US4118331A
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Method for working metal and lubricants for use therein
Assignee: Lubrizol Corp
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Filing: 1977-01-11
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Granted: 1978-10-03
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Expires: 1997-01-11
Abstract
Abstract Lubricants useful in metal working processes, especially drawing, comprise an oil of lubricating viscosity; a carboxylic acid or derivative thereof, especially an anhydride of a hydrocarbon-substituted succinic acid in which the substituent contains about 6-30 carbon atoms; and a phosphorus acid salt, usually a zinc salt of a phosphorodithioic acid. The lubricant may also contain other ingredients, especially chlorinated wax or mixtures of aliphatic alcohols and hydrocarbons. Said lubricant provides improved lubricity, corrosion resistance, cleanability, anti-wear properties and extreme pressure properties when used in the working operation.
Inventors
- 👤 Richard William Jahnke
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 09:57
CPC Classifications
C; C10; C10M; C10M141/00; C10M141/10; C10M2203/00; C10M2203/02; C10M2203/022; C10M2203/024; C10M2203/04; C10M2203/06; C10M2203/10; C10M2203/108; C10M2205/00; C10M2205/02; C10M2205/024; C10M2205/026; C10M2205/028; C10M2207/00; C10M2207/02; C10M2207/021; C10M2207/04; C10M2207/10; C10M2207/12; C10M2207/121; C10M2207/123; C10M2207/129; C10M2207/22; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/286; C10M2207/34; C10M2207/40; C10M2207/402; C10M2207/404; C10M2209/00; C10M2209/02; C10M2209/10; C10M2209/103; C10M2209/104; C10M2209/105; C10M2209/11; C10M2209/111; C10M2211/00; C10M2211/06; C10M2211/08; C10M2213/00; C10M2213/02; C10M2213/06; C10M2213/062; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/042; C10M2215/08; C10M2215/082; C10M2215/086; C10M2215/24; C10M2215/26; C10M2215/28; C10M2217/00; C10M2217/04; C10M2217/042; C10M2217/043; C10M2217/046; C10M2217/06; C10M2219/00; C10M2219/02; C10M2219/022; C10M2219/024; C10M2219/04; C10M2219/044; C10M2219/08; C10M2219/082; C10M2219/086; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/041; C10M2223/042; C10M2223/043; C10M2223/045; C10M2223/06; C10M2223/061; C10M2223/063; C10M2223/065; C10M2227/00; C10M2227/06; C10M2227/061; C10M2229/00; C10M2229/04; C10M2229/041; C10M2229/042; C10M2229/045; C10M2229/046; C10M2229/047; C10M2229/048; C10N; C10N2010/00; C10N2010/04; C10N2010/08; C10N2020/00; C10N2020/01; C10N2040/00; C10N2040/20; C10N2040/24; C10N2040/241; C10N2040/242; C10N2040/243; C10N2040/244; C10N2040/245; C10N2040/246; C10N2040/247
Claims Analysis
Total Claims: 46
Claim 1
Independent Claim
149 words
A method for lubricating metal during working thereof which comprises applying to said metal a composition free from elemental sulfur and triaryl phosphates and comprising (A) an oil of lubricating viscosity, (B) at least one substituted succinic acid in which the substituent is a hydrocarbon-based substituent containing 6-75 carbon atoms of an anhydride or lithium salt thereof, and (C) at least one phosphorus acid salt having the formula ##STR3## wherein M is a Group I metal, a Group II metal, aluminum, tin, cobalt, lead, molybdenum, manganese, nickel or ammonium; each of R 1 and R 2 is a hydrocarbon-based radical; each of X 1 and X 2 is oxygen or sulfur; and each of a and b is 0 or 1; components B and C comprising about 3-30% by weight of said composition and about 0.5-5.0 parts by weight of component B being present per part of component C.
