Patent US3747049A successfully refreshed from Google Patents.
US4113706A
Expired / Lapsed
US
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Aromatic imino acids and resins derived therefrom
Assignee: Elantas PDG Inc
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Filing: 1977-08-11
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Granted: 1978-09-12
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Expires: 1997-08-11
Abstract
Abstract This invention relates to imino dicarboxylic acids (IDA) of the general formulae ##STR1## where Z is a moiety, preferably aromatic, R is a moiety, preferably aliphatic, and to resins derived from such acids. Such resins, which may vary widely, are illustrated by polyesters, poly(ester-amides), poly(ester-imides), poly(ester-imide-amides), etc. In the preferred embodiment such resins contain tris (hydroxyethyl) isocyanurate. The preferred IDA, which is derived from trimellitic anhydride (TMA) and glycine, has the following idealized formula ##STR2## IS THE PREDOMINANT DICARBOXYLIC ACID EMPLOYED IN SUCH RESINS. This invention also relates to aromatic IDA where R is aryl as illustrated by IDA derived from aminobenzoic acid and resins prepared therefrom.
Inventors
- 👤 Daniel J. Lange
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 04:25
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/303; H01B3/305; C; C08; C08G; C08G63/00; C08G63/68; C08G63/685; C08G63/6854; C08G69/00; C08G69/44; C08G73/00; C08G73/06; C08G73/10; C08G73/16; H01B3/306; H01B3/42; H01B3/421; H01B3/422; H01B3/423
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
247 words
A resin derived from (A) a dicarboxylic acid component which is an imino-dicarboxylic acid of the formula ##STR44## where Z and Z' are aromatic moieties, the indicated ##STR45## attached to Z being attached to an aromatic ring of Z, the ##STR46## linking an N to Z or Z' each being attached to an aromatic ring in Z or Z' and being present in a 5 membered imide ring and the moiety Ar being an aromatic ring, the N and COOH moieties being attached to the aromatic ring; and of a polyhydric alcohol component which is at least one of (B) a glycol component, and (C) a polyol component containing at least three esterifiable hydroxyl groups; and any further components of said resin being (D) the imide or imide-amide of (D 1 ) an aromatic diamine and (D 2 ) an aromatic tricarboxylic or aromatic tetracarboxylic acid, of the formulae, respectively, ##STR47## or the anhydrides thereof, two of the COOH groups of the acid (a) and each of the COOH groups of each of the two pairs of such groups of the acid (b) being attached to adjacent carbons of a benzene ring of the Z" and Z''' moieties, respectively, Z" and Z''' being aromatic moieties; where (A) and at least one of (B) and (C) and (D) are the sole polymer-forming components of said resin and only the components (A) and at least one of (B) and (C) are required to be present as polymer forming components.
Claim 2
Dependent Claim
247 words
A resin derived from (A) a dicarboxylic acid component which is an imino-dicarboxylic acid of the formula ##STR44## where Z and Z' are aromatic moieties, the indicated ##STR45## attached to Z being attached to an aromatic ring of Z, the ##STR46## linking an N to Z or Z' each being attached to an aromatic ring in Z or Z' and being present in a 5 membered imide ring and the moiety Ar being an aromatic ring, the N and COOH moieties being attached to the aromatic ring; and of a polyhydric alcohol component which is at least one of (B) a glycol component, and (C) a polyol component containing at least three esterifiable hydroxyl groups; and any further components of said resin being (D) the imide or imide-amide of (D 1 ) an aromatic diamine and (D 2 ) an aromatic tricarboxylic or aromatic tetracarboxylic acid, of the formulae, respectively, ##STR47## or the anhydrides thereof, two of the COOH groups of the acid (a) and each of the COOH groups of each of the two pairs of such groups of the acid (b) being attached to adjacent carbons of a benzene ring of the Z" and Z''' moieties, respectively, Z" and Z''' being aromatic moieties; where (A) and at least one of (B) and (C) and (D) are the sole polymer-forming components of said resin and only the components (A) and at least one of (B) and (C) are required to be present as polymer forming components.
Claim 3
Dependent Claim
18 words
The resin of claim 1 where the iminodicarboxylic acid component has at least one of the formulae ##STR48##
Claim 4
Dependent Claim
21 words
The resin of claim 2 where the resin is a polyester of (A), (B) and (C), the components (D) being absent.
Claim 5
Dependent Claim
18 words
The resin of claim 2 where the resin is a poly(ester-imide) of components (A), (B), (C) and (D).
Claim 6
Dependent Claim
18 words
The resin of claim 2 where the resin is a poly(ester-imide-amide) of components (A), (B), (C) and (D).
Claim 7
Dependent Claim
14 words
The resin of claim 3 in which the polyol component (C) is tris(hydroxyethyl) isocyanurate.
Claim 8
Dependent Claim
14 words
The resin of claim 4 in which the polyol component (C) is tris(hydroxyethyl) isocyanurate.
Claim 9
Dependent Claim
14 words
The resin of claim 5 in which the polyol component (C) is tris(hydroxyethyl) isocyanurate.
Claim 10
Dependent Claim
14 words
The resin of claim 6 where the component (A) is the iminodicarboxylic acid ##STR49##
Claim 11
Dependent Claim
14 words
The resin of claim 7 where the component (A) is the iminodicarboxylic acid ##STR50##
Claim 12
Dependent Claim
14 words
The resin of claim 8 where the component (A) is the iminodicarboxylic acid ##STR51##
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-09-11 | 1982-03-13 | 1982-09-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-09-11 | 1986-03-13 | 1986-09-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-09-11 | 1990-03-13 | 1990-09-12 | $7700.00 | Window Closed / Lapsed |