US4110263A
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Mild cleansing compositions containing alkyleneoxylated bisquaternary ammonium compounds
Assignee: Johnson and Johnson Professional Inc
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Filing: 1977-06-17
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Granted: 1978-08-29
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Expires: 1997-06-17
Abstract
Abstract Mild cleansing compositions comprising at least one detergent and at least one alkyleneoxylated bisquaternary ammonium compound are described. Suitable bisquaternary ammonium compounds are represented by the formula ##STR1## wherein R is an aliphatic radical of from about 10 to about 26 carbon atoms, R' is methyl, ethyl, propyl or R, X is an anion, n is an integer from 2 to 3, and x is an integer of from 1 to about 30. Suitable detergents are anionic or amphoteric detergents. The addition of alkyleneoxylated bisquaternary ammonium compound to anionic and amphoteric detergents reduces the irritant properties of the detergents.
Inventors
- 👤 Martin K. O. Lindemann
- 👤 Robert R. Kennedy
- 👤 Robert J. Verdicchio
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 14:35
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/88; C11D1/94; A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/45; A61Q; A61Q19/00; A61Q19/10; A61Q5/00; A61Q5/02; C11D1/38; C11D1/62; C11D1/65; C11D1/02; C11D1/04; C11D1/06; C11D1/10; C11D1/12; C11D1/123; C11D1/14; C11D1/29; C11D1/886; C11D1/90; C11D1/92
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
135 words
A cosmetic cleansing composition comprising a detergent component in admixture with a alkyleneoxylated bisquaternary ammonium compound component wherein said detergent component comprises at least one detergent selected from the group consisting of an anionic detergent and an amphoteric detergent; said alkyleneoxylated bisquaternary ammonium compound component contains one or more compounds represented by the formula ##STR18## wherein R is an aliphatic radical of from about 10 to about 26 carbon atoms, R' is methyl, ethyl, propyl or R, X is an anion, n is 2 or 3, and x is an integer of from 1 to about 30; and said detergent component is present in an amount of from about 4 percent to 40 percent by weight of the composition and the weight ratio of said bisquaternary ammonium compound to detergent from 0.01:1 to about 0.3:1.
Claim 2
Dependent Claim
135 words
A cosmetic cleansing composition comprising a detergent component in admixture with a alkyleneoxylated bisquaternary ammonium compound component wherein said detergent component comprises at least one detergent selected from the group consisting of an anionic detergent and an amphoteric detergent; said alkyleneoxylated bisquaternary ammonium compound component contains one or more compounds represented by the formula ##STR18## wherein R is an aliphatic radical of from about 10 to about 26 carbon atoms, R' is methyl, ethyl, propyl or R, X is an anion, n is 2 or 3, and x is an integer of from 1 to about 30; and said detergent component is present in an amount of from about 4 percent to 40 percent by weight of the composition and the weight ratio of said bisquaternary ammonium compound to detergent from 0.01:1 to about 0.3:1.
Claim 3
Dependent Claim
14 words
A composition according to claim 1 wherein the detergent component is an anionic detergent.
Claim 4
Dependent Claim
93 words
A composition according to claim 2 wherein the anionic detergent is a polyethyleneoxylated anionic detergent represented by the formula R.sub.1 --(OCH.sub.2 CH.sub.2).sub.2-4 --Y.sup.- M.sup.+ wherein R 1 is selected from the group consisting of alkyl containing from about 8 to about 20 carbon atoms, alkylphenyl wherein the alkyl portion of the alkylphenyl contains from about 6 to about 25 carbon atoms, and acylamino wherein the acyl contains from about 8 to about 16 carbon atoms; Y is selected from the group consisting of sulfate and sulfonate; and M is a non-toxic water-soluble cation.
Claim 5
Dependent Claim
27 words
A composition according to claim 3 wherein R 1 is alkyl containing from about 8 to about 20 carbon atoms, Y is sulfate and M is sodium.
Claim 6
Dependent Claim
14 words
A composition according to claim 1 wherein the detergent component is an amphoteric detergent.
Claim 7
Dependent Claim
99 words
A composition according to claim 5 wherein the amphoteric detergent is represented by the formula ##STR19## wherein R 2 is a higher alkyl group containing from 8 to 20 carbon atoms; R 3 and R 4 are lower alkyl radicals containing from 1 to about 4 carbon atoms; Q is selected from the group consisting of alkylene containing from 1 to 3 carbon atoms, and hydroxyalkylene containing from 2 to 3 carbon atoms; Z is selected from the group consisting of carboxylate and sulfonate provided that when Z is carboxylate, Q is alkylene; and m is 0 or 1.
Claim 8
Dependent Claim
28 words
A composition according to claim 6 wherein R 3 and R 4 are methyl, Q is alkylene containing from 1 to 3 carbon atoms; and Z is carboxylate.
Claim 9
Dependent Claim
27 words
A composition according to claim 6 wherein R 3 and R 4 are methyl, Q is hydroxyalkylene containing from 2 to 3 carbon atoms; Z is sulfonate.
Claim 10
Dependent Claim
18 words
A composition according to claim 1 wherein the detergent component is a mixture of amphoteric and anionic detergents.
Claim 11
Dependent Claim
13 words
A composition according to claim 9 wherein the bisquaternary compound is dodeca(ethyleneoxy)ethylene-bis-(docosyl-dimethylammonium bromide).
