US4129556A
Expired / Lapsed
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Curable epoxide resin mixtures
Assignee: BASF Corp
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Filing: 1977-12-02
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Granted: 1978-12-12
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Expires: 1997-12-02
Abstract
Abstract Curable mixtures containing (a) a polyepoxide compound having on average more than one epoxide group per molecule and (b) a diamine which contains hydroxyl groups and has the general formula Ia or Ib ##STR1## IN WHICH R is an alkyl radical having 2 to 16 C atoms, an aralkylene radical having 7 to 12 C atoms, an arylene radical having 6 to 16 C atoms, a cycloaliphatic radical having 6 to 12 C atoms or a radical containing at least one N, O or S atom in chains or cyclic groups, and R 1 is a hydrogen atom, a halogen atom or an alkyl group having 1 to 4 C atoms and in which, in formula Ia, the two OH groups are in the orthoposition or para-position relative to the methylene group, there being, in the mixtures, 0.5 to 1.5 equivalents of active hydrogen atoms, which are bonded to nitrogen and oxygen in the diamine containing hydroxyl groups, per 1 equivalent of epoxide groups.
Inventors
- 👤 Helmut Zondler
- 👤 Roland Moser
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 01:46
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/62; C08G59/621; C08G59/623
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
169 words
A curable mixture comprising (a) a polyepoxide compound having on average more than one epoxide group per molecule and (b) a hydroxyl groups containing diamine of the formula Ia or Ib ##STR27## in which R denotes a straight-chain or branched alkylene having a total of 2 to 16 C atoms, an aralkylene having a total of 7 to 12 C atoms, an arylene having a total of 6 to 16 C atoms, a cycloaliphatic or cycloaliphatic-aliphatic radical having 6 to 12 C atoms or a radical which contains at least one N, O or S atom in chains or cyclic groups and R 1 denotes hydrogen, halogen or alkyl group having 1 to 4 C atoms, and in which, in formula Ia, the two OH groups are in the ortho-position or para-position relative to the methylene group, there being, in the mixture, 0.5 to 1.5 equivalents of active hydrogen atoms, which are bonded to nitrogen and oxygen in the diamine containing hydroxyl groups, per 1 equivalent of epoxide groups.
Claim 2
Dependent Claim
169 words
A curable mixture comprising (a) a polyepoxide compound having on average more than one epoxide group per molecule and (b) a hydroxyl groups containing diamine of the formula Ia or Ib ##STR27## in which R denotes a straight-chain or branched alkylene having a total of 2 to 16 C atoms, an aralkylene having a total of 7 to 12 C atoms, an arylene having a total of 6 to 16 C atoms, a cycloaliphatic or cycloaliphatic-aliphatic radical having 6 to 12 C atoms or a radical which contains at least one N, O or S atom in chains or cyclic groups and R 1 denotes hydrogen, halogen or alkyl group having 1 to 4 C atoms, and in which, in formula Ia, the two OH groups are in the ortho-position or para-position relative to the methylene group, there being, in the mixture, 0.5 to 1.5 equivalents of active hydrogen atoms, which are bonded to nitrogen and oxygen in the diamine containing hydroxyl groups, per 1 equivalent of epoxide groups.
Claim 3
Dependent Claim
72 words
A mixture according to claim 1, which comprises a bis-(2-hydroxybenzyl)-diamine of the formula II ##STR28## in which R denotes straight-chain or branched alkylene having a total of 2 to 16 C atoms or aralkylene having a total of 7 to 12 C atoms or arylene having a total of 6 to 16 C atoms or a radical which contains at least one N, O or S atom in chains or cyclic groups.
Claim 4
Dependent Claim
28 words
A mixture according to claim 2, which comprises a bis-(2-hydroxybenzyl)-diamine of the formula II in which R denotes unbranched or branched alkylene having 2 to 12 C atoms.
Claim 5
Dependent Claim
83 words
A mixture according to claim 2, which comprises a bis-(2-hydroxybenzyl)-diamine of the formula II in which R denotes a divalent residue of the formula III ##STR29## in which R 2 denotes --SO 2 --, --NH-- or --O--, or in which R is a divalent residue of the formula IV ##STR30## in which R 3 denotes --H or --CH 3 , or in which R is a divalent residue of the formula V ##STR31## in which R 3 denotes --H or --CH 3 .
Claim 6
Dependent Claim
27 words
A mixture according to claim 4, which comprises a bis-(2-hydroxybenzyl)-diamine in which R is of the formula IV and R 3 is --H or --CH 3 .
Claim 7
Dependent Claim
37 words
A mixture according to claim 2, which comprises a bis-(2-hydroxybenzyl)-diamine of the formula II in which R denotes a divalent residue selected from the group consisting of ##STR32## wherein R 3 denotes --H or --CH 3 .
Claim 8
Dependent Claim
23 words
A mixture according to claim 1, which comprises a bis-(2-hydroxybenzyl)-diamine of the formula Ia, Ib or II which is solid at room temperature.
Claim 9
Dependent Claim
60 words
A mixture according to claim 1, which comprises as the bis-(2-hydroxybenzyl)-diamine of the formula Ia, Ib or II, a compound of this type which has been obtained by catalytically hydrogenating a bisazomethine of the formula ##STR33## in the presence of inert organic solvents at temperatures of 20° to 150° C and subsequently freeing the product from the catalyst and solvents.
Claim 10
Dependent Claim
22 words
A mixture according to claim 1, wherein the said mixture is in the form of a B-stage which is stable on storage.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-12-11 | 1982-06-12 | 1982-12-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-12-11 | 1986-06-12 | 1986-12-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-12-11 | 1990-06-12 | 1990-12-12 | $7700.00 | Window Closed / Lapsed |