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US4132628A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for recovering hydrocarbons from molten metal halides

Assignee: United States Department of Energy
•
Filing: 1977-08-12
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Granted: 1979-01-02
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Expires: 1997-08-12
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Abstract

Abstract In a process for hydrocracking heavy carbonaceous materials by contacting such carbonaceous materials with hydrogen in the presence of a molten metal halide catalyst to produce hydrocarbons having lower molecular weights and thereafter recovering the hydrocarbons so produced from the molten metal halide, an improvement comprising injecting into the spent molten metal halide, a liquid low-boiling hydrocarbon stream is disclosed.

Inventors

  • 👤 Melvyn B. Pell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 05:42
CPC Classifications
C; C10; C10G; C10G47/00; C10G47/02; C10G47/08; Y; Y10; Y10S; Y10S423/00; Y10S423/09; Y10S423/12

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 107 words
In a process for hydrocracking heavy carbonaceous materials by contacting said heavy carbonaceous materials with hydrogen in the presence of a molten metal halide catalyst to produce hydrocarbons having a lower molecular weight and thereafter separating at least a major portion of said hydrocarbons from the spent molten metal halide, the improvement comprising separating a major portion of said hydrocarbons from said spent melt and thereafter injecting into said spent molten metal halide a liquid low-boiling hydrocarbon stream so that said liquid low-boiling hydrocarbon stream is vaporized in said spent molten metal halide thereby recovering additional quantities of heavy hydrocarbonaceous material from said spent molten metal halide.
Claim 2
Dependent Claim 107 words
In a process for hydrocracking heavy carbonaceous materials by contacting said heavy carbonaceous materials with hydrogen in the presence of a molten metal halide catalyst to produce hydrocarbons having a lower molecular weight and thereafter separating at least a major portion of said hydrocarbons from the spent molten metal halide, the improvement comprising separating a major portion of said hydrocarbons from said spent melt and thereafter injecting into said spent molten metal halide a liquid low-boiling hydrocarbon stream so that said liquid low-boiling hydrocarbon stream is vaporized in said spent molten metal halide thereby recovering additional quantities of heavy hydrocarbonaceous material from said spent molten metal halide.
Claim 3
Dependent Claim 12 words
The improvement of claim 1 wherein said metal halide is zinc halide.
Claim 4
Dependent Claim 20 words
The improvement of claim 2 wherein said low-boiling stream has a boiling point, at one atmosphere, below about 200° C.
Claim 5
Dependent Claim 19 words
The improvement of claim 3 wherein the boiling point of said low-boiling stream is greater than about 50° C.
Claim 6
Dependent Claim 34 words
The improvement of claim 1 wherein substantially all hydrocarbons having a boiling point below about 475° C have been removed from said molten zinc chloride prior to injection of said liquid low-boiling hydrocarbon stream.

References Cited (Backward Citations)

US3355376A Cited
US3371049A Cited
US3505206A Cited
US3505207A Cited
US3679577A Cited
US3594329A Cited
US3764515A Cited
US3736250A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-01 1982-07-03 1983-01-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-01 1986-07-03 1987-01-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-01 1990-07-03 1991-01-02 $7700.00 Window Closed / Lapsed

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