Dependent Claim 16 words
A process of claim 11 wherein the phenolic antioxidant is N,N'-hexamethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide), N,N'-trimethylene-bis-(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide) or mixtures thereof.
Claim 17
Dependent Claim 21 words
A process of claim 11 wherein the copolymerizable photostabilizer has the formula ##STR16## where (n + m) equals 10 to 30.

References Cited (Backward Citations)

US3766146A Cited
US3763109A Cited
US3974127A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-22 1982-07-24 1983-01-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-22 1986-07-24 1987-01-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-22 1990-07-24 1991-01-23 $7700.00 Window Closed / Lapsed

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