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US4112013A Expired / Lapsed US ⏱️ 0.0 years remaining

Adhesive composition

Assignee: EIDP Inc
•
Filing: 1977-02-18
•
Granted: 1978-09-05
•
Expires: 1997-02-18
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Abstract

Abstract Solutions of chlorosulfonated polyethylene or mixtures of sulfonyl chlorides and chlorinated polymers in polymerizable vinyl monomers having a Brookfield viscosity of up to about 1 million form excellent adhesive compositions which cure to high bond strengths. Acrylic monomers are preferred.

Inventors

  • 👤 Paul Clayton Briggs, Jr.
  • 👤 Lawrence Carl Muschiatti

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 15:31
CPC Classifications
C; C09; C09J; C09J123/00; C09J123/26; C09J123/28; B; B32; B32B; B32B15/00; B32B15/04; B32B15/043; B32B27/00; B32B27/04; B32B7/00; B32B7/04; B32B7/12; C09J4/00; C09J4/06; B32B2311/00; B32B2311/24; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31699; Y10T428/31855; Y10T428/31935

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 150 words
A polymer-in-monomer solution suitable for use as an adhesive when combined with polymerization catalyst, which when so combined gives bonds that can be characterized by at least one of the following: the setting time is less than about 10 minutes, the T-peel strength is greater than about 5 pli, the lap shear strength on prepared surfaces is greater than about 2500 psi, and the bond strength on oily surfaces is not significantly adversely affected by the presence of the oil, said solution consisting essentially of (a) chlorosulfonated polyethylene made from branched polyethylene having a melt index of about 100, said chlorosulfonated polyethylene containing about 43% by weight chlorine and about 34 mmoles of sulfonyl chloride per 100 grams of polymer and (b) a mixture of the following acrylic monomers: methyl methacrylate, glacial methacrylic acid and ethylene glycol dimethacrylate, said solution having a Brookfield viscosity of up to about 1 million.
Claim 2
Dependent Claim 150 words
A polymer-in-monomer solution suitable for use as an adhesive when combined with polymerization catalyst, which when so combined gives bonds that can be characterized by at least one of the following: the setting time is less than about 10 minutes, the T-peel strength is greater than about 5 pli, the lap shear strength on prepared surfaces is greater than about 2500 psi, and the bond strength on oily surfaces is not significantly adversely affected by the presence of the oil, said solution consisting essentially of (a) chlorosulfonated polyethylene made from branched polyethylene having a melt index of about 100, said chlorosulfonated polyethylene containing about 43% by weight chlorine and about 34 mmoles of sulfonyl chloride per 100 grams of polymer and (b) a mixture of the following acrylic monomers: methyl methacrylate, glacial methacrylic acid and ethylene glycol dimethacrylate, said solution having a Brookfield viscosity of up to about 1 million.
Claim 3
Dependent Claim 33 words
The composition of claim 1 in which the mixture of acrylic monomers contains about 85 parts methyl methacrylate, about 15 parts of glacial methacrylic acid, and about two parts of ethylene glycol dimethacrylate.
Claim 4
Dependent Claim 33 words
The composition of claim 2 in which the mixture of acrylic monomers if present in the amount of 50 to 500 parts by weight per 100 parts by weight of the chlorosulfonated polyethylene.

References Cited (Backward Citations)

US2407143A Cited
GB592325A Cited
US2994632A Cited
US3262803A Cited
GB1077083A Cited
US3616040A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-09-04 1982-03-06 1982-09-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-09-04 1986-03-06 1986-09-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-09-04 1990-03-06 1990-09-05 $7700.00 Window Closed / Lapsed

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