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US4132724A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of organoaluminum compositions

Assignee: Manchem Ltd
•
Filing: 1977-06-30
•
Granted: 1979-01-02
•
Expires: 1997-06-30
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Abstract

Abstract Organoaluminum compounds of the formula ##STR1## in which A, B and C are each selected from alkoxy, aryloxy, alkylcarboxyl, arylcarboxyl, a dicarboxylic acid half ester, a dicarboxylic acid half amide, alkyl sulfate, aryl sulfonate, dialkyl phosphate, alkylaryl phosphate, diaryl phosphate, dialkyl-phosphite, alkylaryl phosphite, diarylphosphite, or oxymetal group of the formula OMA in which M is a divalent metal; a and b are 0, 1 or 2 with the proviso that a + b = 2; x is at least 2 and z is a polyfunctional group selected from organic polymers or polycondensation products, inorganic macromolecules and metals. The products are prepared by addition of a polyfunctional compound or metal to an excess of organoaluminum compound.

Inventors

  • 👤 John H. W. Turner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 18:06
CPC Classifications
C; C09; C09D; C09D5/00; B; B22; B22C; B22C1/00; B22C1/16; B22C1/20; B22C1/205; C07; C07F; C07F5/00; C07F5/06; C07F5/069; C08; C08G; C08G63/00; C08G63/91; C08G63/914; C08G79/00; C08G79/10; C08K; C08K5/00; C08K5/0091; C08K5/56

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 177 words
The process for preparing a storage-stable fluid, moisture-sensitive compound of a formula selected from the group consisting of ##STR9## in which a polyfunctional compound of the formula H x Z is added to an excess of an organoaluminum compound of at least one formula selected from the group consisting of ##STR10## wherein A, B and C are each selected from the group consisting of alkoxy, aryloxy, alkylcarboxyl, arylcarboxyl, a dicarboxylic acid half ester, a dicarboxylic acid half amide, alkyl sulfate, aryl sulfonate, dialkyl phosphate, alkylaryl phosphate, diarylphosphate, dialkylphosphite, alkylaryl phosphite, diarylphosphite, and an oxymetal organic group of the formula OMA in which M is a divalent metal and A is as defined herein, a and b are each selected from 0, 1 and 2 and c is selected from 1, 2 and 3 with the proviso that a + b + c = 3, H x Z is a polyfunctional compound selected from the group consisting of pigments and fillers containing reactive hydroxyl groups, and x is the number of groups capable of reacting with said C.
Claim 2
Dependent Claim 177 words
The process for preparing a storage-stable fluid, moisture-sensitive compound of a formula selected from the group consisting of ##STR9## in which a polyfunctional compound of the formula H x Z is added to an excess of an organoaluminum compound of at least one formula selected from the group consisting of ##STR10## wherein A, B and C are each selected from the group consisting of alkoxy, aryloxy, alkylcarboxyl, arylcarboxyl, a dicarboxylic acid half ester, a dicarboxylic acid half amide, alkyl sulfate, aryl sulfonate, dialkyl phosphate, alkylaryl phosphate, diarylphosphate, dialkylphosphite, alkylaryl phosphite, diarylphosphite, and an oxymetal organic group of the formula OMA in which M is a divalent metal and A is as defined herein, a and b are each selected from 0, 1 and 2 and c is selected from 1, 2 and 3 with the proviso that a + b + c = 3, H x Z is a polyfunctional compound selected from the group consisting of pigments and fillers containing reactive hydroxyl groups, and x is the number of groups capable of reacting with said C.
Claim 3
Dependent Claim 24 words
The process according to claim 1 in which A, B, and C represent alkoxy or alkoxy-substituted alkoxy groups of 1 to 6 carbon atoms.
Claim 4
Dependent Claim 15 words
The process according to claim 2 in which said alkoxy group is a branched chain.
Claim 5
Dependent Claim 16 words
The process according to claim 1 in which said H x Z contains surface hydroxyl groups.
Claim 6
Dependent Claim 16 words
The process according to claim 1 in which said H x Z is an inorganic pigment.
Claim 7
Dependent Claim 59 words
The process according to claim 1 in which said H x Z is a member of the group consisting of silica, titanium dioxide, china clay, blanc fix, Prussian blue, phthalocyanines, iron oxide, cuprous oxide, red lead, lead chromate, zinc borate, basic lead carbonate, basic lead sulfate, zinc phosphate, zinc chromate, aluminum, zinc, copper, carbon, zirconia, asbestos, titania and vermiculite.
Claim 8
Dependent Claim 20 words
The process according to claim 1 in which said H x Z contains water physically bound to the surface thereof.
Claim 9
Dependent Claim 15 words
The process according to claim 1 in which said organoaluminum compound is in a solvent.
Claim 10
Dependent Claim 17 words
The process according to claim 1 in which an alkyd resin is added to the reaction mixture.
Claim 11
Dependent Claim 35 words
In the process of reacting an alkoxyaluminum compound with an inorganic pigment containing at least two reactive hydroxyl groups, the improvement which consists of adding said inorganic pigment to an excess of said alkoxyaluminum compound.
Claim 12
Dependent Claim 35 words
In the process of reacting an alkoxyaluminum compound with an inorganic pigment containing at least two reactive hydroxyl groups, the improvement which consists of adding said inorganic pigment to an excess of said alkoxyaluminum compound.
Claim 13
Dependent Claim 16 words
The process of claim 11 in which an alkyd resin is included in the reaction mixture.
Claim 14
Dependent Claim 13 words
The process of claim 11 in which said inorganic pigment is titanium dioxide.

References Cited (Backward Citations)

GB772144A Cited
GB798186A Cited
GB809309A Cited
GB835874A Cited
GB832622A Cited
US2911316A Cited
GB803454A Cited
US3296242A Cited
US3679723A Cited
US3788885A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-01 1982-07-03 1983-01-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-01 1986-07-03 1987-01-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-01 1990-07-03 1991-01-02 $7700.00 Window Closed / Lapsed

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