Polyether polyureides

Claim 2

A polyether polyureide comprising a substituted ureido-terminated polyoxyalkylene selected from the group consisting of a compound of the formula: ##STR27## wherein R 1 and R 2 are, independently, hydrogen or an aliphatic or aromatic monovalent hydrocarbon radical, provided at least one R 1 or R 2 is not hydrogen; X' is hydrogen, a methyl radical or an ethyl radical; Z is a hydrocarbon radical having 2 to 5 carbon atoms forming from 2 to 4 external ether linkages; n is a number from 1 to about 20; and, r is a number from 2 to 4; and a compound of the formula: ##STR28## wherein R 1 and R 2 are as defined above; A is a polyoxyalkylene radical containing from about 1 to 17 oxyalkylene groups; B is a polyoxyalkylene amino radical containing from about 1 to 17 oxyalkylene groups; R is a hydrocarbon radical having from 2 to 5 carbon atoms and forming from 2 to 4 oxycarbon linkages with A and B; X is a C═O radical, a C═S radical or a radical derived from a difunctional isocyanate having two ##STR29## groups; c and d are from 1 to 3 chosen such that their sum is from 1 to 4; e is a number from 1 to 3, f is a number from 1 to 3, g is a number from 1 to 3, y is a number from 0 to about 5, and z is a number from 0 to 2.

Claim 3

The polyether polyureide of claim 1 wherein X' is a methyl radical; n is a number from 2 to 17, Z is a 1,2-propylene radical and r is about 2 or 3.

Claim 4

The polyether polyureide of claim 1 wherein A corresponds to the formula: ##STR30## wherein n is a number from 0 to 15; B corresponds to the formula: ##STR31## wherein m is a number from 0 to 15; c and d are from 1 to 2 and chosen so that their sum is from 2 to 3; e is a number from 1 to 2; g is a number from 1 to 2; f is a number from 1 to 2; z is a number from 0 to 1; y is a number from 1 to 4; and X is a C═O radical.

Claim 5

The polyether polyureide of claim 3 wherein n and m are, independently, numbers from about 1 to 10.

Claim 6

The polyether polyureide of claim 1 wherein X is the radical selected from a group consisting of ##STR32## and mixtures thereof.

Claim 7

A polyether polyureide comprises a substituted ureido-terminated polyoxyalkylene material, formed by the reaction of a substituted ureido group forming compound with a compound selected from a polyoxyalkylenepolyamine of the formula ##STR33## wherein X' is a hydrogen, a methyl radical or an ethyl radical; Z is a hydrocarbon radical having from 2 to 5 carbon atoms forming from 2 to 4 external either linkages; n is a number from 1 to about 20 and r is a number from 2 to 4 and a polyoxyalkylene ureylene or thioureylene having terminal primary amino groups of the formula ##STR34## wherein A is a poloyxyalkylene radical containing from about 1 to about 17 oxyalkylene groups wherein each oxyalkylene group contains from 2 to about 4 carbon atoms; B is a polyoxyalkylene amino radical containing from about 1 to 17 oxyalkylene groups where each oxyalkylene group contains from 2 to about 4 carbon atoms; R is a hydrocarbon radical having from 2 to 5 carbon atoms forming from 2 to 4 oxycarbon linkages with A and B; X is a C═O radical, a C═S radical or a radical derived from a difunctional isocyanate having two ##STR35## groups; c and d are from 1 to 3 chosen such that their sum is 2 to 4; e is a number from 1 to 3; f is a number from 1 to 3; g is a number from 1 to 3; y is a number from 0 to about 5; z is a number from 0 to 2 in a molar ratio of about 1 mole of the substituted ureido forming compound for each mole of amine.

