← Back to Patent Explorer
US4119608A Expired / Lapsed US ⏱️ 0.0 years remaining

Solutions of polyester-imides

Assignee: SI Group Inc
•
Filing: 1977-02-22
•
Granted: 1978-10-10
•
Expires: 1997-02-22
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Polyester-imide resins are prepared which are soluble in non-phenolic solvents by incorporating a monoether of a diethylene glycol or triethylene glycol into the resin.

Inventors

  • 👤 John T. Keating

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 18:29
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/16; H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/303; H01B3/306; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/294

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 190 words
A polyester-polyimide having a hydroxy to carboxyl ratio of 1.25:1 to 2:1, 95 to 50% ester groups, 5 to 50% imide groups, the polyimide being an imide of reactants comprising a diamine and trimellitic anhydride, the polyester being an ester of isophthalic acid or terephthalic acid with up to 10% of an alkane dicarboxylic acid having 6 to 10 carbon atoms with alcohols wherein 5 to 45% of the hydroxyl groups are contributed by (I) an ether-alcohol which either (a) has the formula RO(C n H 2n O) x H where R is an alkyl group of 1 to 6 carbon atoms or phenyl, n is 2 or 3 and x is 2 or 3 or (b) is the monophenyl ether of ethylene glycol, (II) at least 20% of the hydroxyl group are contributed by a trihydric alcohol and (III) any balance of hydroxyl groups are contributed by a dihydric alcohol, said polyester-polyimide having a sufficiently low molecular weight that it is soluble in a mono lower alkyl ether of diethylene glycol alone or in the monophenyl ether of diethylene glycol or phenoxyethanol or a mixture of said phenyl ethers.
Claim 2
Dependent Claim 190 words
A polyester-polyimide having a hydroxy to carboxyl ratio of 1.25:1 to 2:1, 95 to 50% ester groups, 5 to 50% imide groups, the polyimide being an imide of reactants comprising a diamine and trimellitic anhydride, the polyester being an ester of isophthalic acid or terephthalic acid with up to 10% of an alkane dicarboxylic acid having 6 to 10 carbon atoms with alcohols wherein 5 to 45% of the hydroxyl groups are contributed by (I) an ether-alcohol which either (a) has the formula RO(C n H 2n O) x H where R is an alkyl group of 1 to 6 carbon atoms or phenyl, n is 2 or 3 and x is 2 or 3 or (b) is the monophenyl ether of ethylene glycol, (II) at least 20% of the hydroxyl group are contributed by a trihydric alcohol and (III) any balance of hydroxyl groups are contributed by a dihydric alcohol, said polyester-polyimide having a sufficiently low molecular weight that it is soluble in a mono lower alkyl ether of diethylene glycol alone or in the monophenyl ether of diethylene glycol or phenoxyethanol or a mixture of said phenyl ethers.
Claim 3
Dependent Claim 34 words
A polyester-polyimide according to claim 1 wherein R is alkyl of 1 to 4 carbon atoms or phenyl, the trihydric alcohol is tris(2-hydroxyethyl)isocyanurate glycerine, trimethylolpropane or trimethylolethane and the diamine is an aromatic diamine.
Claim 4
Dependent Claim 21 words
A polyester-polyimide according to claim 2 wherein any dihydric alcohol present is an alkane diol having 2 to 8 carbon atoms.
Claim 5
Dependent Claim 16 words
A polyester-polyimide according to claim 3 wherein the diamine is methylene dianiline, tolylene diamine or oxydianiline.
Claim 6
Dependent Claim 18 words
A polyester-polyimide according to claim 4 wherein the diamine is methylene dianiline, the dicarboxylic acid is terephthalic acid.
Claim 7
Dependent Claim 14 words
A polyester-polyimide according to claim 5 having a molecular weight of 500 to 1500.
Claim 8
Dependent Claim 14 words
A polyester-polyimide according to claim 6 having a molecular weight of 550 to 1200.
Claim 9
Dependent Claim 17 words
A polyester-polyimide according to claim 5 wherein (I) comprises methoxyethoxyethanol, ethoxyethoxyethanol, butoxyethoxyethanol, methoxypropoxypropanol, methoxypropoxypropoxypropanol, phenoxyethanol or phenoxyethoxyethanol.
Claim 10
Dependent Claim 13 words
A polyester-polyimide according to claim 8 wherein the trihydric alcohol is tris(2-hydroxyethyl) isocyanurate.
Claim 11
Dependent Claim 11 words
A polyester-polyimide according to claim 9 which has no component (III).
Claim 12
Dependent Claim 22 words
A polyester-polyimide according to claim 9 wherein component (III) is present in an amount of at least 10% and is ethylene glycol.
Claim 13
Dependent Claim 15 words
A polyester-polyimide according to claim 8 wherein the trihydric alcohol is glycerine or trimethylol propane.
Claim 14
Dependent Claim 10 words
A polyester-polyimide according to claim 8 wherein (I) is methoxyethoxyethanol.
Claim 15
Dependent Claim 18 words
A polyester-polyimide according to claim 13 wherein 5 to 30% of the hydroxyl groups are contributed by (I).
Claim 16
Dependent Claim 18 words
A polyester-polyimide according to claim 14 wherein 5 to 12% of the hydroxyl groups are contributed by (I).
Claim 17
Dependent Claim 18 words
A polyester-polyimide according to claim 4 wherein 5 to 30% of the hydroxyl groups are contributed by (I).
Claim 18
Dependent Claim 16 words
A polyester-polyimide according to claim 1 wherein (II) contributes at least 30% of the hydroxyl groups.
Claim 19
Dependent Claim 16 words
A polyester-polyimide according to claim 17 wherein the hydroxy to carboxyl ratio is 1.8:1 to 2:1.
Claim 20
Dependent Claim 10 words
A polyester-polyimide according to claim 1 where (I) is ethoxyethoxyethanol.
Claim 21
Dependent Claim 10 words
A polyester-polyimide according to claim 1 where (I) is butoxyethoxyethanol.
Claim 22
Dependent Claim 10 words
A polyester-polyimide according to claim 1 where (I) is methoxypropoxypropanol.
Claim 23
Dependent Claim 10 words
A polyester-polyimide according to claim 1 where (I) is methoxypropoxypropanol.
Claim 24
Dependent Claim 10 words
A polyester-polyimide according to claim 1 wherein (I) is methoxypropoxypropoxypropanol.
Claim 25
Dependent Claim 10 words
A polyester-polyimide according to claim 1 wherein (I) comprises phenoxyethanol.
Claim 26
Dependent Claim 10 words
A polyester-polyimide according to claim 1 wherein (I) comprises phenoxyethoxyethanol.

References Cited (Backward Citations)

US3929714A Cited
US3382203A Cited
US3676403A Cited
US3853817A Cited
JPS50150737A Cited
JPS5116342A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-10-09 1982-04-10 1982-10-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-10-09 1986-04-10 1986-10-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-10-09 1990-04-10 1990-10-10 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag