US4118464A
Expired / Lapsed
US
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Process for separating silica from silicate-bearing materials
Assignee: University of Utah Research Foundation Inc
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Filing: 1977-02-07
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Granted: 1978-10-03
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Expires: 1997-02-07
Abstract
Abstract A process for removing silicon from a silicate-bearing material. The silicate-bearing material is analyzed for its silicon content and mixed with a controlled quantity of carbon as indicated by the analysis. The carbon is limited to an amount less than the stoichiometric amount necessary to react with the silicon to form silicon carbide. The silicate-bearing material/carbon mixture is formed into a first phase and interposed with a second phase containing additional carbon to form a reaction mixture. The reaction mixture is subjected to a carbothermal reduction reaction to reduce silica in the silicate-bearing material to silicon monoxide. At the temperatures involved in the reaction, the silicon monoxide is in the gaseous phase and readily diffuses from the first phase into the second phase where the diffused silicon monoxide reacts with the additional carbon in the second phase to form silicon carbide. The silicon carbide formation reaction occurs in the gaseous phase so that the silicon carbide is deposited in the second phase in the form of fine fibers. The silicon carbide fibers may be separated from the reaction mixture residue by conventional mechanical separation techniques. The first phase residue has a reduced silica content and may also be mechanically separated from the second phase.
Inventors
- 👤 Ivan B. Cutler
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 12:34
CPC Classifications
C; C01; C01F; C01F7/00; C01F7/02; C01F7/30; C01B; C01B32/00; C01B32/90; C01B32/914; C01B32/956; C01B32/963; C01B32/97; C01B33/00; C01B33/113; C01B33/20; C01B33/26; C01G; C01G25/00; C01G25/02; C04; C04B; C04B35/00; C04B35/622; C04B35/62227; C01P; C01P2004/00; C01P2004/01; C01P2004/02; C01P2004/10
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
252 words
A process for treating a silicate-bearing material to remove therefrom at least a portion of the silicon comprising the steps of: obtaining a quantity of silicate-bearing material; analyzing the silicate-bearing material to determine the silica content of the silicate-bearing material as a basis for calculating the amount of carbon necessary to reduce at least a portion of the silica to silicon monoxide without forming silicon carbide; admixing a predetermined first quantity of carbon with the silicate-bearing material to form a first solid phase, the first carbon being present in the first solid phase in an amount sufficient to reduce at least said portion of silica to silicon monoxide, said first carbon being less than a stoichiometric amount to form silicon carbide upon reaction between the first carbon and said portion of the silica in the silicate-bearing material as indicated by the analyzing step; dispersing the first solid phase in a second solid phase comprising a second carbon by pelletizing the first solid phase thereby forming a solids reaction mixture; heating the solids reaction mixture under a nonreactive atmosphere to a temperature above about 1200° C thereby reducing said portion of the silica to silicon monoxide with the first carbon in the first solid phase; diffusing the silicon monoxide as a gaseous phase from the first solid phase into the second solid phase; and reacting the gaseous silicon monoxide with the second carbon in the second solid phase to form silicon carbide, the silicon carbide thereby becoming part of the second solid phase.
Claim 2
Dependent Claim
252 words
A process for treating a silicate-bearing material to remove therefrom at least a portion of the silicon comprising the steps of: obtaining a quantity of silicate-bearing material; analyzing the silicate-bearing material to determine the silica content of the silicate-bearing material as a basis for calculating the amount of carbon necessary to reduce at least a portion of the silica to silicon monoxide without forming silicon carbide; admixing a predetermined first quantity of carbon with the silicate-bearing material to form a first solid phase, the first carbon being present in the first solid phase in an amount sufficient to reduce at least said portion of silica to silicon monoxide, said first carbon being less than a stoichiometric amount to form silicon carbide upon reaction between the first carbon and said portion of the silica in the silicate-bearing material as indicated by the analyzing step; dispersing the first solid phase in a second solid phase comprising a second carbon by pelletizing the first solid phase thereby forming a solids reaction mixture; heating the solids reaction mixture under a nonreactive atmosphere to a temperature above about 1200° C thereby reducing said portion of the silica to silicon monoxide with the first carbon in the first solid phase; diffusing the silicon monoxide as a gaseous phase from the first solid phase into the second solid phase; and reacting the gaseous silicon monoxide with the second carbon in the second solid phase to form silicon carbide, the silicon carbide thereby becoming part of the second solid phase.
Claim 3
Dependent Claim
40 words
The process defined in claim 1 wherein the admixing step further comprises providing the first quantity of carbon in an amount within the range on the order of about 5.0% to 16.0% carbon by weight percent of the reaction mixture.
Claim 4
Dependent Claim
31 words
The process defined in claim 1 wherein the pelletizing step comprises forming pellets having a particle size within the range on the order of about 100 mesh to 1.0 cubic centimeter.
Claim 5
Dependent Claim
48 words
The process defined in claim 1 wherein the reacting step further comprises following the reacting step with a separating step comprising mechanically separating the first solid phase from the second solid phase thereby removing the first solid phase from the second solid phase and the silicon carbide therein.
Claim 6
Dependent Claim
29 words
The process defined in claim 1 wherein the separating step further comprises a secondary separating step comprising removing the silicon carbide from the carbon in the second solid phase.
