US4113725A — Multifunctional additives

Claim 1

Independent Claim 179 words

A heterocyclic nitrogen compound selected from the class consisting of (a) a compound comprising two monovalent amine substituted mononuclear diazine nuclei in which each said monovalent amine substituent is bonded through an amino nitrogen atom to a carbon atom of one of said diazine nuclei, said diazine nuclei being linked one to the other through a bivalent amine radical bonded through an amino nitrogen atom to a carbon atom of each of said diazine nuclei; (b) a monovalent amine substituted mononuclear diazine in which said monovalent amine substituent is bonded through an amino nitrogen atom to a carbon atom of the diazine nucleus, the amine of said monovalent amine substituent being selected from the group consisting of: ##STR17## the amine of said bivalent amine radical being selected from the group consisting of: ##STR18## wherein: m is an integer of from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; and R' is an alkyl group containing from 8 to about 300 carbon atoms.

Claim 2

Dependent Claim 179 words

A heterocyclic nitrogen compound selected from the class consisting of (a) a compound comprising two monovalent amine substituted mononuclear diazine nuclei in which each said monovalent amine substituent is bonded through an amino nitrogen atom to a carbon atom of one of said diazine nuclei, said diazine nuclei being linked one to the other through a bivalent amine radical bonded through an amino nitrogen atom to a carbon atom of each of said diazine nuclei; (b) a monovalent amine substituted mononuclear diazine in which said monovalent amine substituent is bonded through an amino nitrogen atom to a carbon atom of the diazine nucleus, the amine of said monovalent amine substituent being selected from the group consisting of: ##STR17## the amine of said bivalent amine radical being selected from the group consisting of: ##STR18## wherein: m is an integer of from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; and R' is an alkyl group containing from 8 to about 300 carbon atoms.

Claim 3

Dependent Claim 92 words

The compound of claim 1 in which said heterocyclic nitrogen compound also includes at least one additional substituent bonded to a carbon atom of at least one of said diazine nuclei, said additional substituent being selected from the group consisting of (a) amino, anilino, alkyl amino and alkyl anilino radicals having from 1 to 100 carbon atoms bonded directly through an amino nitrogen to a carbon atom of at least one of said diazine nuclei; (b) N-phenyl-p-phenylene diamine; (c) 2-(2-aminoethylamino)-ethanol and (d) an alkyl group having from 1 to 100 carbon atoms.

Claim 4

Dependent Claim 58 words

The compound of claim 1 in which each of the diazine nuclei of compound (a) also includes at least one additional amine substituent bonded directly through an amino nitrogen to a carbon atom of each said diazine nucleus, said additional amine substituent selected from the group consisting of members (1) through (6) inclusive, as defined in claim 1.

Claim 5

Dependent Claim 12 words

The compound of claim 1 in which the diazine nucleus is pyrimidine.

Claim 6

Dependent Claim 43 words

The compound of claim 1 in which the diazine nucleus is pyrimidine and in which the amine of said monovalent and said bivalent amine radicals is a bis(alkenylsuccinimide)amine having the structure of member (2) of the group of amines defined in claim 1.

Claim 7

Dependent Claim 55 words

The compound of claim 1 in which the diazine nucleus is pyrimidine including an additional monovalent amine substituent bonded through an amino nitrogen to a carbon atom of said pyrimidine nucleus, the additional monovalent amine of said monovalent amine radical havig the structure of member (1) of the group of amines defined in claim 1.

Claim 8

Dependent Claim 36 words

A compound comprising the compound of claim 1 which has been reactively combined with from 0.005% to about 10% by weight, based upon the total weight of said composition, of an alkali or alkaline earth metal.

Claim 9

Dependent Claim 17 words

The compound of claim 7 including of from 0.005% to about 1% by weight of said metal.

Claim 10

Dependent Claim 28 words

A compound comprising a product of the reaction of the compound of claim 1 and an alkali or alkaline earth metal oxide, hydroxide, carbonate, carboxylate, alcoholate or phenolate.

Claim 11

Dependent Claim 68 words

A compound of the formula ##STR19## where A is a monovalent amine radical bonded through an amino nitrogen to a carbon atom of the pyrimidine nucleus, the amine of said monovalent amine radical having the structure ##STR20## wherein: m is an integer from 1 to 3; e is an integer from 1 to 10; and R is an alkenyl group containing from 8 to about 300 carbon atoms.

