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US4118552A Expired / Lapsed US ⏱️ 0.0 years remaining

Self-supporting electrode and method of making same

Assignee: Whittaker Technical Products Inc
•
Filing: 1978-01-05
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Granted: 1978-10-03
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Expires: 1998-01-05
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Abstract

Abstract The improved self-supporting electrode of the present invention comprises a uniform mixture of cuprous chloride, preferably in major proportion and silver chloride, preferably in minor proportion. The electrode may also include a minor proportion of copper metal uniformly dispersed therein. The electrode is primarily used as a cathode, particularly in cells employing sea water as the electrolyte. The cathode preferably is formed by mixing the ingredients together and melting at least the cuprous chloride and silver chloride of the mixture and then casting the mixture and solidifying it so as to cause it to adhere to a current collector such as expanded copper metal. The current collector preferably is at or near the surface of the electrode and helps to support the electrode. The electrode is less expensive than one fabricated solely of silver chloride and yet is more resistant to degradation by humidity and has better electrical properties than conventional cuprous chloride electrodes.

Inventors

  • 👤 Roland F. Chireau
  • 👤 Aldo S. Berchielli

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 04:45
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/36; H01M4/58; H01M4/582; H01M4/06

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 30 words
An improved self-supporting electrode, said electrode comprising a substantially uniform cast, solidified mixture of a major proportion by weight of cuprous chloride and a minor proportion by weight silver chloride.
Claim 2
Dependent Claim 30 words
An improved self-supporting electrode, said electrode comprising a substantially uniform cast, solidified mixture of a major proportion by weight of cuprous chloride and a minor proportion by weight silver chloride.
Claim 3
Dependent Claim 16 words
The improved electrode of claim 1 wherein said electrode includes a minor proportion of copper metal.
Claim 4
Dependent Claim 24 words
The improved electrode of claim 2 wherein said silver chloride is present in said mixture in a concentration of about 1-5 percent by weight.
Claim 5
Dependent Claim 24 words
The improved electrode of claim 2 wherein said copper metal is present in said mixture in a concentration of about 1-10 percent by weight.
Claim 6
Dependent Claim 27 words
The improved electrode of claim 2 wherein said electrode is a cathode and wherein said mixture consists essentially of said cuprous chloride, silver chloride and copper metal.
Claim 7
Dependent Claim 17 words
The improved electrode of claim 2 wherein said electrode includes a current collector adherent to said mixture.
Claim 8
Dependent Claim 14 words
The improved electrode of claim 6 wherein said current collector comprises expanded copper metal.
Claim 9
Dependent Claim 30 words
The improved electrode of claim 6 wherein said mixture has been melted, cast and solidified in association with said collector so as to adhere strongly thereto and be supported thereby.
Claim 10
Dependent Claim 22 words
The improved electrode of claim 8 wherein at least a portion of said collector is exposed on the exterior of said electrode.
Claim 11
Independent Claim 65 words
A method of making an improved supporting electrode, which method comprises: a. forming a mixture comprising a major proportion by weight of cuprous chloride and a minor proportion by weight of silver chloride; b. heating said mixture to a temperature at least sufficient to melt said cuprous chloride and silver chloride; c. casting the resultant molten mixture and solidifying the same to a self-supporting electrode.
Claim 12
Independent Claim 65 words
A method of making an improved supporting electrode, which method comprises: a. forming a mixture comprising a major proportion by weight of cuprous chloride and a minor proportion by weight of silver chloride; b. heating said mixture to a temperature at least sufficient to melt said cuprous chloride and silver chloride; c. casting the resultant molten mixture and solidifying the same to a self-supporting electrode.
Claim 13
Dependent Claim 31 words
The improved method of claim 10 wherein a minor proportion of copper metal is present in said mixture and wherein said temperature is insufficient to boil constituents of said mixture therefrom.
Claim 14
Dependent Claim 41 words
The method of claim 11 wherein said temperature is between about 455° C. and about 475° C. so that said copper is not melted in said molten mixture, said copper being present in said molten mixture in uniformly dispersed particulate form.
Claim 15
Dependent Claim 29 words
The method of claim 11 wherein said solidifying of said mixture is carried out in the presence of a current collector so that said mixture, when solidified, adheres thereto.
Claim 16
Dependent Claim 38 words
The method of claim 13 wherein said current collector comprises expanded copper metal and wherein said casting and solidification are effected such that at least a portion of said collector is exposed on the exterior of said electrode.
Claim 17
Dependent Claim 42 words
The method of claim 14 wherein said silver chloride is present in said mixture in a concentration of about 1-5 percent by weight and wherein said copper metal is present in said mixture in a concentration of about 1-10 percent by weight.

References Cited (Backward Citations)

US2636060A Cited
US3445290A Cited
US3591464A Cited
JPS4826502A Cited
JPS499339A Cited
US3824170A Cited
US3959012A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-10-02 1982-04-03 1982-10-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-10-02 1986-04-03 1986-10-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-10-02 1990-04-03 1990-10-03 $7700.00 Window Closed / Lapsed

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