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US4129569A Expired / Lapsed US ⏱️ 0.0 years remaining

Cyclic oxazo derivatives

Assignee: International Flavors and Fragrances Inc
•
Filing: 1977-06-16
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Granted: 1978-12-12
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Expires: 1997-06-16
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Abstract

Abstract Described are intermediate mixtures of cyclic oxazo derivatives having the generic structure: ##STR1## wherein one of the dashed lines is a carbon carbon double bond and the other two dashed lines are carbon carbon single bonds and n is 0 or 1; R 1 , R 2 and R 6 are each the same or different and each represents hydrogen or C 1 -C 3 lower alkyl; and R 3 , R 4 and R 5 are each the same or different and each represents hydrogen or methyl; as well as the precursor oxazo derivative having the structure: ##STR2## Such oxazo derivatives have as their primary use intermediates in reactions whereby mixtures of dihydro alpha ionone, dihydro beta ionone and dihydro gamma ionone or homologues thereof are produced.

Inventors

  • 👤 William L. Schreiber
  • 👤 James N. Siano
  • 👤 John B. Hall

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:15
CPC Classifications
C; C07; C07D; C07D263/00; C07D263/02; C07D263/04; C07C; C07C45/00; C07C45/56; C07D265/00; C07D265/04; C07D265/06

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 110 words
A mixture of three oxazo derivatives of dihydro ionone derivatives defined by the generic structure: ##STR13## wherein one of the dashed lines is a carbon carbon double bond and the other two dashed lines are carbon carbon single bonds and n is 0 or 1; R 1 , R 2 and R 6 are each the same or different and each represents hydrogen or C 1 -C 3 lower alkyl; and R 3 , R 4 and R 5 are each the same or different and each represents hydrogen or methyl, wherein in said mixture, the only difference among the derivatives is in the position of the carbon-to-carbon double bond.
Claim 2
Dependent Claim 110 words
A mixture of three oxazo derivatives of dihydro ionone derivatives defined by the generic structure: ##STR13## wherein one of the dashed lines is a carbon carbon double bond and the other two dashed lines are carbon carbon single bonds and n is 0 or 1; R 1 , R 2 and R 6 are each the same or different and each represents hydrogen or C 1 -C 3 lower alkyl; and R 3 , R 4 and R 5 are each the same or different and each represents hydrogen or methyl, wherein in said mixture, the only difference among the derivatives is in the position of the carbon-to-carbon double bond.
Claim 3
Dependent Claim 63 words
The mixture of oxazo derivatives of claim 1 wherein each of R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are hydrogen and n is 0 defined according to the structure: ##STR14## wherein one of the dashed lines is a carbon carbon double bond and the other two dashed lines are carbon carbon single bonds.
Claim 4
Dependent Claim 12 words
A cyclic oxazo derivative of geranyl acetone having the structure: ##STR15## .
Claim 5
Dependent Claim 12 words
A cyclic oxazo derivative of geranyl acetone having the structure: ##STR15## .

References Cited (Backward Citations)

US2960508A Cited
US2974140A Cited
FR2143563B1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-12-11 1982-06-12 1982-12-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-12-11 1986-06-12 1986-12-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-12-11 1990-06-12 1990-12-12 $7700.00 Window Closed / Lapsed

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