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US4125480A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for reactivating used silver ethylene oxide catalysts

Assignee: Shell USA Inc
•
Filing: 1977-10-18
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Granted: 1978-11-14
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Expires: 1997-10-18
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Abstract

Abstract The performance of used supported silver-based ethylene oxide catalysts is improved by a) washing the used catalyst with water or a mixture of water with a water-miscible organic solvent and b) depositing on the washed catalyst from about 0.00004 to about 0.008 gram equivalent weights per kilogram of total catalyst of ions of one or more of the alkali metals sodium, potassium, rubidium or cesium.

Inventors

  • 👤 Ian E. Maxwell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 07:48
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/38; B01J23/54; B01J23/66; B01J23/90; B01J23/96; C; C07; C07D; C07D301/00; C07D301/02; C07D301/03; C07D301/04; C07D301/08; C07D301/10; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52; Y02P20/584

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 136 words
A process for improving the performance of used silver-based catalysts used for the production of ethylene oxide by contacting ethylene in the vapor phase with a molecular oxygen-containing gas at a temperature of from about 150°-300° C. which comprises: (a) washing the used catalyst with 1-10 times its volume of water or a mixture of at least ten percent water with a water-miscible organic solvent, and (b) depositing on the washed catalyst from about 0.00004 to about 0.008 gram equivalent weights per kilogram of total catalyst of alkali metal ions selected from the group consisting of sodium, potassium, rubidium, cesium, or mixtures thereof by impregnating the catalyst with a solution of alkali metal ions dissolved in a solvent selected from the group consisting of alkanols having 1 to 6 carbon atoms, acetone methyl acetate and tetrahydrofuran.
Claim 2
Dependent Claim 136 words
A process for improving the performance of used silver-based catalysts used for the production of ethylene oxide by contacting ethylene in the vapor phase with a molecular oxygen-containing gas at a temperature of from about 150°-300° C. which comprises: (a) washing the used catalyst with 1-10 times its volume of water or a mixture of at least ten percent water with a water-miscible organic solvent, and (b) depositing on the washed catalyst from about 0.00004 to about 0.008 gram equivalent weights per kilogram of total catalyst of alkali metal ions selected from the group consisting of sodium, potassium, rubidium, cesium, or mixtures thereof by impregnating the catalyst with a solution of alkali metal ions dissolved in a solvent selected from the group consisting of alkanols having 1 to 6 carbon atoms, acetone methyl acetate and tetrahydrofuran.
Claim 3
Dependent Claim 24 words
The process of claim 1 wherein the water-miscible organic solvent is selected from the group consisting of methanol, ethanol, isopropanol, acetone and mixtures thereof.
Claim 4
Dependent Claim 17 words
The process of claim 1 wherein the solvent is an alkanol having 1 to 6 carbon atoms.
Claim 5
Dependent Claim 10 words
The process of claim 1 wherein the solvent is acetone.
Claim 6
Dependent Claim 31 words
The process of claim 1 wherein the amount of alkali metal deposited on the washed catalyst is between about 0.0001 and about 0.002 gram equivalent weights per kilo of total catalyst.

References Cited (Backward Citations)

US2194602A Cited
US3962136A Cited
US4010115A Cited
US3962136B1 Cited
US4007135A Cited
DE2519599C2 Cited
US4033903A Cited
US4066575A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-11-13 1982-05-15 1982-11-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-11-13 1986-05-15 1986-11-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-11-13 1990-05-15 1990-11-14 $7700.00 Window Closed / Lapsed

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