US4124561A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Reinforced thermoplastic polyester compositions having improved shatter resistance
Assignee: General Electric Co
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Filing: 1976-12-06
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Granted: 1978-11-07
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Expires: 1996-12-06
Abstract
Abstract Reinforced thermoplastic compositions are provided which comprise a high molecular weight polyester and a mineral reinforcing filler comprising mica, talc or mixtures thereof in combination with a glass fiber reinforcement. The use of glass fibers together with the mineral reinforcement provides shatter resistance and further enhances other physical properties, such as tensile strength, modulus, impact strength and heat distortion temperature. Self-extinguishing embodiments are also disclosed.
Inventors
- 👤 Donald L. Phipps, Jr.
- 👤 Allen D. Wambach
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 00:20
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34; C08K3/01; C08K3/013; C08K7/00; C08K7/02; C08K7/04; C08K7/14
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
89 words
A reinforced, shatter-resistant thermoplastic composition comprising: (a) a high molecular weight polyester resin; and (b) a reinforcing agent therefor comprising (i) a mineral reinforcing filler comprising mica, talc or a mixture thereof, and in combination therewith (ii) glass fibers, said reinforcing agent (b) being present in an amount at least sufficient to reinforce the composition and said glass fibers (b)(ii) being present in an amount at least sufficient to provide improved shatter resistance in comparison with a corresponding composition wherein the reinforcing material consists essentially of said mineral filler.
Claim 2
Dependent Claim
89 words
A reinforced, shatter-resistant thermoplastic composition comprising: (a) a high molecular weight polyester resin; and (b) a reinforcing agent therefor comprising (i) a mineral reinforcing filler comprising mica, talc or a mixture thereof, and in combination therewith (ii) glass fibers, said reinforcing agent (b) being present in an amount at least sufficient to reinforce the composition and said glass fibers (b)(ii) being present in an amount at least sufficient to provide improved shatter resistance in comparison with a corresponding composition wherein the reinforcing material consists essentially of said mineral filler.
Claim 3
Dependent Claim
46 words
A composition as defined in claim 1 wherein reinforcing agent (b) comprises from about 5 to about 60%. by weight of a mineral reinforcing filler and from about 2 to about 60% by weight of glass fibers, based on the combined weights of (a) and (b).
Claim 4
Dependent Claim
53 words
A composition as defined in claim 2 wherein the mineral reinforcing filler is present in an amount of from about 10 to about 50% by weight and the glass fibers are present in an amount of from about 5 to about 50% by weight based on the combined weights of (a) and (b).
Claim 5
Dependent Claim
38 words
A composition as defined in claim 1 wherein said polyester has an intrinsic viscosity of at least about 0.4 deciliters per gram when measured in a solution in a 60:40 mixture of phenol and trichloroethane at 30° C.
Claim 6
Dependent Claim
35 words
A composition as defined in claim 6 wherein said polyester has an intrinsic viscosity of at least about 0.7 deciliters per gram when measured in a solution in a 60:40 mixture of phenol and trichloroethane.
Claim 7
Dependent Claim
46 words
A composition as defined in claim 1 wherein said polyester is selected from the group consisting of polymeric glycol terephthalate and isophthalate esters having repeating units of the formula: ##STR3## wherein n is a whole number of from two to four, and mixtures of such esters.
Claim 8
Dependent Claim
13 words
A composition as defined in claim 6 wherein said polyester is poly(1,4-butylene terephthalate).
Claim 9
Dependent Claim
14 words
A composition as defined in claim 1 wherein the mineral reinforcement (b)(i) is mica.
Claim 10
Dependent Claim
14 words
A composition as defined in claim 1 wherein the mineral reinforcement (b)(i) is talc.
Claim 11
Dependent Claim
18 words
A composition as defined in claim 1 which includes a flame retardant amount of a flame retardant agent.
Claim 12
Dependent Claim
79 words
A reinforced, shatter-resistant thermoplastic composition comprising: (a) a high molecular weight polyester resin; and (b) a reinforcing agent therefor comprising (i) mica and in combination therewith (ii) glass fibers, said reinforcing agent (b) being present in an amount at least sufficient to reinforce the composition and said glass fibers (b)(ii) being present in an amount at least sufficient to provide improved shatter resistance in comparison with a corresponding composition wherein the reinforcing material consists essentially of said mineral filler.
Claim 13
Dependent Claim
79 words
A reinforced, shatter-resistant thermoplastic composition comprising: (a) a high molecular weight polyester resin; and (b) a reinforcing agent therefor comprising (i) mica and in combination therewith (ii) glass fibers, said reinforcing agent (b) being present in an amount at least sufficient to reinforce the composition and said glass fibers (b)(ii) being present in an amount at least sufficient to provide improved shatter resistance in comparison with a corresponding composition wherein the reinforcing material consists essentially of said mineral filler.
Claim 14
Dependent Claim
43 words
A composition as defined in claim 11 wherein reinforcing agent (b) comprises from about 5 to about 60% by weight of mica and from about 2 to about 60% by weight of glass fibers, based on the combined weights of (a) and (b).
Claim 15
Dependent Claim
51 words
A composition as defined in claim 12 wherein the mica is present in an amount of from about 10 to about 50% by weight and the glass fibers are present in an amount of from about 5 to about 50% by weight based on the combined weights of (a) and (b).
Claim 16
Dependent Claim
38 words
A composition as defined in claim 11 wherein said polyester has an intrisic viscosity of at least about 0.4 deciliters per gram when measured in a solution in a 60:40 mixture of phenol and trichloroethane at 30° C.
Claim 17
Dependent Claim
35 words
A composition as defined in claim 11 wherein said polyester has an intrinsic viscosity of at least about 0.7 deciliters per gram when measured in a solution in a 60:40 mixture of phenol and trichloroethane.
Claim 18
Dependent Claim
46 words
A composition as defined in claim 11 wherein said polyester is selected from the group consisting of polymeric glycol terephthalate and isophthalate esters having repeating units of the formula: ##STR4## wherein n is a whole number of from two to four, and mixtures of such esters.
Claim 19
Dependent Claim
13 words
A composition as defined in claim 16 wherein said polyester is poly(1,4-butylene terephthalate).
Claim 20
Dependent Claim
18 words
A composition as defined in claim 11 which includes a flame retardant amount of a flame retardant agent.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-11-06 | 1982-05-08 | 1982-11-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-11-06 | 1986-05-08 | 1986-11-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-11-06 | 1990-05-08 | 1990-11-07 | $7700.00 | Window Closed / Lapsed |