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US4129489A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of polymer based powder coatings by ionizing radiation

Assignee: PPG Industries Inc
•
Filing: 1978-04-24
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Granted: 1978-12-12
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Expires: 1998-04-24
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Abstract

Abstract A novel method of preparing polymer based powder coating compositions involves as a first step the preparation of a mixture containing one or more ethylenically unsaturated monomers which are polymerizable by ionizing radiation, and optionally other coating composition additives. Optional additives which may be incorporated in the mixture include pigments, internal or external crosslinkers, chain transfer agents, flow promoters, plasticizers, viscosity control agents, minor proportions of resins, and the like. Pigments are especially desirable additives. The next step in the process is to apply a coating of the mixture to a substrate. Then, the coated substrate is subjected to ionizing radiation to polymerize the ethylenically unsaturated monomers and thereby form a solid film. Finally, the film is broken into particles by any of several mechanical means to form a polymer based powder coating composition which when applied to a substrate and baked, fuses to produce a film. This novel and convenient method is particularly suited to the preparation of pigmented and unpigmented thermoplastic or thermosetting acrylic polymer-based powder coating compositions which form films having excellent properties.

Inventors

  • 👤 Roger M. Christenson
  • 👤 Rostyslaw Dowbenko
  • 👤 Joseph M. Makhlouf

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 20:25
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/03; C08; C08F; C08F2/00; C08F2/46; C08F2/54

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 120 words
A method of preparing a polymer based powder coating material which comprises the steps of: (a) preparing a mixture comprising one or more monomers each having substantially no more than one ethylenically unsaturated group, which mixture is polymerizable by means of ionizing radiation to form a thermoplastic, substantially non-crosslinked film; (b) applying a coating of said mixture to a substrate; (c) subjecting the coated substrate to ionizing radiation to polymerize said ethylenically unsaturated monomer or monomers in said coating and to thereby form a solid thermoplastic, substantially non-crosslinked film; and (d) breaking and reducing said film into substantially powder-sized particles of polymer based powder coating composition which when electrostatically deposited upon a substrate and baked, fuse to produce a film.
Claim 2
Independent Claim 120 words
A method of preparing a polymer based powder coating material which comprises the steps of: (a) preparing a mixture comprising one or more monomers each having substantially no more than one ethylenically unsaturated group, which mixture is polymerizable by means of ionizing radiation to form a thermoplastic, substantially non-crosslinked film; (b) applying a coating of said mixture to a substrate; (c) subjecting the coated substrate to ionizing radiation to polymerize said ethylenically unsaturated monomer or monomers in said coating and to thereby form a solid thermoplastic, substantially non-crosslinked film; and (d) breaking and reducing said film into substantially powder-sized particles of polymer based powder coating composition which when electrostatically deposited upon a substrate and baked, fuse to produce a film.
Claim 3
Dependent Claim 18 words
The method of claim 1 wherein said mixture of ethylenically unsaturated monomers is a mixture of acrylic monomers.
Claim 4
Dependent Claim 38 words
The method of claim 2 wherein at least one of the acrylic monomers of the mixture is an acrylic monomer having a hydroxyl, carboxyl, epoxy or amide group and an external crosslinking agent is added to the mixture.
Claim 5
Dependent Claim 18 words
The method of claim 3 wherein said acrylic monomer is a hydroxyalkyl ester of acrylic or methacrylic acid.
Claim 6
Dependent Claim 12 words
The method of claim 4 wherein said acrylic monomer is hydroxyethyl acrylate.
Claim 7
Dependent Claim 14 words
The method of claim 3 wherein said crosslinking agent is a blocked polyisocyanate prepolymer.
Claim 8
Dependent Claim 17 words
The method of claim 6 wherein said blocked polyisocyanate prepolymer is an epsilon-caprolactam blocked, 1,6-hexanediol-isophorone diisocyanate prepolymer.
Claim 9
Dependent Claim 16 words
The method of claim 1 wherein a minor proportion of resin is added to said mixture.
Claim 10
Dependent Claim 24 words
The method of claim 1 wherein pigments, plasticizers, flow promoters, chain transfer agents, viscosity control agents or combinations thereof are added to said mixture.
Claim 11
Dependent Claim 12 words
The method of claim 1 wherein said ionizing radiation is accelerated electrons.
Claim 12
Dependent Claim 19 words
The method of claim 1 wherein the total dosage of irradiation is from about 1 to about 150 megarads.
Claim 13
Dependent Claim 17 words
The method of claim 1 wherein said film is broken by means of scraping, crushing, or pulverizing.

References Cited (Backward Citations)

US2921006A Cited
US2701391A Cited
US3037963B1 Cited
US3037963A Cited
US3912607A Cited
US3770848A Cited
USB417164I5 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-12-11 1982-06-12 1982-12-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-12-11 1986-06-12 1986-12-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-12-11 1990-06-12 1990-12-12 $7700.00 Window Closed / Lapsed

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