Claim 2
Independent Claim
149 words
A method for lubricating metal during working thereof which comprises applying to said metal a composition free from elemental sulfur and triaryl phosphates and comprising (A) an oil of lubricating viscosity, (B) at least one substituted succinic acid in which the substituent is a hydrocarbon-based substituent containing 6-75 carbon atoms of an anhydride or lithium salt thereof, and (C) at least one phosphorus acid salt having the formula ##STR3## wherein M is a Group I metal, a Group II metal, aluminum, tin, cobalt, lead, molybdenum, manganese, nickel or ammonium; each of R 1 and R 2 is a hydrocarbon-based radical; each of X 1 and X 2 is oxygen or sulfur; and each of a and b is 0 or 1; components B and C comprising about 3-30% by weight of said composition and about 0.5-5.0 parts by weight of component B being present per part of component C.
Claim 3
Dependent Claim
37 words
A method according to claim 1 wherein M is zinc or lead, each of R 1 and R 2 is a hydrocarbon radical, X 1 and X 2 are oxygen, and a and b are each 1.
Claim 4
Dependent Claim
23 words
A method according to claim 2 wherein each of R 1 and R 2 is a lower alkyl radical and M is zinc.
Claim 5
Dependent Claim
29 words
A method according to claim 3 wherein component B is tetrapropenyl succinic anhydride, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 6
Dependent Claim
21 words
A method according to claim 4 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 7
Dependent Claim
11 words
A method according to claim 5 wherein the working comprises drawing.
Claim 8
Dependent Claim
14 words
A method according to claim 3 wherein said composition additionally contains a chlorinated wax.
Claim 9
Dependent Claim
29 words
A method according to claim 7 wherein component B is tetrapropenyl succinic anhydride, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 10
Dependent Claim
21 words
A method according to claim 8 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 11
Dependent Claim
11 words
A method according to claim 8 wherein the working comprises drawing.
Claim 12
Dependent Claim
47 words
A method according to claim 3 in which component B is the lithium salt of a polybutenyl succinic anhydride in which the polybutene substituent has a molecular weight of about 1000, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 13
Dependent Claim
21 words
A method according to claim 11 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 14
Dependent Claim
11 words
A method according to claim 12 wherein the working comprises drawing.
Claim 15
Dependent Claim
14 words
A method according to claim 3 wherein the composition additionally contains a thixotropic agent.
Claim 16
Dependent Claim
32 words
A method according to claim 14 wherein the thixotropic agent comprises a mixture of linear and branched chain C 20-30 alcohols and C 24-40 hydrocarbons, said mixture melting at about 45°-50° C.
Claim 17
Dependent Claim
29 words
A method according to claim 15 wherein component B is tetrapropenyl succinic anhydride, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 18
Dependent Claim
21 words
A method according to claim 16 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 19
Dependent Claim
11 words
A method according to claim 17 wherein the working comprises drawing.
Claim 20
Dependent Claim
14 words
A method according to claim 15 wherein said composition additionally contains a chlorinated wax.
Claim 21
Dependent Claim
29 words
A method according to claim 19 wherein component B is tetrapropenyl succinic anhydride, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 22
Dependent Claim
21 words
A method according to claim 20 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 23
Dependent Claim
11 words
A method according to claim 21 wherein the working comprises drawing.
Claim 24
Dependent Claim
47 words
A method according to claim 15 in which component B is the lithium salt of a polyisobutenyl succinic anhydride in which the polyisobutene substituent has a molecular weight of about 1000, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 25
Dependent Claim
21 words
A method according to claim 23 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 26
Dependent Claim
11 words
A method according to claim 24 wherein the working comprises drawing.
Claim 27
Dependent Claim
145 words
A metal workpiece having on its surface a film of a composition free from elemental sulfur and triaryl phosphates and comprising (A) an oil of lubricating viscosity, (B) at least one substituted succinic acid in which the substituent is a hydrocarbon-based substituent containing 6-75 carbon atoms or an anhydride or lithium salt thereof, and (C) at least one phosphorus acid salt having the formula ##STR4## wherein M is a Group I metal, a Group II metal, aluminum, tin, cobalt, lead, molybdenum, manganese, nickel or ammonium; each of R 1 and R 2 is a hydrocarbon-based radical; each of X 1 and X 2 is oxygen or sulfur; and each of a and b is 0 or 1; components B and C comprising about 3-30% by weight of said composition and about 0.5-5.0 parts by weight of component B being present per part of component C.
