US4126587A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Cleaning agents for contact lenses
Assignee: Barnes Hind Pharmaceuticals Inc
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Filing: 1977-03-28
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Granted: 1978-11-21
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Expires: 1997-03-28
Abstract
Abstract Method and compositions are provided for the effective cleaning of soft and silicone contact lenses by soaking the lenses for a time sufficient to remove adherent residues in a solution containing an epoxy modified silicone surfactant and a fatty acid amide (or nitrogen analog thereof) surfactant, which may be cationic or non-ionic. Other additives may also be included such as thickening agents, bactericides, salts, anionic surfactants, and the like. The compositions are found to be particularly effective in removing strongly adhering proteinaceous matter, as well as lipids and polysaccharides. By employing a particular combination of surfactants, soft contact lenses can be freed of impurities and adhering matter introduced during manufacture of the lens, while the lens is being hydrated. The lens is soaked under moderate conditions in an aqueous saline bath with a combination of a zwitterion surfactant and a fatty acid amide surfactant.
Inventors
- 👤 Murray J. Sibley
- 👤 Gordon H. K. Yung
- 👤 Petronio D. Urrea
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 01:48
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3703; C11D3/373; C11D3/3738; C08; C08K; C08K5/00; C08K5/0008; C08K5/0058; C08K5/16; C08K5/20; C08L; C08L1/00; C08L83/00; C08L83/10; C08L83/12; C11D1/00; C11D1/38; C11D1/52; C11D1/523; C11D1/88; C11D1/94; C11D3/0005; C11D3/0078
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
187 words
An aqueous composition useful for the removal of deposits accumulated during the manufacture of soft contact lenses which comprises: a mixture of fatty acid amides of the formula ##STR5## wherein one member of the mixture has m equal to 0, and the other member has m equal to 1, X being oxygen when m is 0 and nitrogen when m is 1, wherein the nitrogen to which Y and z is attached is positive; R is an aliphatic group of from 9 to 13 carbon atoms; Y is an aliphatically saturated group of from 2 to 4 carbon atoms and from 1 to 3 oxygen atoms, the oxygen atoms being present as oxy or non-oxo-carbonyl; and Z is a saturated aliphatic group of from 2 to 3 carbon atoms and 1 to 2 oxygen atoms as oxy or non-oxo-carbonyl, with the proviso that when m is 1, at least one of Y and Z have a non-oxo carbonyl functionality, wherein the weight ratio of the two amides will be 0.5-2:1 and the concentration of each amide will be in the range of 2 to 10 weight %.
Claim 2
Dependent Claim
187 words
An aqueous composition useful for the removal of deposits accumulated during the manufacture of soft contact lenses which comprises: a mixture of fatty acid amides of the formula ##STR5## wherein one member of the mixture has m equal to 0, and the other member has m equal to 1, X being oxygen when m is 0 and nitrogen when m is 1, wherein the nitrogen to which Y and z is attached is positive; R is an aliphatic group of from 9 to 13 carbon atoms; Y is an aliphatically saturated group of from 2 to 4 carbon atoms and from 1 to 3 oxygen atoms, the oxygen atoms being present as oxy or non-oxo-carbonyl; and Z is a saturated aliphatic group of from 2 to 3 carbon atoms and 1 to 2 oxygen atoms as oxy or non-oxo-carbonyl, with the proviso that when m is 1, at least one of Y and Z have a non-oxo carbonyl functionality, wherein the weight ratio of the two amides will be 0.5-2:1 and the concentration of each amide will be in the range of 2 to 10 weight %.
Claim 3
Dependent Claim
11 words
An aqueous composition according to claim 1, diluted from 10-20 fold.
Claim 4
Dependent Claim
41 words
An aqueous composition according to claim 1, wherein from about 20 to 33 mole % of the amide where m is 0 is replaced with a diethanolamine fatty acid salt, said fatty acid being of from 16 to 18 carbon atoms.
Claim 5
Dependent Claim
29 words
An aqueous composition according to claim 3, wherein when m is 0, Y and Z are 2-hydroxyethyl and when m is 1, Y is carboxymethoxyethyl and Z is carboxymethyl.
Claim 6
Dependent Claim
51 words
An aqueous composition useful for the removal of deposits accumulated during the manufacture of soft contact lenses which comprises: a mixture of N,N-di(2-hydroxyethyl) lauramide and 2-undecyl-3-(2'-carboxymethoxyethyl)-3-carboxymethyl-1-imidazoline disodio salt hydroxide in a weight ratio of 0.5-2:1 respectively and at an individual concentration in the range of about 2 to 10 weight percent.
Claim 7
Dependent Claim
51 words
An aqueous composition useful for the removal of deposits accumulated during the manufacture of soft contact lenses which comprises: a mixture of N,N-di(2-hydroxyethyl) lauramide and 2-undecyl-3-(2'-carboxymethoxyethyl)-3-carboxymethyl-1-imidazoline disodio salt hydroxide in a weight ratio of 0.5-2:1 respectively and at an individual concentration in the range of about 2 to 10 weight percent.
Claim 8
Dependent Claim
15 words
An aqueous composition according to claim 5, at a dilution of from 10 to 20-fold.
Claim 9
Dependent Claim
58 words
A method for cleaning and hydrating soft contact lenses after machining soft contact lens blanks, which comprises: immersing said lenses in a solution according to claim 1, at a temperature in the range of about 35° to 75° C. for a time of from about 0.5 to 12 hours and sufficient to hydrate said lenses and remove deposits.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-11-20 | 1982-05-22 | 1982-11-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-11-20 | 1986-05-22 | 1986-11-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-11-20 | 1990-05-22 | 1990-11-21 | $7700.00 | Window Closed / Lapsed |