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US4110288A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous vinyl polymeric emulsion system and process of preparing the same using aminoplast resin

Assignee: Wyeth Holdings LLC
•
Filing: 1976-09-01
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Granted: 1978-08-29
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Expires: 1996-09-01
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Abstract

Abstract An aqueous vinyl polymeric emulsion system prepared by polymerizing at least one polymerizable vinyl monomer in an aqueous emulsion system in the presence of an emulsifying agent, a polymerization catalyst and from about 0.1% to about 5%, by weight, based on the total weight of the monomer solids being polymerized, of a non-copolymerizable aminoplast resin.

Inventors

  • 👤 Peter J. Schirmann
  • 👤 Werner J. Blank

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 20:35
CPC Classifications
C; C08; C08F; C08F283/00; C08F2/00; C08F2/12; C08F2/16; C08F2/22; C08F2/24

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 87 words
A process for preparing an aqueous emulsion of a vinyl polymer comprising polymerizing at least one polymerizable vinyl monomer in an aqueous emulsion system in the presence of an emulsifying agent, a polymerization catalyst and from about 0.1% to about 5%, by weight, based on the weight of the monomer being polymerized, of a non-copolymerizable aminoplast resin which is water-soluble or water-dispersible in the presence of the emulsifying agent and which has been prepared from an amino compound, formaldehyde and a C 1 -C 4 monohydric alcohol.
Claim 2
Dependent Claim 87 words
A process for preparing an aqueous emulsion of a vinyl polymer comprising polymerizing at least one polymerizable vinyl monomer in an aqueous emulsion system in the presence of an emulsifying agent, a polymerization catalyst and from about 0.1% to about 5%, by weight, based on the weight of the monomer being polymerized, of a non-copolymerizable aminoplast resin which is water-soluble or water-dispersible in the presence of the emulsifying agent and which has been prepared from an amino compound, formaldehyde and a C 1 -C 4 monohydric alcohol.
Claim 3
Dependent Claim 16 words
A process according to claim 1 in which a plurality of polymerizable vinyl monomers is used.
Claim 4
Dependent Claim 19 words
A process according to claim 2 in which at least one of the vinyl monomers is an acrylic monomer.
Claim 5
Dependent Claim 16 words
A process according to claim 2 in which one of the vinyl monomers is vinyl acetate.
Claim 6
Dependent Claim 15 words
A process according to claim 3 in which the acrylic monomer is a hard monomer.
Claim 7
Dependent Claim 35 words
A process according to claim 3 in which the acrylic monomer is a functional monomer and is present in an amount up to 15%, by weight, based on the total weight of vinyl monomers present.
Claim 8
Dependent Claim 15 words
A process according to claim 3 in which the acrylic monomer is a soft monomer.
Claim 9
Dependent Claim 56 words
A process according to claim 3 in which there is present (A) up to 85 %, by weight, of a hard monomer (B) up to 85%, by weight, of a soft monomer and (C) up to 15%, by weight, of a functional monomer, wherein the total percentages of (A), (B) and (C), by weight, total 100%.
Claim 10
Dependent Claim 19 words
A process according to claim 3 in which the monomers are butyl acrylate, methyl methacrylate, acrylonitrile and methacrylic acid.
Claim 11
Dependent Claim 79 words
An aqueous emulsion of a vinyl polymer, said emulsion being produced by polymerizing at least one polymerizable vinyl monomer in an aqueous emulsion system in the presence of from about 0.1% to about 5%, by weight, based on the weight of monomer being polymerized of a non-copolymerizable aminoplast resin which is water-soluble or water-dispersible in the presence of the emulsifying agent and which has been prepared from an amino compound, formaldehyde and a C 1 -C 4 monohydric alcohol.
Claim 12
Dependent Claim 79 words
An aqueous emulsion of a vinyl polymer, said emulsion being produced by polymerizing at least one polymerizable vinyl monomer in an aqueous emulsion system in the presence of from about 0.1% to about 5%, by weight, based on the weight of monomer being polymerized of a non-copolymerizable aminoplast resin which is water-soluble or water-dispersible in the presence of the emulsifying agent and which has been prepared from an amino compound, formaldehyde and a C 1 -C 4 monohydric alcohol.
Claim 13
Dependent Claim 11 words
The process of claim 1 wherein said amino compound is melamine.
Claim 14
Dependent Claim 17 words
The process of claim 9 wherein the aminoplast resin has been prepared from melamine, formaldehyde and methanol.
Claim 15
Dependent Claim 19 words
The emulsion of claim 10 wherein butyl acrylate, methyl methacrylate, acrylonitrile and methacrylic acid are utilized as vinyl monomers.
Claim 16
Dependent Claim 18 words
The emulsion of claim 12 in which the aminoplast resin has been prepared from melamine, formaldehyde and methanol.

References Cited (Backward Citations)

US2694687A Cited
US3352838A Cited
US3365414A Cited
US3544491A Cited
US3666521A Cited
US3714078A Cited
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US3931086A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-08-28 1982-02-27 1982-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-08-28 1986-02-27 1986-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-08-28 1990-02-27 1990-08-29 $7700.00 Window Closed / Lapsed

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