US4129549A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of grafting a polymer to filler materials
Assignee: Union Minerale
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Filing: 1976-03-26
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Granted: 1978-12-12
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Expires: 1996-03-26
Abstract
Abstract A method of grafting a polymer to filler materials, which comprises the steps of fixing a predetermined quantity of a surfactant to the mineral particles of said filler materials while keeping free one or a plurality of reactive functions, subsequently adding a product capable to reacting with the still free functions of said surfactant, in order to form in situ an organic polymer which is thus strongly fixed to the mineral filler by a heat treatment at a temperature in the range of 100° to 150° C.
Inventors
- 👤 Lucien Kahane
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 05:00
CPC Classifications
C; C08; C08K; C08K9/00; C08K9/04; C08G; C08G83/00; C08G83/001; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2991; Y10T428/2998
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
118 words
A method of grafting a polymer to an inorganic filler material composed of mineral particles comprising: (a) fixing a predetermined quantity of a surfactant consisting essentially of a non-ionic substance containing a plurality of --OH functions to the mineral particles of said filler material while keeping free at least one functionally reactive --OH site of said surfactant; and (b) reacting the product formed in step (a) at a temperature in the range of about from 100° C. to 150° C. with an organic chemical reagent containing at least one carboxyl function capable of esterifying said free at least one functionally reaction --OH site of the surfactant to form, in situ, an organic polymer grafted to the mineral filler.
Claim 2
Independent Claim
118 words
A method of grafting a polymer to an inorganic filler material composed of mineral particles comprising: (a) fixing a predetermined quantity of a surfactant consisting essentially of a non-ionic substance containing a plurality of --OH functions to the mineral particles of said filler material while keeping free at least one functionally reactive --OH site of said surfactant; and (b) reacting the product formed in step (a) at a temperature in the range of about from 100° C. to 150° C. with an organic chemical reagent containing at least one carboxyl function capable of esterifying said free at least one functionally reaction --OH site of the surfactant to form, in situ, an organic polymer grafted to the mineral filler.
Claim 3
Dependent Claim
36 words
The method of claim 1 wherein the filler material is a substance capable of absorbing little or no organic product and is selected from the group consisting of asbestos, dolomite, chalk, kaolinite, marmor, quartz, and talc.
Claim 4
Dependent Claim
32 words
The method of claim 1 wherein the filler material is a substance capable of absorbing an organic product and is selected from the group consisting of attapulgite, montmorillonite, silica gel, and sepiolite.
Claim 5
Dependent Claim
22 words
The method of claim 2 wherein the quantity of surfactant ranges from about 0.5 to 10% by weight of the filler material.
Claim 6
Dependent Claim
52 words
The method of claim 1 wherein the non-ionic substance is a member selected from the group consisting of ethylene glycol, glycerol, a polyethylene glycol, and a glycol ether, and the organic chemical reagent is a diacid selected from the group consisting of phthalic acid, maleic acid, and the anhydrides of these diacids.
Claim 7
Dependent Claim
24 words
The method of claim 1 wherein the quantity of the organic chemical reagent ranges from about 1 to 20% by weight of the surfactant.
Claim 8
Dependent Claim
69 words
The method of claim 5 wherein the filler material is heated at a temperature of about from 110° C. to 150° C. for about from 15 minutes to 2 hours prior to its treatment with the surfactant to remove excess water, and the resulting dry filler material is thereafter treated with the surfactant in an amount of about from 0.5% to 10% by weight of the treated filler material.
Claim 9
Dependent Claim
135 words
The method of claim 5 wherein the filler material is heated at a temperature of about from 110° C. to 150° C. for about from 15 minutes to 2 hours prior to its treatment with the surfactant to remove excess water, the resulting dry filler material is then treated with the surfactant in an amount of about from 0.5% to 10% by weight of the treated filler material at the same temperature of about from 110° C. to 150° C., with stirring, for about from 15 minutes to 30 minutes, the organic chemical reagent is thereafter gradually added in an amount ranging from about 1 to 20% by weight of the surfactant, while stirring, at the same temperature of about from 110° C. to 150° C., and, finally, vacuum is applied for about 30 minutes.
Claim 10
Dependent Claim
9 words
The product produced by the method of claim 1.
Claim 11
Dependent Claim
9 words
The product produced by the method of claim 5.
Claim 12
Dependent Claim
47 words
A method for facilitating the dispersion of elastomers and plastomers in a formulation selected from the group consisting of a rubber, a plastic, a paint, and a glue while imparting improved mechanical properties to the final product, comprising incorporating into said formulation the product of claim 9.
Claim 13
Dependent Claim
47 words
The method for facilitating the dispersion of elastomers and plastomers in a formulation selected from the group consisting of a rubber, a plastic, a paint, and a glue while imparting improved mechanical properties to the final product, comprising incorporating into said formulation the product of claim 10.
Claim 14
Dependent Claim
27 words
The process of claim 8 wherein the inorganic filler material is chalk, the surfactant is 1,4 butanediol diglycidic ether, and the organic chemical reagent is phthalic anhydride.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-12-11 | 1982-06-12 | 1982-12-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-12-11 | 1986-06-12 | 1986-12-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-12-11 | 1990-06-12 | 1990-12-12 | $7700.00 | Window Closed / Lapsed |