Claim 12

Dependent Claim 68 words

A compound of the formula ##STR19## where A is a monovalent amine radical bonded through an amino nitrogen to a carbon atom of the pyrimidine nucleus, the amine of said monovalent amine radical having the structure ##STR20## wherein: m is an integer from 1 to 3; e is an integer from 1 to 10; and R is an alkenyl group containing from 8 to about 300 carbon atoms.

Claim 13

Dependent Claim 68 words

A compound of the formula ##STR21## where A is a monovalent amine radical bonded through an amino nitrogen to a carbon of the pyrimidine nucleus, the amine of said monovalent amine radical having the structure of ##STR22## wherein: m is an integer from 1 to 3; e is an integer from 1 to 10; and R is an alkenyl group containing from 8 to about 300 carbon atoms.

Claim 14

Dependent Claim 68 words

A compound of the formula ##STR21## where A is a monovalent amine radical bonded through an amino nitrogen to a carbon of the pyrimidine nucleus, the amine of said monovalent amine radical having the structure of ##STR22## wherein: m is an integer from 1 to 3; e is an integer from 1 to 10; and R is an alkenyl group containing from 8 to about 300 carbon atoms.

Claim 15

Dependent Claim 135 words

A compound of the formula ##STR23## wherein A is a monovalent amine radical bonded through an amino nitrogen atom to a carbon atom of the pyrimidine nucleus, the amine of said monovalent amine radical being selected from the group consisting of ##STR24## wherein: m is an integer from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; R' is an alkyl group containing from 8 to about 300 carbon atoms, and B and D are members selected from the group consisting of (a) hydrogen; (b) A; (c) amino, anilino, alkyl amino and alkyl anilino radicals having from 1 to 100 carbon atoms; (d) N-phenyl-p-phenylene diamine; (e) 2-(2-aminoethylamino)-ethanol, and (f) an alkyl group having from 1 to 100 carbon atoms.

Claim 16

Dependent Claim 135 words

A compound of the formula ##STR23## wherein A is a monovalent amine radical bonded through an amino nitrogen atom to a carbon atom of the pyrimidine nucleus, the amine of said monovalent amine radical being selected from the group consisting of ##STR24## wherein: m is an integer from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; R' is an alkyl group containing from 8 to about 300 carbon atoms, and B and D are members selected from the group consisting of (a) hydrogen; (b) A; (c) amino, anilino, alkyl amino and alkyl anilino radicals having from 1 to 100 carbon atoms; (d) N-phenyl-p-phenylene diamine; (e) 2-(2-aminoethylamino)-ethanol, and (f) an alkyl group having from 1 to 100 carbon atoms.

Claim 17

Dependent Claim 43 words

The compound of claim 12 having the structure ##STR25## wherein n is an integer from 1 to 3; e is an integer from 1 to 10; R is a polybutenyl group; and R' is an alkyl group having up to 100 carbon atoms.

Claim 18

Dependent Claim 54 words

The compound of claim 12 having the structure ##STR26## where A, B and D are monovalent amine radicals bonded through an amino nitrogen to a carbon atom of the pyrimidine nucleus, the amine of each said monovalent amine radical having the structure of member (2) of the group of amines defined in claim 12.

Claim 19

Dependent Claim 23 words

A compound comprising the compound of claim 14 which has been reactively combined with from 0.005% to about 1% of an alkali metal.

Claim 20

Dependent Claim 57 words

The compound of claim 12 having the structure ##STR27## where B is an amino group and A is a monovalent amine radical bonded through an amino nitrogen to a carbon atom of the pyrimidine nucleus, the amine of said monovalent amine radical having the structure of member (2) of the group of amines defined in claim 12.

Claim 21

Dependent Claim 23 words

A compound comprising the compound of claim 16 which has been reactively combined with from 0.005% to about 1% of an alkali metal.

Claim 22

Dependent Claim 54 words

The compound of claim 12 having the structure ##STR28## where A, B and D are monovalent amine radicals bonded through an amino nitrogen to a carbon atom of the pyrimidine nucleus, the amine of each said monovalent amine radical having the structure of member (4) of the group of amines defined in claim 12.

Claim 23

Dependent Claim 54 words

The compound of claim 12 having the structure ##STR29## where A, B and D are monovalent amine radicals bonded through an amino nitrogen to a carbon atom of the pyrimidine nucleus, the amine of each said monovalent amine radical having the structure of member (6) of the group of amines defined in claim 12.

