US4135997A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Electrolytic production of metallic lead
Assignee: Honeywell UOP LLC
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Filing: 1978-03-09
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Granted: 1979-01-23
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Expires: 1998-03-09
Abstract
Abstract The production of metallic lead from lead bearing sources may be facilitated by a process in which a lead bearing source such as lead sulfide ores or concentrates are halogenated and the halogenated source is then brine leached in the presence of a sodium chloride solution to separate the soluble lead halide from solid material such as gangue and elemental sulfur. The soluble lead halide is recrystallized at a reduced temperature and thereafter converted to lead carbonate by treatment with sodium carbonate. Metallic lead in the form of sheets is recovered by solubilizing the lead carbonate in hydrofluosilicic acid and electrowinning lead from the solution.
Inventors
- 👤 John C. Stauter
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 16:42
CPC Classifications
C; C25; C25C; C25C1/00; C25C1/18; C22; C22B; C22B13/00; C22B13/04
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
104 words
In a process for the production of lead from a lead bearing source which comprises the steps of: (a) subjecting said lead bearing source to an activation or drying treatment; (b) halogenating the treated lead bearing source; (c) leaching the halogenated lead bearing source with brine; (d) filtering the leached solution to separate gangue from soluble lead halide; (e) crystallizing said lead halide; and (f) recovering metallic lead, the improvement which comprises converting said crystallized lead halide to lead carbonate by treatment with sodium carbonate, solubilizing said lead carbonate in hydrofluosilicic acid and subjecting the resulting lead fluosilicate to electrowinning to form metallic lead.
Claim 2
Dependent Claim
104 words
In a process for the production of lead from a lead bearing source which comprises the steps of: (a) subjecting said lead bearing source to an activation or drying treatment; (b) halogenating the treated lead bearing source; (c) leaching the halogenated lead bearing source with brine; (d) filtering the leached solution to separate gangue from soluble lead halide; (e) crystallizing said lead halide; and (f) recovering metallic lead, the improvement which comprises converting said crystallized lead halide to lead carbonate by treatment with sodium carbonate, solubilizing said lead carbonate in hydrofluosilicic acid and subjecting the resulting lead fluosilicate to electrowinning to form metallic lead.
Claim 3
Dependent Claim
40 words
The process as set forth in claim 1 in which said activation treatment of said lead bearing source is effected at a temperature in the range of from about 300° to about 600° C. in a neutral or reducing atmosphere.
Claim 4
Dependent Claim
33 words
The process as set forth in claim 1 in which the drying of said lead bearing source is effected at a temperature in the range of from about 100° to about 150° C.
Claim 5
Dependent Claim
28 words
The process as set forth in claim 1 in which the halogenation of said lead bearing source is effected by treating said source with a gaseous halogenating agent.
Claim 6
Dependent Claim
16 words
The process as set forth in claim 4 in which said halogenating agent is chlorine gas.
Claim 7
Dependent Claim
28 words
The process as set forth in claim 4 in which the halogenation is effected at a temperature in the range of from about 80° to about 120° C.
Claim 8
Dependent Claim
36 words
The process as set forth in claim 1 in which said halogenated lead bearing source is leached at a temperature in the range of from about 80° to about 120° C. with a sodium chloride solution.
Claim 9
Dependent Claim
34 words
The process as set forth in claim 1 in which the conversion of lead halide to lead carbonate is effected in a neutral chloride or water system using sodium carbonate as the conversion agent.
Claim 10
Dependent Claim
49 words
The process as set forth in claim 1 in which the electrowinning is effected under electrolysis conditions which include a voltage in the range of from about 2.5 to about 4.0 volts and a current density in the range of from about 100 to about 400 amps/m 2 .
References Cited (Backward Citations)
US1850757A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-01-22 | 1982-07-24 | 1983-01-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-01-22 | 1986-07-24 | 1987-01-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-01-22 | 1990-07-24 | 1991-01-23 | $7700.00 | Window Closed / Lapsed |