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US4129418A Expired / Lapsed US ⏱️ 0.0 years remaining

Discriminating halogen sensor

Assignee: Yokogawa Electric Corp
•
Filing: 1978-02-21
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Granted: 1978-12-12
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Expires: 1998-02-21
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Abstract

Abstract A halogen detector is disclosed herein in which the active alkali metal compound is independently heated thereby permitting the sensor to discriminate between halogen compounds of different thermal stabilities. Certain lesser stable halogen compounds such as Freon 22 and chloroform can be distinguished from more stable halogen compounds such as Freon 12 when such halogen compounds are present in air.

Inventors

  • 👤 William D. Davis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 12:35
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/62; G01N27/626

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 145 words
A discriminating halogen detector comprising: an envelope with an air inlet and an air outlet at substantially opposite ends thereof, said envelope enclosing a source region and an electrode region, said source region being proximal to the air inlet and said electrode region being proximal to the air outlet, said source region internally communicating with said electrode region; an alkali metal compound source contained in said source region; means to independently heat said source region; a heated anode disposed in said electrode region capable of ionizing alkali vapors generated by said alkali metal compound source; and a cathode disposed in said electrode region adjacent to but not contacting said anode, whereby ions generated at the heated anode migrate to said cathode thereby forming a detectable current in an external circuit in response to halogens contained in air passing through the source region of the detector.
Claim 2
Dependent Claim 145 words
A discriminating halogen detector comprising: an envelope with an air inlet and an air outlet at substantially opposite ends thereof, said envelope enclosing a source region and an electrode region, said source region being proximal to the air inlet and said electrode region being proximal to the air outlet, said source region internally communicating with said electrode region; an alkali metal compound source contained in said source region; means to independently heat said source region; a heated anode disposed in said electrode region capable of ionizing alkali vapors generated by said alkali metal compound source; and a cathode disposed in said electrode region adjacent to but not contacting said anode, whereby ions generated at the heated anode migrate to said cathode thereby forming a detectable current in an external circuit in response to halogens contained in air passing through the source region of the detector.
Claim 3
Dependent Claim 32 words
The detector of claim 1 in which the alkali metal compound source is selected from the group consisting of the alkali metal carbonates, the alkali metal silicates and the alkali metal aluminates.
Claim 4
Dependent Claim 23 words
The detector of claim 1 in which the alkali metal compound is selected from the group consisting of sodium carbonate and rubidium carbonate.
Claim 5
Dependent Claim 27 words
The detector of claim 1 in which the independent means to heat said source region operates at a temperature between approximately 500° C. and approximately 600° C.
Claim 6
Dependent Claim 17 words
The detector of claim 1 in which the means to independently heat said source region is adjustable.
Claim 7
Dependent Claim 18 words
The detector of claim 1 in which the anode is heated to a temperature of approximately 1,000° C.
Claim 8
Dependent Claim 39 words
A discriminating halogen detector system comprising: the halogen detector of claim 1; external circuit means to bias said cathode at a negative potential with respect to said anode; and means to detect increases in current in said external circuit.
Claim 9
Dependent Claim 26 words
The detector of claim 1 in which the anode is a filament composed of a material selected from the group consisting of platinum, iridium, and palladium.
Claim 10
Dependent Claim 29 words
The halogen detector system of claim 8 in which the biasing means operates to maintain the said anode and cathode at a potential difference of approximately 180 dc volts.

References Cited (Backward Citations)

US2136741A Cited
US3535088A Cited
US3607096A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-12-11 1982-06-12 1982-12-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-12-11 1986-06-12 1986-12-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-12-11 1990-06-12 1990-12-12 $7700.00 Window Closed / Lapsed

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