Lubricant additive

Claim 2

A boronated product useful as a lubricating oil dispersant made by reacting an initial compound having the formula: ##STR17## wherein: (a) each R 3 is the same or different and is a hydrogen atom, an alkyl group containing from 1 to about 16 carbon atoms, a halogen atom, or one R 3 group in the ortho position relative to the oxygen atom is a group of the formula: ##STR18## in which (i) n is an integer from 1 to 6, (ii) each Z is the same or different and is a methylene group or a sulfur chain of formula -S) m wherein m is from 1 to 4, (iii) each R 4 is the same or different and is a hydrogen atom, an alkyl group containing from 1 to 16 carbon atoms, a halogen atom, a hydroxyl group or a group of formula ##STR19## (iv) each R 5 is the same or different and is a hydrogen atom, an alkyl group containing from 1 to 16 carbon atoms, a halogen atom, or a hydroxyl group, provided that one of, but not more than one of, R 4 and R 5 is a hydroxyl group, (v) each R 6 is the same or different and is a hydrogen atom, an alkyl group containing 1 to 29 carbon atoms, a halogen atom or is as R 2 , provided that one group R 3 in the ortho position relative to the oxygen atom attached to the aromatic nucleus is a hydrogen, a halogen, or a methyl or ethyl group, (b) each R is the same or different and is a straight or branched chain alkylene group containing from 1 to 20 carbon atoms, (c) each R 1 is the same or different and is a hydrogen atom or the ester residue of an alkanol containing from 1 to 5 carbon atoms, and (d) each R 2 is the same or different and is an alkyl group containing at least 30 carbon atoms; with about 0.5 to 10 equivalents per mole of said initial compound of an amine containing a reactive hydrogen atom bonded to nitrogen to form an amide and reacting said amide with a boron compound capable of introducing boron into the molecule, said boron compound being selected from the group consisting of boron acids, salts of boron acids, esters of boron acids, boron oxides, boron halides and boron salts of oxygen acids, to obtain a boronated product containing at least 0.01 atoms of boron per nitrogen atom.

Claim 3

A boronated product of claim 1 wherein R 3 is a hydrogen atom.

Claim 4

A boronated product of claim 2 wherein R is a methylene group.

Claim 5

A boronated product of claim 3 wherein R 2 is a polyolefin group containing 50-200 carbon atoms.

Claim 6

A boronated product of claim 4 wherein R 1 is the ester residue of an alkanol containing 1 to 5 carbon atoms.

Claim 7

A boronated product of claim 4 wherein said amine is an alkylene polyamine.

Claim 8

A boronated product of claim 5 wherein said amine is an alkylene polyamine.

Claim 9

A boronated product of claim 6 wherein said boron compound is a boron acid.

Claim 10

A boronated product of claim 7 wherein said boron compound is a boron acid.

Claim 11

A boronated product of claim 9 wherein said boron acid is a boric acid.

Claim 12

A process for making a boronated lubricating oil additive, said process comprising reacting an initial compound having the formula: ##STR20## wherein: (a) each R 3 is the same or different and is a hydrogen atom, an alkyl group containing from 1 to about 16 carbon atoms, a halogen atom, or one R 3 group in the ortho position relative to the oxygen atom is a group of the formula: ##STR21## in which (i) n is an integer from 1 to 6, (ii) each Z is the same or different and is a methylene group or a sulfur chain of formula -S) m wherein m is from 1 to 4, (iii) each R 4 is the same or different and is a hydrogen atom, an alkyl group containing from 1 to 16 carbon atoms, a halogen atom, a hydroxyl group or a group of formula ##STR22## (iv) each R 5 is the same or different and is a hydrogen atom, an alkyl group containing from 1 to 16 carbon atoms, a halogen atom, or a hydroxyl group, provided that one of, but not more than one of, R 4 and R 5 is a hydroxyl group, (v) each R 6 is the same or different and is a hydrogen atom, an alkyl group containing 1 to 29 carbon atoms, a halogen atom or is as R 2 , provided that one group R 3 in the ortho position relative to the oxygen atom attached to the aromatic nucleus is a hydrogen, a halogen, or a methyl or ethyl group, (b) each R is the same or different and is a straight or branched chain alkylene group containing from 1 to 20 carbon atoms, (c) each R 1 is the same or different and is a hydrogen atom or the ester residue of an alkanol containing from 1 to 5 carbon atoms, and (d) each R 2 is the same or different and is an alkyl group containing at least 30 carbon atoms; with about 0.5 to 10 equivalents per mole of said initial compound of an amine containing a reactive hydrogen atom bonded to nitrogen to form an amide and reacting said amide with a boron compound capable of introducing boron into the molecule, said boron compound being selected from the group consisting of boron acids, salts of boron acids, esters of boron acids, boron oxides, boron halides and boron salts of oxygen acids, to obtain a boronated product containing at least 0.01 atoms of boron per nitrogen atom.

