Isocyanurate specific electrode and method of analysis and quaternary ammonium isocyanuric acid salts therefore

Claim 2

An electrode specific for the isocyanurate ion and capable of determining isocyanurate ion activity in solutions comprising: (a) a platinum conductor covered with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt; (b) means for electrically connecting the platinum conductor to a pH meter, and (c) means for insulating said platinum conductor from said solution.

Claim 3

An electrode specific for the isocyanurate ion and capable of determining isocyanurate ion activity in solutions comprising a platinum surface, portion of which is covered with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt, said surface which is not covered with said composition being covered by a substance that is impermeable to water and electrical conducting means attached to said electrode.

Claim 4

An electrode specific for the isocyanurate ion and capable of determining isocyanurate ion activity in solutions comprising a platinum surface, portion of which is covered with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt, said surface which is not covered with said composition being covered by a substance that is impermeable to water and electrical conducting means attached to said electrode.

Claim 5

The electrode of claim 2 wherein said platinum is electrically connected to a shielded coaxial cable.

Claim 6

An electrode specific for the isocyanurate ion and capable of determining isocyanurate ion activity in solutions comprising a centrally located platinum wire one end of which is coated with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt, said wire being surrounded from the coated end for a distance along the length of the wire by a substance that is impermeable to water.

Claim 7

An electrode specific for the isocyanurate ion and capable of determining isocyanurate ion activity in solutions comprising a centrally located platinum wire one end of which is coated with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt, said wire being surrounded from the coated end for a distance along the length of the wire by a substance that is impermeable to water.

Claim 8

The electrode of claim 4 wherein the other end of said platinum wire is electrically connected to a shielded coaxial cable.

Claim 9

A platinum redox electrode that has been modified by covering that part of the platinum that is exposed with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt.

Claim 10

A platinum redox electrode that has been modified by covering that part of the platinum that is exposed with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt.

Claim 11

An electrochemical method of analyzing an aqueous solution for isocyanurate ion which comprises: (a) immersing a reference electrode and a platinum electrode covered with a plasticized polyvinyl chloride resin containing a quaternary ammonium isocyanurate salt in a series of aqueous solutions containing known molar concentrations of isocyanurate ions; (b) measuring the difference in potential between the reference electrode and covered platinum electrode when immersed in each of said solutions; (c) preparing a calibration curve by plotting a function of the molar isocyanurate concentration of each solution against the differential potential developed in that solution; (d) immersing said reference electrode and said platinum electrode in an unknown aqueous solution to be analyzed for isocyanurate activity and measuring the differential voltage developed; and (e) determining from the measured differential voltage and the calibration curve the concentration of isocyanurate ion in said unknown aqueous solution.

Claim 12

An electrochemical method of analyzing an aqueous solution for isocyanurate ion which comprises: (a) immersing a reference electrode and a platinum electrode covered with a plasticized polyvinyl chloride resin containing a quaternary ammonium isocyanurate salt in a series of aqueous solutions containing known molar concentrations of isocyanurate ions; (b) measuring the difference in potential between the reference electrode and covered platinum electrode when immersed in each of said solutions; (c) preparing a calibration curve by plotting a function of the molar isocyanurate concentration of each solution against the differential potential developed in that solution; (d) immersing said reference electrode and said platinum electrode in an unknown aqueous solution to be analyzed for isocyanurate activity and measuring the differential voltage developed; and (e) determining from the measured differential voltage and the calibration curve the concentration of isocyanurate ion in said unknown aqueous solution.

Claim 13

The method of claim 7 wherein the quaternary ammonium salt is tricaprylylmethyl ammonium isocyanurate.

Claim 14

The method of claim 7 wherein the quaternary ammonium salt is tetrabutyl ammonium isocyanurate.

Claim 15

The method of claim 7 wherein the plasticizer is decanol.

Claim 16

A quaternary isocyanuric acid salt having the formula: ##STR2## wherein R 1 , R 2 , R 3 and R 4 are alkyl radicals of 1 to 18 carbon atoms and the total number of carbon atoms in all of the alkyl radicals is such that the quaternary ammonium salt is soluble in decanol.

Claim 17

A quaternary isocyanuric acid salt having the formula: ##STR2## wherein R 1 , R 2 , R 3 and R 4 are alkyl radicals of 1 to 18 carbon atoms and the total number of carbon atoms in all of the alkyl radicals is such that the quaternary ammonium salt is soluble in decanol.

Claim 18

The quaternary isocyanuric acid salt of claim 11 wherein R 1 , R 2 , R 3 and R 4 are butyl radicals.

Claim 19

The quaternary isocyanuric acid salt of claim 11 wherein R 1 , R 2 and R 3 are caprylyl radicals and R 4 is a methyl radical.