Claim 24

Dependent Claim 66 words

The compound of claim 12 having the structure ##STR30## wherein A, B and D are monovalent amine radicals bonded through an amino nitrogen to a carbon atom of the pyrimidine ring, the amines of said monovalent amine radicals being selected from the group consisting of N-phenyl-p-phenylene diamine 2-(2-aminoethylamino)-ethanol, and an amine having the structure of member (2) of the group of amines defined in claim 12.

Claim 25

Dependent Claim 82 words

The compound of claim 12 having the structure ##STR31## where A is a monovalent amine radical bonded through an amino nitrogen to a carbon atom of the pyrimidine nucleus, the amine of said monovalent amine radical having the structure of member (2) of the group of amines defined in claim 12; B is NH 2 or a monovalent amine radical bonded through an amine nitrogen to a carbon atom of the pyrimidine ring, the amine of said amine radical being N-phenyl-p-phenylene diamine.

Claim 26

Dependent Claim 64 words

The compound of claim 12 having the structure ##STR32## where D is an alkyl group having from 1 to 100 carbon atoms, and A is a monovalent amine radical bonded through an amino nitrogen to a compound atom of the pyrimidine nucleus, the amine of said monovalent amine radical having the structure of member (2) of the group of amines defined in claim 12.

Claim 27

Dependent Claim 202 words

A compound of the formula ##STR33## wherein B is a monovalent amine radical bonded through an amino nitrogen atom to a carbon atom of each of said pyrimidine nuclei, the amine of said monovalent amine radical being selected from the group consisting of: ##STR34## D is selected from the group consisting of (a) hydrogen; (b) a monovalent amine radical substituent bonded through an amino nitrogen atom to a carbon atom of the pyrimidine nucleus, the amine of said monovalent amine raidical being selected from the group consisting of members (1) through (6) inclusive of the group of amines defined above; (c) amino, anilino, alkyl amino and alkyl anilino radicals having from 1 to 100 carbon atoms; (d) N-phenyl-p-phenylene diamine; (e) 2-(2-aminoethylamino)-ethanol, and (f) an alkyl group having from 1 to 100 carbon atoms A is selected from the group consisting of (7) --HN (C m H 2m NH) e-1 C m H 2m NH and ##STR35## wherein: m is an integer of from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; and R' is an alkyl group containing from 8 to about 300 carbon atoms.

Claim 28

Dependent Claim 202 words

A compound of the formula ##STR33## wherein B is a monovalent amine radical bonded through an amino nitrogen atom to a carbon atom of each of said pyrimidine nuclei, the amine of said monovalent amine radical being selected from the group consisting of: ##STR34## D is selected from the group consisting of (a) hydrogen; (b) a monovalent amine radical substituent bonded through an amino nitrogen atom to a carbon atom of the pyrimidine nucleus, the amine of said monovalent amine raidical being selected from the group consisting of members (1) through (6) inclusive of the group of amines defined above; (c) amino, anilino, alkyl amino and alkyl anilino radicals having from 1 to 100 carbon atoms; (d) N-phenyl-p-phenylene diamine; (e) 2-(2-aminoethylamino)-ethanol, and (f) an alkyl group having from 1 to 100 carbon atoms A is selected from the group consisting of (7) --HN (C m H 2m NH) e-1 C m H 2m NH and ##STR35## wherein: m is an integer of from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; and R' is an alkyl group containing from 8 to about 300 carbon atoms.

Claim 29

Dependent Claim 209 words

A compound of the formula ##STR36## wherein X and Y are mononuclear diazine nuclei, Z is a bivalent amine radical connected through an amino nitrogen to a carbon atom of each of diazine nuclei to which said Z is bonded, the amine of said bivalent amine radical being selected from the group consisting of: H 2 n (c m H 2m NH) e H and ##STR37## A is a monovalent amine substituent bonded through an amino nitrogen to a carbon atom of X, the amine of said monovalent amine substituent being selected from the group consisting of ##STR38## wherein: n is from 0 to 10 m is an integer of from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; R' is an alkyl group containing from 8 to about 300 carbon atoms, and B and D are selected from the group consisting of (a) hydrogen; (b) A; (c) alkyl, alkenyl, hydroxyalkyl, and alkyl carboxy radicals having from one to about 500 carbon atoms; (d) aralkyl, aryl, alkaryl and hydroxyaryl radicals having from 1 to about 100 carbon atoms; (e) carboxy, hydroxy, phosphono phosphato sulfonoto and mercapto radicals; (f) N-phenyl-p-phenylene diamine; (g) 2-(a-aminoethylamino)-ethanol.

