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US4119607A Expired / Lapsed US ⏱️ 0.0 years remaining

Multicomponent polyester- block copolymer- polymer blends

Assignee: Shell USA Inc
•
Filing: 1978-03-07
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Granted: 1978-10-10
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Expires: 1998-03-07
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Abstract

Abstract A multicomponent polymer blend composition is prepared by intimately mixing a thermoplastic polyester, a selectively hydrogenated monoalkenyl arene-diene block copolymer, and at least one dissimilar engineering thermoplastic resin under such conditions that at least two of the polymers form at least partial continuous network phases which interlock with the other polymer networks and therefore results in a desirable balance of properties. These blends have an unobviously high heat distortion temperature relative to the improved impact strength.

Inventors

  • 👤 William P. Gergen
  • 👤 Sol Davison

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 21:05
CPC Classifications
C; C08; C08L; C08L53/00; C08L53/02; C08L53/025; C08L101/00; C08L67/00

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 236 words
A composition comprising the admixture obtained by intimately mixing about 4 to about 40 parts by weight of a block copolymer, about 5 to about 48 parts by weight of at least one dissimilar engineering thermoplastic, and a saturated thermoplastic polyester in a weight ratio of polyester to dissimilar engineering thermoplastic of greater than 1:1, so as to form a polyblend wherein at least two of the polymers have at least partial continuous interlocked networks with each other and wherein: (a) said block copolymer comprises at least two monoalkenyl arene polymer end blocks A and at least one substantially completely hydrogenated conjugated diene polymer mid block B, said block copolymer having an 8 to 55 percent by weight monoalkenyl arene polymer block content, each polymer block A having an average molecular weight of between about 5,000 and about 125,000, and each polymer block B having an average molecular weight of between about 10,000 and about 300,000; (b) said thermoplastic polyester has a molecular weight in excess of about 20,000, a generally crystalline structure, a melting point over about 120° C. and is selected from the group consisting of (i) the condensation product of a dicarboxylic acid and a glycol, (ii) polypivalolactone, and (iii) polycaprolactone; and (c) said dissimilar engineering thermoplastic resin is capable of forming a continuous structure and is selected from the group consisting of polyamides, polyolefins, thermoplastic polyurethanes, halogenated thermoplastics, and nitrile barrier resins.
Claim 2
Dependent Claim 236 words
A composition comprising the admixture obtained by intimately mixing about 4 to about 40 parts by weight of a block copolymer, about 5 to about 48 parts by weight of at least one dissimilar engineering thermoplastic, and a saturated thermoplastic polyester in a weight ratio of polyester to dissimilar engineering thermoplastic of greater than 1:1, so as to form a polyblend wherein at least two of the polymers have at least partial continuous interlocked networks with each other and wherein: (a) said block copolymer comprises at least two monoalkenyl arene polymer end blocks A and at least one substantially completely hydrogenated conjugated diene polymer mid block B, said block copolymer having an 8 to 55 percent by weight monoalkenyl arene polymer block content, each polymer block A having an average molecular weight of between about 5,000 and about 125,000, and each polymer block B having an average molecular weight of between about 10,000 and about 300,000; (b) said thermoplastic polyester has a molecular weight in excess of about 20,000, a generally crystalline structure, a melting point over about 120° C. and is selected from the group consisting of (i) the condensation product of a dicarboxylic acid and a glycol, (ii) polypivalolactone, and (iii) polycaprolactone; and (c) said dissimilar engineering thermoplastic resin is capable of forming a continuous structure and is selected from the group consisting of polyamides, polyolefins, thermoplastic polyurethanes, halogenated thermoplastics, and nitrile barrier resins.
Claim 3
Dependent Claim 26 words
A composition according to claim 1 wherein said block copolymer monoalkenyl arene is styrene and said block copolymer conjugated diene is selected from isoprene and butadiene.
Claim 4
Dependent Claim 15 words
A composition according to claim 1 wherein said block copolymer has an ABA linear structure.
Claim 5
Dependent Claim 14 words
A composition according to claim 1 wherein said block copolymer has a branched structure.
Claim 6
Dependent Claim 32 words
A composition according to claim 3 wherein said block copolymer is a selectively hydrogenated block copolymer of styrene and butadiene, said butadiene having a 1,2 content of between about 35% and 55%.
Claim 7
Dependent Claim 20 words
A composition according to claim 1 wherein said thermoplastic polyester is prepared by condensing a dicarboxylic acid with a glycol.
Claim 8
Dependent Claim 13 words
A composition according to claim 6 wherein said thermoplastic polyester is poly(butylene terephthalate).
Claim 9
Dependent Claim 12 words
A composition according to claim 1 wherein said thermoplastic polyester is polypivalolactone.
Claim 10
Dependent Claim 12 words
A composition according to claim 1 wherein said thermoplastic polyester is polycaprolactone.
Claim 11
Dependent Claim 22 words
A composition according to claim 1 wherein said thermoplastic polyester has the generalized formula: ##STR22## wherein n varies from 70 to 140.
Claim 12
Dependent Claim 14 words
A composition according to claim 1 wherein said dissimilar engineering thermoplastic is a polyolefin.
Claim 13
Dependent Claim 13 words
A composition according to claim 1 wherein said polyolefin is essentially isotactic polypropylene.
Claim 14
Dependent Claim 18 words
A composition according to claim 1 which contains about 2 to about 80 percent by weight glass fibers.
Claim 15
Dependent Claim 24 words
A composition according to claim 1 wherein the block copolymer, thermoplastic polyester, and dissimilar engineering thermoplastic are melt blended under essentially isoviscous blending conditions.
Claim 16
Dependent Claim 43 words
A composition according to claim 14 wherein the viscosity ratio of the viscosity of the block copolymer divided by the viscosity of the thermoplastic polyester, dissimilar engineering thermoplastic, or mixture thereof is between about 0.2 and about 4.0 at the processing temperature Tp.
Claim 17
Dependent Claim 17 words
A composition according to claim 15 wherein said viscosity ratio is between about 0.8 and about 1.2.
Claim 18
Dependent Claim 20 words
A composition according to claim 15 wherein said processing temperature Tp is between about 150° C. and about 400° C.
Claim 19
Dependent Claim 28 words
A composition according to claim 1 wherein said dissimilar engineering thermoplastic is a polyamide selected from the group consisting of nylon 6, 6/6, 11, 12, 6/3 and 6/12.
Claim 20
Dependent Claim 14 words
A composition according to claim 1 wherein said dissimilar engineering thermoplastic is poly(vinylidene fluoride).

References Cited (Backward Citations)

US3562355A Cited
US3646162A Cited
US3975460A Cited
US4039629A Cited
US4006116A Cited
US4041103A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-10-09 1982-04-10 1982-10-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-10-09 1986-04-10 1986-10-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-10-09 1990-04-10 1990-10-10 $7700.00 Window Closed / Lapsed

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