Claim 13

A process for making a boronated lubricating oil additive, said process comprising reacting an initial compound having the formula: ##STR20## wherein: (a) each R 3 is the same or different and is a hydrogen atom, an alkyl group containing from 1 to about 16 carbon atoms, a halogen atom, or one R 3 group in the ortho position relative to the oxygen atom is a group of the formula: ##STR21## in which (i) n is an integer from 1 to 6, (ii) each Z is the same or different and is a methylene group or a sulfur chain of formula -S) m wherein m is from 1 to 4, (iii) each R 4 is the same or different and is a hydrogen atom, an alkyl group containing from 1 to 16 carbon atoms, a halogen atom, a hydroxyl group or a group of formula ##STR22## (iv) each R 5 is the same or different and is a hydrogen atom, an alkyl group containing from 1 to 16 carbon atoms, a halogen atom, or a hydroxyl group, provided that one of, but not more than one of, R 4 and R 5 is a hydroxyl group, (v) each R 6 is the same or different and is a hydrogen atom, an alkyl group containing 1 to 29 carbon atoms, a halogen atom or is as R 2 , provided that one group R 3 in the ortho position relative to the oxygen atom attached to the aromatic nucleus is a hydrogen, a halogen, or a methyl or ethyl group, (b) each R is the same or different and is a straight or branched chain alkylene group containing from 1 to 20 carbon atoms, (c) each R 1 is the same or different and is a hydrogen atom or the ester residue of an alkanol containing from 1 to 5 carbon atoms, and (d) each R 2 is the same or different and is an alkyl group containing at least 30 carbon atoms; with about 0.5 to 10 equivalents per mole of said initial compound of an amine containing a reactive hydrogen atom bonded to nitrogen to form an amide and reacting said amide with a boron compound capable of introducing boron into the molecule, said boron compound being selected from the group consisting of boron acids, salts of boron acids, esters of boron acids, boron oxides, boron halides and boron salts of oxygen acids, to obtain a boronated product containing at least 0.01 atoms of boron per nitrogen atom.

Claim 14

A process of claim 11 wherein R 3 is a hydrogen atom.

Claim 15

A process of claim 12 wherein R is a methylene group.

Claim 16

A process of claim 13 wherein R 2 is a polyolefin group containing 50-200 carbon atoms.

Claim 17

A process of claim 14 wherein R 1 is the ester residue of an alkanol containing 1 to 5 carbon atoms.

Claim 18

A process of claim 14 wherein said amine is an alkylene polyamine.

Claim 19

A process of claim 15 wherein said amine is an alkylene polyamine.

Claim 20

A process of claim 16 wherein said boron compound is a boron acid.

Claim 21

A process of claim 17 wherein said boron compound is a boron acid.

Claim 22

A process of claim 19 wherein said boron acid is boric acid.

Claim 23

A lubricating oil composition comprising a major amount of lubricating oil containing a dispersant amount of a boronated product of claim 1.

Claim 24

An additive concentrate which when added to lubricating oils will impart a balance of desirable properties to said lube oil, said concentration comprising about 15-50% diluent oil and about 5-75% boronated product of claim 1.