US4136090A
Expired / Lapsed
US
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Stabilized copolyetherester compositions
Assignee: EIDP Inc
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Filing: 1978-03-02
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Granted: 1979-01-23
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Expires: 1998-03-02
Abstract
Abstract Copolyetheresters are stabilized against oxidative degradation due to exposure to heat and light by incorporating into the polymer effective concentrations of a phenolic antioxidant and copolymerized hindered amine photostabilizer units having the formula ##STR1## wherein A is ethylene and/or propylene, X is a divalent hydrocarbon radical of 2 to 18 carbon atoms and (n + m) equals 5 to 40, said photostabilizer units being connected to ester units in the copolyetherester through ester linkages.
Inventors
- 👤 Guenther K. Hoeschele
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 16:39
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/685; C08G63/6854; C08G63/6856
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
221 words
A copolyetherester composition stabilized against oxidative degradation due to exposure to heat and light, said composition consisting essentially of a copolyetherester consisting essentially of a multiplicity of recurring long chain ester units and short chain ester units joined head-to-tail through ester linkages, said long chain ester units being represented by the formula ##STR11## and said short chain ester units being represented by the formula ##STR12## where G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol having a number average molecular weight of about 400-6000 and a carbon to oxygen atomic ratio of about 2.0-4.3; R is a divalent radical remaining after removal of carboxyl groups from an aromatic dicarboxylic acid having a molecular weight less than about 300, and D is a divalent radical remaining after removal of hydroxyl groups from a diol having a molecular weight less than about 250; said short chain ester units amount to about 15-95% by weight of said copolyetherester and effective concentrations of a phenolic antioxidant and copolymerized hindered amine photostabilizer units having the formula ##STR13## wherein A is ethylene and/or propylene, X is a divalent hydrocarbon radical of 2 to 18 carbon atoms and (n + m) equals 5 to 40, said photostabilizer units being connected to ester units in the copolyetherester through ester linkages.
Claim 2
Dependent Claim
221 words
A copolyetherester composition stabilized against oxidative degradation due to exposure to heat and light, said composition consisting essentially of a copolyetherester consisting essentially of a multiplicity of recurring long chain ester units and short chain ester units joined head-to-tail through ester linkages, said long chain ester units being represented by the formula ##STR11## and said short chain ester units being represented by the formula ##STR12## where G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide) glycol having a number average molecular weight of about 400-6000 and a carbon to oxygen atomic ratio of about 2.0-4.3; R is a divalent radical remaining after removal of carboxyl groups from an aromatic dicarboxylic acid having a molecular weight less than about 300, and D is a divalent radical remaining after removal of hydroxyl groups from a diol having a molecular weight less than about 250; said short chain ester units amount to about 15-95% by weight of said copolyetherester and effective concentrations of a phenolic antioxidant and copolymerized hindered amine photostabilizer units having the formula ##STR13## wherein A is ethylene and/or propylene, X is a divalent hydrocarbon radical of 2 to 18 carbon atoms and (n + m) equals 5 to 40, said photostabilizer units being connected to ester units in the copolyetherester through ester linkages.
Claim 3
Dependent Claim
13 words
A composition of claim 1 wherein X is 2 or 3 carbon atoms.
Claim 4
Dependent Claim
9 words
A composition of claim 1 wherein A is ethylene.
Claim 5
Dependent Claim
13 words
A composition of claim 1 wherein (n + m) equals 10 to 30.
Claim 6
Dependent Claim
17 words
A composition of claim 1 wherein the phenolic antioxidant is N,N'-hexamethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide, N,N'-trimethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide) or mixtures thereof.
Claim 7
Dependent Claim
22 words
A composition of claim 1 wherein the copolymerized photostabilizer units have the formula ##STR14## where (n + m) equals 10 to 30.
Claim 8
Dependent Claim
18 words
A composition of claim 1 containing up to 50 millimoles of copolymerized photostabilizer units per kilogram of copolyetherester.
Claim 9
Dependent Claim
17 words
A composition of claim 1 containing about 2-20 millimoles of copolymerized photostabilizer units per kilogram of copolyetherester.
Claim 10
Dependent Claim
18 words
A composition of claim 1 containing up to 5% by weight of the copolyetherester of a phenolic antioxidant.
Claim 11
Dependent Claim
17 words
A composition of claim 1 containing about 0.1-2% by weight of the copolyetherester of a phenolic antioxidant.
Claim 12
Dependent Claim
78 words
A process for producing the stabilized copolyetherester composition of claim 1 which comprises reacting said poly(alkylene oxide) glycol, said dicarboxylic acid and said diol in the presence of effective amounts of a phenolic antioxidant that is stable and substantially nonvolatile during polymerization and a copolymerizable hindered amine photostabilizer having the formula ##STR15## wherein A is ethylene and/or propylene, X is a divalent hydrocarbon radical of 2 to 18 carbon atoms, and (n + m) equals 5 to 40.
Claim 13
Dependent Claim
13 words
A process of claim 11 wherein X is 2 or 3 carbon atoms.
Claim 14
Dependent Claim
9 words
A process of claim 11 wherein A is ethylene.
Claim 15
Dependent Claim
13 words
A process of claim 11 wherein (n + m) equals 10 to 30.
Claim 16
Dependent Claim
16 words
A process of claim 11 wherein the phenolic antioxidant is N,N'-hexamethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide), N,N'-trimethylene-bis-(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide) or mixtures thereof.
Claim 17
Dependent Claim
21 words
A process of claim 11 wherein the copolymerizable photostabilizer has the formula ##STR16## where (n + m) equals 10 to 30.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-01-22 | 1982-07-24 | 1983-01-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-01-22 | 1986-07-24 | 1987-01-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-01-22 | 1990-07-24 | 1991-01-23 | $7700.00 | Window Closed / Lapsed |