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US4111769A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiation curable pressure sensitive adhesive composition

Assignee: Union Carbide Corp
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Filing: 1977-12-29
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Granted: 1978-09-05
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Expires: 1997-12-29
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Abstract

Abstract Radiation curable pressure sensitive adhesive composition comprises: a polyoxyalkylene homo- or copolymer which is either a polyxyethylene homopolymer or a poly (oxyethylene - oxypropylene) copolymer, or mixture thereof, having a molecular weight of from 1,700 to 90,000, in which at least 40 percent by weight of the oxyalkylene units are oxyethylene units; a liquid carbamyloxy alkyl acrylate; and, optionally, a photoinitiator. Also disclosed is a process of preparing such a composition and the radiation cured pressure sensitive adhesive produced therefrom.

Inventors

  • 👤 Kenneth Charles Stueben

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 15:12
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/02; C09; C09J; C09J4/00; C09J4/06; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/2852; Y10T428/2878; Y10T428/2891; Y10T428/31504; Y10T428/31786

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 149 words
A radiation curable pressure sensitive adhesive composition comprising: (A) from 35 to 80 weight percent of a liquid carbamyloxy alkyl acrylate of the formula: ##STR3## wherein R and R" are each, individually, hydrogen or alkyl from 1 to 3 carbon atoms, R' is alkylene of 1 to 3 carbon atoms; (B) from 20 to 65 weight percent of a polyoxyalkylene homopolymer or copolymer which is characterized by the repeating units: ##STR4## wherein each R'" is hydrogen or methyl and a sufficient number of the R'" substituents are hydrogen that from 40 to 100 percent by weight of the oxyalkylene units in the polymer are oxyethylene units and from 60 to 0 percent by weight are oxypropylene units; and x is a number such that the molecular weight of the polyoxyalkylene homopolymer or copolymer is from 1,700 to 90,000; and (C) from 0.1 to 10 weight percent of a photoinitiator.
Claim 2
Dependent Claim 149 words
A radiation curable pressure sensitive adhesive composition comprising: (A) from 35 to 80 weight percent of a liquid carbamyloxy alkyl acrylate of the formula: ##STR3## wherein R and R" are each, individually, hydrogen or alkyl from 1 to 3 carbon atoms, R' is alkylene of 1 to 3 carbon atoms; (B) from 20 to 65 weight percent of a polyoxyalkylene homopolymer or copolymer which is characterized by the repeating units: ##STR4## wherein each R'" is hydrogen or methyl and a sufficient number of the R'" substituents are hydrogen that from 40 to 100 percent by weight of the oxyalkylene units in the polymer are oxyethylene units and from 60 to 0 percent by weight are oxypropylene units; and x is a number such that the molecular weight of the polyoxyalkylene homopolymer or copolymer is from 1,700 to 90,000; and (C) from 0.1 to 10 weight percent of a photoinitiator.
Claim 3
Dependent Claim 43 words
Radiation curable pressure sensitive adhesive composition as claimed in claim 1, wherein said component (A) is present at a concentration of from 40 to 75 weight percent and said component (B) is present at a concentration of from 25 to 60 weight percent.
Claim 4
Dependent Claim 28 words
A radiation curable pressure sensitive adhesive composition as claimed in claim 1, wherein said component (C) is present at a concentration of from 0.5 to 5 weight percent.
Claim 5
Dependent Claim 23 words
A radiation curable pressure sensitive adhesive composition as claimed in claim 1, wherein said liquid carbamyloxy alkyl acrylate is 2-(N-methyl carbamyloxy) ethyl acrylate.
Claim 6
Dependent Claim 33 words
A radiation curable pressure sensitive adhesive composition as claimed in claim 1, wherein x has a value such that the molecular weight of said polyoxyalkylene homopolymer or copolymer is from 2,500 to 21,000.
Claim 7
Dependent Claim 22 words
A radiation curable pressure sensitive adhesive composition as claimed in claim 4, wherein said polyoxyalkylene homopolymer or copolymer is a polyoxyethylene homopolymer.
Claim 8
Dependent Claim 22 words
A radiation curable pressure sensitive adhesive composition as claimed in claim 4, wherein said polyoxyalkylene homopolymer or copolymer is a poly(oxyethylene-oxypropylene) copolymer.

References Cited (Backward Citations)

US3479328A Cited
US3674838A Cited
US3956224A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-09-04 1982-03-06 1982-09-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-09-04 1986-03-06 1986-09-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-09-04 1990-03-06 1990-09-05 $7700.00 Window Closed / Lapsed

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