Claim 28
Dependent Claim
145 words
A metal workpiece having on its surface a film of a composition free from elemental sulfur and triaryl phosphates and comprising (A) an oil of lubricating viscosity, (B) at least one substituted succinic acid in which the substituent is a hydrocarbon-based substituent containing 6-75 carbon atoms or an anhydride or lithium salt thereof, and (C) at least one phosphorus acid salt having the formula ##STR4## wherein M is a Group I metal, a Group II metal, aluminum, tin, cobalt, lead, molybdenum, manganese, nickel or ammonium; each of R 1 and R 2 is a hydrocarbon-based radical; each of X 1 and X 2 is oxygen or sulfur; and each of a and b is 0 or 1; components B and C comprising about 3-30% by weight of said composition and about 0.5-5.0 parts by weight of component B being present per part of component C.
Claim 29
Dependent Claim
37 words
A workpiece according to claim 26 wherein M is zinc or lead; each of R 1 and R 2 is a hydrocarbon radical; X 1 and X 2 are oxygen; and a and b are each 1.
Claim 30
Dependent Claim
23 words
A workpiece according to claim 27 wherein each of R 1 and R 2 is a lower alkyl radical and M is zinc.
Claim 31
Dependent Claim
28 words
A workpiece according to claim 27 wherein component A is mineral oil and component B is at least one carboxylic acid or an anhydride or lithium salt thereof.
Claim 32
Dependent Claim
21 words
A workpiece according to claim 29 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 33
Dependent Claim
14 words
A workpiece according to claim 29 wherein said composition additionally contains a chlorinated wax.
Claim 34
Dependent Claim
29 words
A workpiece according to claim 31 wherein component B is tetrapropenyl succinic anhydride, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 35
Dependent Claim
21 words
A workpiece according to claim 32 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 36
Dependent Claim
47 words
A workpiece according to claim 29 in which component B is the lithium salt of a polybutenyl succinic anhydride in which the polybutene substituent has a molecular weight of about 1000, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 37
Dependent Claim
21 words
A workpiece according to claim 34 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 38
Dependent Claim
14 words
A workpiece according to claim 29 wherein the composition additionally contains a thixotropic agent.
Claim 39
Dependent Claim
32 words
A workpiece according to claim 36 wherein the thixotropic agent comprises a mixture of linear and branched chain C 20-30 alcohols and C 24-40 hydrocarbons, said mixture melting at about 45°-50° C.
Claim 40
Dependent Claim
29 words
A workpiece according to claim 37 wherein component B is tetrapropenyl succinic anhydride, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 41
Dependent Claim
21 words
A workpiece according to claim 38 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 42
Dependent Claim
14 words
A workpiece according to claim 37 wherein said composition additionally contains a chlorinated wax.
Claim 43
Dependent Claim
29 words
A workpiece according to claim 40 wherein component B is tetrapropenyl succinic anhydride, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 44
Dependent Claim
21 words
A workpiece according to claim 41 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
Claim 45
Dependent Claim
47 words
A workpiece according to claim 37 in which component B is the lithium salt of a polyisobutenyl succinic anhydride in which the polyisobutene substituent has a molecular weight of about 1000, each of R 1 and R 2 is a lower alkyl radical, and M is zinc.
Claim 46
Dependent Claim
21 words
A workpiece according to claim 43 wherein component C is the zinc salt of a mixed isobutyl- and primary amylphosphorodithioic acid.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-10-02 | 1982-04-03 | 1982-10-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-10-02 | 1986-04-03 | 1986-10-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-10-02 | 1990-04-03 | 1990-10-03 | $7700.00 | Window Closed / Lapsed |