US4132766A
Expired / Lapsed
US
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Separation of oxygen from gaseous mixtures with molten alkali metal salts
Assignee: Air Products and Chemicals Inc
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Filing: 1977-05-24
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Granted: 1979-01-02
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Expires: 1997-05-24
Abstract
Abstract Oxygen is separated from air by a regenerative chemical process. Air is contacted with an oxygen acceptor comprised of a molten solution of alkali nitrite and nitrate salts at elevated temperature and pressure, causing the oxygen to react with the nitrite, and thereby increasing the proportion of nitrate in the salt solution. The oxidized oxygen acceptor is separated from the oxygen depleted air, and then its pressure is reduced while supplying heat, thereby causing the release of relatively pure oxygen, which is collected. The oxygen acceptor, restored to its approximate original composition, is recycled to the oxidation step. Since the oxygen acceptor remains in the liquid state throughout the cycle, both salt to salt heat exchange and salt circulation are facilitated, making possible a continuous process of high efficiency.
Inventors
- 👤 Donald C. Erickson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 14:28
CPC Classifications
C; C01; C01B; C01B13/00; C01B13/02; C01B13/0292; C01B13/0229; C01B13/0233; C01B2210/00; C01B2210/0043; C01B2210/0046; C01B2210/0051; C01B2210/0062
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
85 words
In a continuous process for producing oxygen which comprises the repeated steps of contacting air with an oxygen acceptor which becomes oxidized, separately releasing the oxygen from the oxidized oxygen acceptor so as to regenerate the oxygen acceptor and generate the product oxygen and recycling regenerated oxygen acceptor, the improvement which comprises: said oxygen acceptor a molten solution comprised of alkali metal nitrite and nitrate salts wherein the ratio of alkali metal nitrate to alkali metal nitrite in the solution is maintained greater than 0.3
Claim 2
Dependent Claim
85 words
In a continuous process for producing oxygen which comprises the repeated steps of contacting air with an oxygen acceptor which becomes oxidized, separately releasing the oxygen from the oxidized oxygen acceptor so as to regenerate the oxygen acceptor and generate the product oxygen and recycling regenerated oxygen acceptor, the improvement which comprises: said oxygen acceptor a molten solution comprised of alkali metal nitrite and nitrate salts wherein the ratio of alkali metal nitrate to alkali metal nitrite in the solution is maintained greater than 0.3
Claim 3
Dependent Claim
37 words
The process of claim 1 wherein the heat released by the exothermic reaction between the oxygen acceptor and air is indirectly transferred to supply at least part of the heat required by the endothermic oxygen releasing reaction.
Claim 4
Dependent Claim
33 words
The process of claim 1 wherein at least 50% of the molten salt solution consists of alkali metal nitrate and nitrate salts, and wherein the alkali metal is potassium, sodium, or mixtures thereof.
Claim 5
Independent Claim
152 words
A method of continuously producing a gas enriched in oxygen content from an oxygen containing gas mixture comprising the steps of: a. establishing an oxygen acceptor comprised of a molten solution of alkali metal nitrate and nitrite salts, wherein the molar ratio of alkali metal nitrate to alkali metal nitrite in the solution is maintained greater than 0.3 b. contacting the oxygen containing gas mixture with the oxygen acceptor, thereby oxidizing part of the dissolved alkali metal nitrite to nitrate and depleting the oxygen content of the oxygen containing gas mixture; c. separating the oxidized oxygen acceptor from the oxygen depleted gas mixture; d. decomposing part of the dissolved alkali metal nitrate to nitrite and oxygen, thereby regenerating the oxygen acceptor and yielding said gas enriched in oxygen content; e. separating the gas enriched in oxygen content from the regenerated oxygen acceptor; f. recycling the regenerated oxygen acceptor to step b. above.
Claim 6
Independent Claim
152 words
A method of continuously producing a gas enriched in oxygen content from an oxygen containing gas mixture comprising the steps of: a. establishing an oxygen acceptor comprised of a molten solution of alkali metal nitrate and nitrite salts, wherein the molar ratio of alkali metal nitrate to alkali metal nitrite in the solution is maintained greater than 0.3 b. contacting the oxygen containing gas mixture with the oxygen acceptor, thereby oxidizing part of the dissolved alkali metal nitrite to nitrate and depleting the oxygen content of the oxygen containing gas mixture; c. separating the oxidized oxygen acceptor from the oxygen depleted gas mixture; d. decomposing part of the dissolved alkali metal nitrate to nitrite and oxygen, thereby regenerating the oxygen acceptor and yielding said gas enriched in oxygen content; e. separating the gas enriched in oxygen content from the regenerated oxygen acceptor; f. recycling the regenerated oxygen acceptor to step b. above.
Claim 7
Dependent Claim
49 words
The method of claim 4 wherein the oxidation reaction and the decomposition reaction are conducted concurrently and in heat exchange relationship, thereby causing at least part of the heat released in the exothermic oxidation reaction to supply at least part of the heat required by the endothermic decomposition reaction.
Claim 8
Dependent Claim
100 words
The method of claim 4, wherein at least 50% of the molten salt solution consists of alkali metal nitrate and nitrite salts, and the molar ratio of alkali metal nitrates to alkali metal nitrites in the salt solution is maintained within the approximate limits of 0.3 to 10, and the salt solution temperature is maintained within the approximate limits of 800K to 1200K; and the pressure of the oxidation reaction is maintained within the approximate limits of 5 to 100 atmospheres; and the pressure of the decomposition reaction is maintained within the approximate limits of subatmospheric pressure to 15 atmospheres.
Claim 9
Dependent Claim
16 words
The method of claim 6 wherein the alkali metal is potassium, sodium, lithium, or mixtures thereof.
Claim 10
Dependent Claim
45 words
The method of claim 6 wherein at least one reaction vessel is provided to contain the salt solution throughout the cycle of steps comprising the method, and wherein the portion of salt solution contained in each respective vessel remains in that vessel throughout the cycle.
Claim 11
Dependent Claim
34 words
The method of claim 6 wherein separate reaction vessels are provided for the respective oxidation and decomposition reactions, and the salt solution is circulated between the respective vessels in the course of the cycle.
Claim 12
Dependent Claim
28 words
The method of claim 6 wherein the decomposition reaction is caused to occur by decreasing the pressure of the salt solution below its prevailing equilibrium oxygen partial pressure.
Claim 13
Dependent Claim
57 words
The method of claim 4 wherein the oxygen containing gas mixture is compressed prior to contacting the oxygen acceptor, and the compression energy of the oxygen depleted gas mixture is recovered by expanding it through a turbo-expander, and wherein the expansion takes place in two stages with reheating of the oxygen depleted gas mixture occurring between stages.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-01-01 | 1982-07-03 | 1983-01-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-01-01 | 1986-07-03 | 1987-01-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-01-01 | 1990-07-03 | 1991-01-02 | $7700.00 | Window Closed / Lapsed |