Claim 12
Dependent Claim
283 words
A cosmetic cleansing composition comprising a detergent component and an alkyleneoxy bisquaternary ammonium compound component wherein said detergent component comprises a from 2:1 to 1:2 by weight mixture of (a) a polyethoxylated anionic detergent represented by the formula R.sub.1 -- (O--CH.sub.2 CH.sub.2).sub.2-4 -- Y.sup.- M.sup.+ wherein R 1 is selected from the group consisting of alkyl containing from about 8 to about 20 carbon atoms, alkylphenyl containing from about 6 to about 15 carbon atoms, and acylamino wherein the acyl contains from about 8 to about 16 carbon atoms; Y is selected from the group consisting of sulfate and sulfonate; and M is a non-toxic water-soluble cation; and (b) an amphoteric detergent represented by the formula ##STR20## wherein R 2 is a higher alkyl radical containing from 8 to 20 carbon atoms; R 3 and R 4 are lower alkyl radicals containing from 1 to about 4 carbon atoms; Q is selected from the group consisting of alkylene containing from 1 to 3 carbon atoms, and hydroxyalkylene containing from 2 to 3 carbon atoms; Z is selected from the group consisting of carboxylate and sulfonate provided that when Z is carboxylate Q is alkylene; m is 0 or 1; and said alkyleneoxy bisquaternary ammonium compound component is represented by the formula ##STR21## wherein R is an aliphatic radical of from about 10 to about 26 carbon atoms, Y is halide, and y is an integer of from 7 to about 14; and wherein said detergent component is present in an amount of from about 4 percent to about 40 percent by weight of the composition and wherein the weight ratio of said bisquaternary ammonium compound to detergent is from 0.17:1 to about 0.2:1.
Claim 13
Dependent Claim
283 words
A cosmetic cleansing composition comprising a detergent component and an alkyleneoxy bisquaternary ammonium compound component wherein said detergent component comprises a from 2:1 to 1:2 by weight mixture of (a) a polyethoxylated anionic detergent represented by the formula R.sub.1 -- (O--CH.sub.2 CH.sub.2).sub.2-4 -- Y.sup.- M.sup.+ wherein R 1 is selected from the group consisting of alkyl containing from about 8 to about 20 carbon atoms, alkylphenyl containing from about 6 to about 15 carbon atoms, and acylamino wherein the acyl contains from about 8 to about 16 carbon atoms; Y is selected from the group consisting of sulfate and sulfonate; and M is a non-toxic water-soluble cation; and (b) an amphoteric detergent represented by the formula ##STR20## wherein R 2 is a higher alkyl radical containing from 8 to 20 carbon atoms; R 3 and R 4 are lower alkyl radicals containing from 1 to about 4 carbon atoms; Q is selected from the group consisting of alkylene containing from 1 to 3 carbon atoms, and hydroxyalkylene containing from 2 to 3 carbon atoms; Z is selected from the group consisting of carboxylate and sulfonate provided that when Z is carboxylate Q is alkylene; m is 0 or 1; and said alkyleneoxy bisquaternary ammonium compound component is represented by the formula ##STR21## wherein R is an aliphatic radical of from about 10 to about 26 carbon atoms, Y is halide, and y is an integer of from 7 to about 14; and wherein said detergent component is present in an amount of from about 4 percent to about 40 percent by weight of the composition and wherein the weight ratio of said bisquaternary ammonium compound to detergent is from 0.17:1 to about 0.2:1.
Claim 14
Dependent Claim
13 words
A composition according to claim 11 wherein the bisquaternary compound is hepta(ethyleneoxy)ethylene-bis-(docosyl-dimethylammonium bromide).
Claim 15
Dependent Claim
14 words
A composition according to claim 1 wherein the detergent component is a shampoo composition.
Claim 16
Dependent Claim
15 words
A composition according to claim 1 wherein the detergent component is a baby bath composition.
Claim 17
Independent Claim
103 words
A method for reducing ocular irritancy in cosmetic cleansing compositions containing anionic or amphoteric detergents which comprises adding to the detergent composition an alkyleneoxylated bisquaternary ammonium compound represented by the formula ##STR22## wherein R is an aliphatic radical of from about 10 to about 26 carbon atoms, R' is methyl, ethyl, propyl or R, X is an anion, n is 2 or 3, and x is an integer of from 1 to about 30; wherein said alkyleneoxylated bisquaternary ammonium compound is added in an amount sufficient to provide a weight ratio of bisquaternary ammonium compound to detergent of from 0.1:1 to about 0.3:1.
Claim 18
Independent Claim
103 words
A method for reducing ocular irritancy in cosmetic cleansing compositions containing anionic or amphoteric detergents which comprises adding to the detergent composition an alkyleneoxylated bisquaternary ammonium compound represented by the formula ##STR22## wherein R is an aliphatic radical of from about 10 to about 26 carbon atoms, R' is methyl, ethyl, propyl or R, X is an anion, n is 2 or 3, and x is an integer of from 1 to about 30; wherein said alkyleneoxylated bisquaternary ammonium compound is added in an amount sufficient to provide a weight ratio of bisquaternary ammonium compound to detergent of from 0.1:1 to about 0.3:1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-08-28 | 1982-02-27 | 1982-08-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-08-28 | 1986-02-27 | 1986-08-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-08-28 | 1990-02-27 | 1990-08-29 | $7700.00 | Window Closed / Lapsed |