US4124471A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Controlling silica sol particle size
Assignee: Diamond Shamrock Corp
•
Filing: 1977-08-22
•
Granted: 1978-11-07
•
Expires: 1997-08-22
Abstract
Abstract A novel method of controlling electrodialytically produced silica sol particle size and concentration comprising effecting electrodialysis of an alkali metal silicate anolyte in an electrodialysis cell with a cation permselective membrane separating the anolyte and the catholyte while adding alkali metal silicate solution to the anolyte to maintain the desired pH whereby a silica sol with increasing particle size is formed and when the silica sol has reached the desired particle size, continuing electrodialysis with addition of an alkali metal hydroxide solution to control the pH until the silica sol has the desired concentration.
Inventors
- 👤 Donald F. Lieb
- 👤 Thomas T. Sugano
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 01:26
CPC Classifications
C; C01; C01B; C01B33/00; C01B33/113; C01B33/12; C01B33/14; C01B33/141; B; B01; B01D; B01D61/00; B01D61/42; B01D61/44; B01D2311/00; B01D2311/18
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
165 words
A process for controlling electrodialytically produced silica sol particle size within the range of 10 to 50 millimicrons and the concentration to within about 5 to about 50 weight percent comprising: providing an anolyte having a plurality of glass beads which are fluidized and impinge on the anode so as to substantially prevent the deposition of silica thereon; effecting electrodialysis of an alkali metal silicate anolyte in an electrodialysis cell with a cation permselective membrane separting the anolyte and the catholyte; adding alkali metal silicate solution to the anolyte to maintain the pH within the range of from about 7.5 to about 8.5 whereby a silica sol with increasing particle size is formed; and when the silica sol has reached the desired particle size in the range of 10 to 50 millimicrons, continuing electrodialysis with addition of an alkali metal hydroxide solution to control the pH until the silica sol has the desired concentration within the range of about 5 to about 50 weight percent.
Claim 2
Dependent Claim
165 words
A process for controlling electrodialytically produced silica sol particle size within the range of 10 to 50 millimicrons and the concentration to within about 5 to about 50 weight percent comprising: providing an anolyte having a plurality of glass beads which are fluidized and impinge on the anode so as to substantially prevent the deposition of silica thereon; effecting electrodialysis of an alkali metal silicate anolyte in an electrodialysis cell with a cation permselective membrane separting the anolyte and the catholyte; adding alkali metal silicate solution to the anolyte to maintain the pH within the range of from about 7.5 to about 8.5 whereby a silica sol with increasing particle size is formed; and when the silica sol has reached the desired particle size in the range of 10 to 50 millimicrons, continuing electrodialysis with addition of an alkali metal hydroxide solution to control the pH until the silica sol has the desired concentration within the range of about 5 to about 50 weight percent.
Claim 3
Dependent Claim
13 words
The process of claim 1 wherein said alkali metal silicate is sodium silicate.
Claim 4
Dependent Claim
19 words
The process of claim 1 wherein the anolyte is maintained at a temperature of at least about 60° C.
Claim 5
Dependent Claim
33 words
The process of claim 1 wherein during electrodialysis a portion of the anolyte is removed and a portion of the anolyte which has been previously removed is returned thereto in a continuous manner.
Claim 6
Dependent Claim
17 words
The process of claim 1 wherein the pH is maintained in the range of 8.0 to 8.2.
Claim 7
Dependent Claim
11 words
The process of claim 1 wherein sodium hydroxide is the catholyte.
Claim 8
Dependent Claim
14 words
The process of claim 1 wherein the particle size is 20 to 30 millimicrons.
Claim 9
Dependent Claim
18 words
A stable silica sol with a substantially uniform particle size distribution produced by the process of claim 1.
Claim 10
Dependent Claim
15 words
A silica sol of claim 8 wherein the particle size is 20 to 30 millimicrons.
Claim 11
Dependent Claim
10 words
A silica sol of claim 8 which is sodium silicate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-11-06 | 1982-05-08 | 1982-11-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-11-06 | 1986-05-08 | 1986-11-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-11-06 | 1990-05-08 | 1990-11-07 | $7700.00 | Window Closed / Lapsed |