Claim 30

Dependent Claim 209 words

A compound of the formula ##STR36## wherein X and Y are mononuclear diazine nuclei, Z is a bivalent amine radical connected through an amino nitrogen to a carbon atom of each of diazine nuclei to which said Z is bonded, the amine of said bivalent amine radical being selected from the group consisting of: H 2 n (c m H 2m NH) e H and ##STR37## A is a monovalent amine substituent bonded through an amino nitrogen to a carbon atom of X, the amine of said monovalent amine substituent being selected from the group consisting of ##STR38## wherein: n is from 0 to 10 m is an integer of from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; R' is an alkyl group containing from 8 to about 300 carbon atoms, and B and D are selected from the group consisting of (a) hydrogen; (b) A; (c) alkyl, alkenyl, hydroxyalkyl, and alkyl carboxy radicals having from one to about 500 carbon atoms; (d) aralkyl, aryl, alkaryl and hydroxyaryl radicals having from 1 to about 100 carbon atoms; (e) carboxy, hydroxy, phosphono phosphato sulfonoto and mercapto radicals; (f) N-phenyl-p-phenylene diamine; (g) 2-(a-aminoethylamino)-ethanol.

Claim 31

Dependent Claim 203 words

A compound of the formula ##STR39## wherein Z is a bivalent amine radical bonded through an amino nitrogen to a carbon atom of each of said heterocyclic nuclei, the amine of said bivalent amine radical being selected from the group consisting of H 2 n(c m H 2m NH) e H and ##STR40## B is a monovalent amine substituent bonded through an amino nitrogen atom to a carbon atom of the pyrimidine nucleus to which B is bonded, the amine of said monovalent amine substituent being selected from the group consisting of: ##STR41## wherein: n is from 0 to 10; m is an integer of from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; and R' is an alkyl group containing from 8 to about 300 carbon atoms, D is selected from the group consisting (a) hydrogen (b) B; (c) alkyl, alkenyl, hydroxyalkyl and alkyl carboxy radicals having from 1 to about 100 carbon atoms; (d) aralkyl, aryl, alkaryl and hydroxyaryl radicals having from 1 to about 100 carbon atoms; (e) carboxy, hydroxy, phosphono, phosphato, sulfonato and mercapto radicals; (f) N-phenyl-p phenylene diamine; and (g) 2-(a-aminoethylamino)-ethanol.

Claim 32

Dependent Claim 203 words

A compound of the formula ##STR39## wherein Z is a bivalent amine radical bonded through an amino nitrogen to a carbon atom of each of said heterocyclic nuclei, the amine of said bivalent amine radical being selected from the group consisting of H 2 n(c m H 2m NH) e H and ##STR40## B is a monovalent amine substituent bonded through an amino nitrogen atom to a carbon atom of the pyrimidine nucleus to which B is bonded, the amine of said monovalent amine substituent being selected from the group consisting of: ##STR41## wherein: n is from 0 to 10; m is an integer of from 1 to 3; e is an integer of from 1 to 10; R is an alkenyl group containing from 8 to about 300 carbon atoms; and R' is an alkyl group containing from 8 to about 300 carbon atoms, D is selected from the group consisting (a) hydrogen (b) B; (c) alkyl, alkenyl, hydroxyalkyl and alkyl carboxy radicals having from 1 to about 100 carbon atoms; (d) aralkyl, aryl, alkaryl and hydroxyaryl radicals having from 1 to about 100 carbon atoms; (e) carboxy, hydroxy, phosphono, phosphato, sulfonato and mercapto radicals; (f) N-phenyl-p phenylene diamine; and (g) 2-(a-aminoethylamino)-ethanol.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1981-09-11	1982-03-13	1982-09-12	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1985-09-11	1986-03-13	1986-09-12	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1989-09-11	1990-03-13	1990-09-12	$7700.00	Window Closed / Lapsed

Multifunctional additives

Abstract

Inventors

Bibliographic Details

Claims Analysis

References Cited (Backward Citations)

USPTO Annuity & Maintenance Windows

Assigned Categories & Tags

Assign Category Tag