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US4117103A Expired / Lapsed US ⏱️ 0.0 years remaining

Lithium ion transport compositions

Assignee: Massachusetts Institute of Technology
•
Filing: 1977-05-04
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Granted: 1978-09-26
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Expires: 1997-05-04
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Abstract

Abstract Fast lithium-ion conductors are provided having low resistivities and low-activation-energy mobilities at temperatures at which lithium salts are molten. The novel compounds promote lithium-ion transport in a three dimensional framework and have the general formula: Li.sub.16-2x D.sub.x (TO).sub.4).sub.4 wherein D is a divalent cation such as Mg 2+ , Zn 2+ , Ca 2+ or mixtures thereof, T is a tetravalent cation such as Si 4+ , Ge 4+ or mixtures thereof and x is a number greater than 0 and less than 4.

Inventors

  • 👤 Henry Y-P Hong

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 16:07
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/05; H01M10/056; H01M10/0561; H01M10/0562; C; C01; C01B; C01B33/00; C01B33/20; C01G; C01G17/00; C01G17/006; C04; C04B; C04B35/00; C04B35/01; H01M6/00; H01M6/14; H01M6/18; H01M6/185; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 37 words
A crystalline compound which promotes fast lithium transport in a three dimensional network having the formula: Li.sub.16-2x D.sub.x (GeO.sub.4).sub.4 wherein D is a divalent cation and x is a number greater than zero and less than 4.
Claim 2
Dependent Claim 37 words
A crystalline compound which promotes fast lithium transport in a three dimensional network having the formula: Li.sub.16-2x D.sub.x (GeO.sub.4).sub.4 wherein D is a divalent cation and x is a number greater than zero and less than 4.
Claim 3
Dependent Claim 10 words
The compound of claim 1 of the formula: Li.sub.14 Zn(GeO.sub.4).sub.4
Claim 4
Dependent Claim 11 words
the compound of claim 1 wherein D is Zn 2+ .
Claim 5
Dependent Claim 11 words
The compound of claim 1 wherein D is Mg 2+ .
Claim 6
Dependent Claim 11 words
The compound of claim 1 wherein D is Ca 2+ .
Claim 7
Dependent Claim 32 words
The compound of claim 1 wherein D is a mixture of at least two of the cations selected form the group consisting of Mg 2+ , Zn 2+ and Ca 2+ .

References Cited (Backward Citations)

US3936383A Cited
US4042482A Cited
US4045241A Cited
US4049891A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-09-25 1982-03-27 1982-09-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-09-25 1986-03-27 1986-09-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-09-25 1990-03-27 1990-09-26 $7700.00 Window Closed / Lapsed

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