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US4110308A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilized ethylene-tetrafluoroethylene copolymer composition

Assignee: AGC Inc
•
Filing: 1976-08-25
•
Granted: 1978-08-29
•
Expires: 1996-08-25
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Abstract

Abstract Ethylene-tetrafluorethylene copolymer compositions are stabilized against thermal degradation by incorporating therein a small amount of a copper compound.

Inventors

  • 👤 Takeshi Abe
  • 👤 Masahiko Ichimura
  • 👤 Makoto Noshiro
  • 👤 Nobuaki Kunii
  • 👤 Yasumichi Ito

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 23:02
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/10; C08K3/105; C08K3/02; C08K3/08; C08K3/18; C08K3/20; C08K3/22; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L27/00; C08L27/02; C08L27/12; C08L27/18

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 73 words
An ethylene-tetrafluoroethylene copolymer composition having improved thermal stability which comprises an ethylene-tetrafluoroethylene copolymer wherein said copolymer comprises from 30 to 60 mole % of tetrafluoroethylene units, and from 0.1 ppm to 10 wt.% of a copper compound based on the weight of the copolymer and wherein said copper compound is copper, copper oxide, or a compound which is converted to copper oxide by heating in air at the molding temperature of said copolymer.
Claim 2
Dependent Claim 73 words
An ethylene-tetrafluoroethylene copolymer composition having improved thermal stability which comprises an ethylene-tetrafluoroethylene copolymer wherein said copolymer comprises from 30 to 60 mole % of tetrafluoroethylene units, and from 0.1 ppm to 10 wt.% of a copper compound based on the weight of the copolymer and wherein said copper compound is copper, copper oxide, or a compound which is converted to copper oxide by heating in air at the molding temperature of said copolymer.
Claim 3
Dependent Claim 24 words
The composition of claim 1, wherein the copper compound is copper or a compound which is converted to copper oxide by heating in air.
Claim 4
Dependent Claim 14 words
The composition of claim 1, wherein the copper compound is supported on a carrier.
Claim 5
Dependent Claim 26 words
The composition of claim 1, wherein the copper compound is supplied by the wearing of a copper alloy machine element during the processing of said copolymer.
Claim 6
Dependent Claim 14 words
The composition of claim 1, wherein the copper compound is added together with α-alumina.
Claim 7
Dependent Claim 30 words
The composition of claim 1, wherein the copolymer comprises from about 30 to 60 mole percent of ethylene units and from about 40 to 70 mole percent of tetrafluoroethylene units.
Claim 8
Dependent Claim 21 words
The composition of claim 1, wherein the copolymer has a volumetric melt flow rate of about 10 - 300mm 3 /sec.
Claim 9
Dependent Claim 24 words
The composition of claim 1, wherein the copolymer has a flow initiation temperature of 260°-300° C and a thermal decomposition temperature of 320°-360° C.
Claim 10
Dependent Claim 17 words
The composition of claim 5, wherein the α-alumina has an average particle diameter of less than 100μm.
Claim 11
Dependent Claim 29 words
The composition of claim 1, wherein the amount of the copper compound is from 0.1 ppm to 0.1 wt% and the copper compound is uniformly dispersed in the copolymer.

References Cited (Backward Citations)

US2643988A Cited
US2985620A Cited
US3793287A Cited
US3622537A Cited
US3682859A Cited
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US3880798A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-08-28 1982-02-27 1982-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-08-28 1986-02-27 1986-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-08-28 1990-02-27 1990-08-29 $7700.00 Window Closed / Lapsed

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