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US4113802A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparing polypropylene compositions having high impact strength at low temperatures

Assignee: Montedison SpA
•
Filing: 1976-12-29
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Granted: 1978-09-12
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Expires: 1996-12-29
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Abstract

Abstract There is disclosed a new and improved process for preparing compositions consisting for at least 50% by weight of isotactic polypropylene and having high impact strength at low temperatures. The process comprises three or more steps. In the first step propylene is polymerized in an inert liquid hydrocarbon medium and in contact with a stereospecific catalyst prepared by mixing a titanium trihalide with a dialkyl aluminum monohalide to obtain a slurry. In subsequent steps ethylene, or an ethylene/propylene mixture, is fed to the polymerization suspension of first step and the polymerization is continued until the amount of ethylene polymerized is, at most, 20% by weight of the total, final polymeric composition obtained.

Inventors

  • 👤 Mario Matteoli
  • 👤 Luciano Luciani

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:31
CPC Classifications
C; C08; C08F; C08F297/00; C08F297/06; C08F297/08; C08F297/083

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 189 words
Process for preparing polymeric compositions containing at least 50% by weight of isotactic polypropylene comprising the following steps: (a) polymerizing propylene to isotactic polypropylene by polymerizing propylene in a hydrocarbon solvent at a temperature of from 50° C to 80° C and at a pressure between 3 and 10 kg/cm 2 gauge, in the presence of hydrogen and of a stereospecific catalyst comprising the product obtained by mixing a titanium trihalide with a dialkyl aluminum monohalide, to obtain a suspension of substantially isotactic polypropylene in the hydrocarbon solvent; (b) feeding ethylene continuously into the polymerization suspension while feeding propylene discontinuously into the suspension to obtain, during the propylene feeding, a molar ratio of ethylene to propylene of from 60/40 to 85/15 and, in the feed as a whole, a molar ratio of at least 80/20 between the total amount of ethylene fed and the total amount of propylene fed, both monomers being polymerized at a temperature of from 60° C to 80° C and at a pressure lower than 10 kg/cm 2 gauge, until the resulting copolymer makes up from 8% to 18% by weight of the total composition.
Claim 2
Dependent Claim 189 words
Process for preparing polymeric compositions containing at least 50% by weight of isotactic polypropylene comprising the following steps: (a) polymerizing propylene to isotactic polypropylene by polymerizing propylene in a hydrocarbon solvent at a temperature of from 50° C to 80° C and at a pressure between 3 and 10 kg/cm 2 gauge, in the presence of hydrogen and of a stereospecific catalyst comprising the product obtained by mixing a titanium trihalide with a dialkyl aluminum monohalide, to obtain a suspension of substantially isotactic polypropylene in the hydrocarbon solvent; (b) feeding ethylene continuously into the polymerization suspension while feeding propylene discontinuously into the suspension to obtain, during the propylene feeding, a molar ratio of ethylene to propylene of from 60/40 to 85/15 and, in the feed as a whole, a molar ratio of at least 80/20 between the total amount of ethylene fed and the total amount of propylene fed, both monomers being polymerized at a temperature of from 60° C to 80° C and at a pressure lower than 10 kg/cm 2 gauge, until the resulting copolymer makes up from 8% to 18% by weight of the total composition.

References Cited (Backward Citations)

US3970719A Cited
US3970719B1 Cited
US3798288A Cited
US3629368A Cited
US3974236A Cited
US3998911A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-09-11 1982-03-13 1982-09-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-09-11 1986-03-13 1986-09-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-09-11 1990-03-13 1990-09-12 $7700.00 Window Closed / Lapsed

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