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US4135019A Expired / Lapsed US ⏱️ 0.0 years remaining

Low density bismaleimide-carbon microballoon composites

Assignee: National Aeronautics and Space Administration
•
Filing: 1977-03-16
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Granted: 1979-01-16
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Expires: 1997-03-16
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Abstract

Abstract A process for the preparation of composite laminate structures of glass cloth preimpregnated with polybismaleimide resin and adhered to a polybismaleimide glass or aromatic polyamide paper honeycomb cell structure filled or partially filled with a syntactic foam consisting of a mixture of bismaleimide resin and carbon microballoons. The carbon microballoons are prepared by pyrolyzing phenolic microballons and subsequently bonded using a 2% bismaleimide solution. The laminate structures are cured for two hours at 477° K and are ahered to the honeycomb bismaleimide adhesive using a pressure of 700kN/m 2 pressure at 450° K. The laminate composite is then post-cured for two hours at 527° K to produce a composite laminate having a density in the range from about 95 kilograms per cubic meter to 130 kilograms per cubic meter.

Inventors

  • 👤 Demetrius A. Kourtides
  • 👤 John A. Parker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 17:28
CPC Classifications
B; B32; B32B; B32B3/00; B32B3/10; B32B3/12; B29; B29D; B29D24/00; B29D24/002; B29D24/005; C; C08; C08J; C08J9/00; C08J9/32; B32B2260/00; B32B2260/02; B32B2260/021; B32B2260/04; B32B2260/046; B32B2305/00; B32B2305/02; B32B2305/024; B32B2307/00; B32B2307/70; B32B2307/72; B32B2315/00; B32B2315/08; B32B2315/085; C08J2379/00; C08J2379/04; C08J2379/08; Y; Y10; Y10S; Y10S264/00; Y10S264/06; Y10T; Y10T428/00; Y10T428/23; Y10T428/234; Y10T428/236; Y10T428/24; Y10T428/24149; Y10T428/24157; Y10T428/24174; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/31504; Y10T428/31678; Y10T428/31681; Y10T428/31721

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 46 words
A composite structure comprising: a. a bismaleimide resin impregnated cloth; b. a cellular honeycomb core structure selected from the group consisting of polyamide paper and bismaleimide-glass fabric wherein said cells contain carbon microballoons; and c. a bismaleimide adhesive bonding said impregnated cloth to said core structure.
Claim 2
Dependent Claim 46 words
A composite structure comprising: a. a bismaleimide resin impregnated cloth; b. a cellular honeycomb core structure selected from the group consisting of polyamide paper and bismaleimide-glass fabric wherein said cells contain carbon microballoons; and c. a bismaleimide adhesive bonding said impregnated cloth to said core structure.
Claim 3
Dependent Claim 80 words
A honeycomb construction in accordance with claim 1 comprising at least one cover sheet formed of glass fiber cloth impregnated with cured bismaleimide resin; and the cellular honeycomb core structure being of either polyamide paper or bismaleimide-glass fabric construction; the cells of said core being filled with carbon microballoons that are bonded in situ by a cured coating of bismaleimide resin; at least one said cover sheet being bonded over the filled cells of the core by the bismaleimide adhesive.
Claim 4
Dependent Claim 24 words
A honeycomb construction in accordance with claim 2 that is postcured at an elevated temperature to remove volatiles and to achieve minimal smoke characteristics.

References Cited (Backward Citations)

US3505168A Cited
US3475262A Cited
US3562223A Cited
US3518219A Cited
US3575756A Cited
US3811997A Cited
US3759779A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-15 1982-07-17 1983-01-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-15 1986-07-17 1987-01-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-15 1990-07-17 1991-01-16 $7700.00 Window Closed / Lapsed

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