US4130477A
Expired / Lapsed
US
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Froth flotation process
Assignee: Dow Chemical Co
•
Filing: 1977-12-21
•
Granted: 1978-12-19
•
Expires: 1997-12-21
Abstract
Abstract A process for the recovery of mineral values by froth flotation in an aqueous medium from mineral ores with the use of an effective amount of a mercaptan polyalkylene oxide frother.
Inventors
- 👤 Donald M. Podobnik
- 👤 Guy H. Harris
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 09:06
CPC Classifications
B; B03; B03D; B03D1/00; B03D1/001; B03D1/004; B03D1/012; B03D2201/00; B03D2201/04; B03D2203/00; B03D2203/02
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
181 words
In a process for collecting mineral values from an ore which comprises mixing ground ore with water to form an ore pulp and aerating said pulp in the presence of an effective amount of a frother, the improvement which comprises carrying out said process with a frother of the formula: R[S(EO).sub.x (PO).sub.y (BO).sub.z H].sub.n wherein, in said formula, Eo = c 2 h 4 o, po = c 3 h 6 o and BO = C 4 H 8 O, n = 1 or 2, x = 0-4, y = 1-10, z = 0-2, and where n = 1, the average sum of the x, y and z groups is from 2 to about 12, R represents alkenyl of 3-5 carbon atoms, an alkyl group of from 1 to about 8 carbon atoms or an aryl group, and where n = 2 the average sum of all x+y+z groups is from 2 to about 12, R represents, a bridging --(CH 2 ) m --radical wherein m = 1-6, or a bridging benzylidene radical ##STR7## or frother mixtures of the above formula.
Claim 2
Dependent Claim
181 words
In a process for collecting mineral values from an ore which comprises mixing ground ore with water to form an ore pulp and aerating said pulp in the presence of an effective amount of a frother, the improvement which comprises carrying out said process with a frother of the formula: R[S(EO).sub.x (PO).sub.y (BO).sub.z H].sub.n wherein, in said formula, Eo = c 2 h 4 o, po = c 3 h 6 o and BO = C 4 H 8 O, n = 1 or 2, x = 0-4, y = 1-10, z = 0-2, and where n = 1, the average sum of the x, y and z groups is from 2 to about 12, R represents alkenyl of 3-5 carbon atoms, an alkyl group of from 1 to about 8 carbon atoms or an aryl group, and where n = 2 the average sum of all x+y+z groups is from 2 to about 12, R represents, a bridging --(CH 2 ) m --radical wherein m = 1-6, or a bridging benzylidene radical ##STR7## or frother mixtures of the above formula.
Claim 3
Dependent Claim
14 words
The process of claim 1 wherein the frother is employed with a mineral collector.
Claim 4
Dependent Claim
9 words
The process of claim 1 wherein n is 1.
Claim 5
Dependent Claim
10 words
The process of claim 3 wherein frother mixtures are employed.
Claim 6
Dependent Claim
9 words
The process of claim 3 wherein R is alkyl.
Claim 7
Dependent Claim
9 words
The process of claim 3 wherein R is propenyl.
Claim 8
Dependent Claim
22 words
The process of claim 4 wherein z is 0 and the average sum of x+y is from about 2 to about 8.
Claim 9
Dependent Claim
17 words
The process of claim 7 wherein R is alkyl of from 1 to about 6 carbon atoms.
Claim 10
Dependent Claim
9 words
The process of claim 8 wherein R is methyl.
Claim 11
Dependent Claim
35 words
The process of claim 4 wherein x and z are 0, the average sum of y is from about 2 to about 8 and R is alkyl of from 1 to about 6 carbon atoms.
Claim 12
Dependent Claim
20 words
The process of claim 4 wherein x and z are each 0 and y is an average sum of 5.
Claim 13
Dependent Claim
17 words
The process of claim 11 wherein R is alkyl of from 1 to about 6 carbon atoms.
Claim 14
Dependent Claim
9 words
The process of claim 12 wherein R is methyl.
Claim 15
Dependent Claim
20 words
The process of claim 4 wherein x and z are each 0 and y is an average sum of 7.
Claim 16
Dependent Claim
17 words
The process of claim 14 wherein R is alkyl of from 1 to about 6 carbon atoms.
Claim 17
Dependent Claim
9 words
The process of claim 15 wherein R is methyl.
Claim 18
Dependent Claim
9 words
The process of claim 1 wherein n is 2.
Claim 19
Dependent Claim
10 words
The process of claim 17 wherein frother mixtures are employed.
Claim 20
Dependent Claim
24 words
The process of claim 18 wherein z is zero, R is --(CH 2 ) m -- and m is from 1 to about 4.
Claim 21
Dependent Claim
25 words
The process of claim 18 wherein z is 0, the average sum of x+y is from about 2 to about 8 and m is 2-4.
Claim 22
Dependent Claim
11 words
The process of claim 18 wherein R is a benzylidene radical.
Claim 23
Dependent Claim
22 words
The process of claim 21 wherein x is 0 and the average sum of x+y is from about 2 to about 8.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-12-18 | 1982-06-19 | 1982-12-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-12-18 | 1986-06-19 | 1986-12-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-12-18 | 1990-06-19 | 1990-12-19 | $7700.00 | Window Closed / Lapsed |