Claim 8

A polyether polyureide comprises a substituted ureido-terminated polyoxyalkylene material, formed by the reaction of a substituted ureido group forming compound with a compound selected from a polyoxyalkylenepolyamine of the formula ##STR33## wherein X' is a hydrogen, a methyl radical or an ethyl radical; Z is a hydrocarbon radical having from 2 to 5 carbon atoms forming from 2 to 4 external either linkages; n is a number from 1 to about 20 and r is a number from 2 to 4 and a polyoxyalkylene ureylene or thioureylene having terminal primary amino groups of the formula ##STR34## wherein A is a poloyxyalkylene radical containing from about 1 to about 17 oxyalkylene groups wherein each oxyalkylene group contains from 2 to about 4 carbon atoms; B is a polyoxyalkylene amino radical containing from about 1 to 17 oxyalkylene groups where each oxyalkylene group contains from 2 to about 4 carbon atoms; R is a hydrocarbon radical having from 2 to 5 carbon atoms forming from 2 to 4 oxycarbon linkages with A and B; X is a C═O radical, a C═S radical or a radical derived from a difunctional isocyanate having two ##STR35## groups; c and d are from 1 to 3 chosen such that their sum is 2 to 4; e is a number from 1 to 3; f is a number from 1 to 3; g is a number from 1 to 3; y is a number from 0 to about 5; z is a number from 0 to 2 in a molar ratio of about 1 mole of the substituted ureido forming compound for each mole of amine.

Claim 9

The polyether polyureide of claim 6 wherein said substituted ureido group forming compound is selected from mono substituted isocyanates and mono and disubstituted ureas.

Claim 10

The polyether polyureide of claim 7 wherein X' is a methyl radical, n is a number from 2 to 17, Z is a 1,2-propylene radical and r is about 2 or 3.

Claim 11

The polyether polyureide of claim 7 wherein A corresponds to the formula: ##STR36## wherein n is a number from 0 to 16 and preferably a number from 1 to 10, B corresponds to the formula: ##STR37## wherein m is a number from 0 to 16 and preferably a number from 1 to 10, c and d are from 1 to 2 chosen such that their sum is from 2 to 3, e is a number from 1 to 2, g is a number from 1 to 2, f is a number from 1 to 2, z is a number from 0 to 1, y is a number from 1 to 4, and X' is a C═O or C═S radical.

Claim 12

The polyether polyureide of claim 9 wherein X is the radical selected from a group consisting of ##STR38## and mixtures thereof.

Claim 13

The polyether polyureide of claim 9 wherein X is a mixture of C═O and C═S radicals throughout the formula such as to yield a mixed polyether ureylenethioureylene.

Claim 14

A polyether polyureide comprising a ureido-terminated polyoxyalkylene of the formula: ##STR39## wherein R 1 and R 2 are independently hydrogen, provided only one is hydrogen; or alkyl, alkenyl, alkadienyl, alkatrienyl radicals of from 1 to 20 carbon atoms; or aryl, alkaryl or aralkyl monocyclic, polycyclic, or fused ring aromatic radicals of from 6 to 30 carbon atoms; or R 1 and R 2 , taken together with the nitrogen atom to which each is attached, form a 5 or 6 membered heterocyclic ring; X' is hydrogen, a methyl radical or an ethyl radical; Z is a hydrocarbon radical having 2 to 5 carbon atoms forming from 2 to 4 external ether linkages; n is a number from 1 to about 20; and, r is a number from 2 to 4.

Claim 15

A polyether polyureide comprising a ureido-terminated polyoxyalkylene of the formula: ##STR39## wherein R 1 and R 2 are independently hydrogen, provided only one is hydrogen; or alkyl, alkenyl, alkadienyl, alkatrienyl radicals of from 1 to 20 carbon atoms; or aryl, alkaryl or aralkyl monocyclic, polycyclic, or fused ring aromatic radicals of from 6 to 30 carbon atoms; or R 1 and R 2 , taken together with the nitrogen atom to which each is attached, form a 5 or 6 membered heterocyclic ring; X' is hydrogen, a methyl radical or an ethyl radical; Z is a hydrocarbon radical having 2 to 5 carbon atoms forming from 2 to 4 external ether linkages; n is a number from 1 to about 20; and, r is a number from 2 to 4.

Claim 16

The polyether polyureide of claim 12 wherein X; is a methyl radical; n is a number from 2 to 17, Z is a 1,2-propylene radical and r, is about 2 or 3, R 1 and R 2 are alkyl radicals of from 1 to 4 carbon atoms; or monocyclic aryl.

Claim 17

The polyether polyureide of claim 13 wherein r is 2 and the ureido terminated polyoxyalkylene has a molecular weight of about 2000.

Claim 18

The polyether polyureide of claim 13 wherein the ureido terminated polyoxyalkylene has a molecular weight of about 400.