Claim 7
Dependent Claim
28 words
The process defined in claim 1 wherein the obtaining step further comprises selecting the silicate-bearing material from the group consisting of clay, bauxite, zircon, sand; and diatomaceous earth.
Claim 8
Dependent Claim
25 words
The process defined in claim 6 wherein the selecting step further obtaining a silicate-bearing material having at least one of the elements aluminum and zirconium.
Claim 9
Dependent Claim
217 words
A process for producing silicon carbide fibers comprising the steps of: obtaining a silicate-bearing earthen material selected from the group consisting of clay, bauxite, zircon, sand, and diatomaceous earth; analyzing the earthen material to determine the silica content of the silicate-bearing earthen material as a basis for determining the amount of carbon required to reduce at least a portion of the silica to silicon monoxide without forming silicon carbide; mixing a predetermined quantity of carbon with the earthen material to form a first solid phase, the predetermined quantity of carbon being determined by the analyzing step and present in amounts less than the stoichiometric amount required to convert the silica to silicon carbide; dispersing the first solid phase of carbon earthen material in a second solid phase comprising a carbon matrix by pelletizing the first solid phase to accommodate screening to separate the pellets from the carbon matrix, thereby forming a solids reaction mixture; and forming silicon monoxide in the pellets by reacting the silica with the carbon in the pellets under a nonreactive atmosphere and at a temperature above about 1200° C, the silicon monoxide diffusing from the pellets of the first solid phase and reacting with the carbon matrix of the second solid phase to form fibers of silicon carbide in the second solid phase.
Claim 10
Dependent Claim
217 words
A process for producing silicon carbide fibers comprising the steps of: obtaining a silicate-bearing earthen material selected from the group consisting of clay, bauxite, zircon, sand, and diatomaceous earth; analyzing the earthen material to determine the silica content of the silicate-bearing earthen material as a basis for determining the amount of carbon required to reduce at least a portion of the silica to silicon monoxide without forming silicon carbide; mixing a predetermined quantity of carbon with the earthen material to form a first solid phase, the predetermined quantity of carbon being determined by the analyzing step and present in amounts less than the stoichiometric amount required to convert the silica to silicon carbide; dispersing the first solid phase of carbon earthen material in a second solid phase comprising a carbon matrix by pelletizing the first solid phase to accommodate screening to separate the pellets from the carbon matrix, thereby forming a solids reaction mixture; and forming silicon monoxide in the pellets by reacting the silica with the carbon in the pellets under a nonreactive atmosphere and at a temperature above about 1200° C, the silicon monoxide diffusing from the pellets of the first solid phase and reacting with the carbon matrix of the second solid phase to form fibers of silicon carbide in the second solid phase.
Claim 11
Dependent Claim
41 words
The process defined in claim 8 wherein the forming step further comprises separating the pellets of the first solid phase from the second solid phase of silicon carbide fibers and carbon matrix and the silicon carbide fibers from the carbon matrix.
Claim 12
Dependent Claim
146 words
A process for separating silicon from silicate-bearing alumina mixtures comprising the steps of: obtaining a silicate-bearing alumina mixture; admixing a first quantity of carbon with the silicate-bearing alumina mixture at a ratio of about 10.0% to 16.0% carbon, by weight; forming a first solid phase with the silicate-bearing alumina and first carbon mixture formed as a plurality of pellets; interspersing the pellets of the first solid phase in a second solid phase comprising a second quantity of carbon to form a reaction mixture; heating the reaction mixture under an inert atmosphere to a temperature above about 1200° C; reducing silica of the silicate-bearing material to silicon monoxide, the silicon monoxide diffusing from the first solid phase and reacting with the carbon of the second solid phase to form silicon carbide in the second solid phase; and separating the first solid phase from the second solid phase.
Claim 13
Dependent Claim
146 words
A process for separating silicon from silicate-bearing alumina mixtures comprising the steps of: obtaining a silicate-bearing alumina mixture; admixing a first quantity of carbon with the silicate-bearing alumina mixture at a ratio of about 10.0% to 16.0% carbon, by weight; forming a first solid phase with the silicate-bearing alumina and first carbon mixture formed as a plurality of pellets; interspersing the pellets of the first solid phase in a second solid phase comprising a second quantity of carbon to form a reaction mixture; heating the reaction mixture under an inert atmosphere to a temperature above about 1200° C; reducing silica of the silicate-bearing material to silicon monoxide, the silicon monoxide diffusing from the first solid phase and reacting with the carbon of the second solid phase to form silicon carbide in the second solid phase; and separating the first solid phase from the second solid phase.
Claim 14
Dependent Claim
70 words
The process defined in claim 10 wherein the obtaining step further comprises obtaining a silicate-bearing alumina mixture from a natural source including a naturally-occurring carbon source and analyzing the mixture for silica and carbon prior to said admixing step, said admixing step further comprising adjusting the carbon/silica ratio by supplementing the mixture with the required amount of at least one of silica and carbon thereby achieving the preselected silica/carbon ratio.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-10-02 | 1982-04-03 | 1982-10-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-10-02 | 1986-04-03 | 1986-10-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-10-02 | 1990-04-03 | 1990-10-03 | $7700.00 | Window Closed / Lapsed |