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US4110002A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical fibers formed of aluminum borophosphate glass compositions

Assignee: Verizon Laboratories Inc
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Filing: 1977-03-02
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Granted: 1978-08-29
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Expires: 1997-03-02
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Abstract

Abstract Novel optical fibers are formed from glass compositions enclosed by the iso-composition lines, 2 and 18 mole percent P 2 O 5 , 30 and 70 mole percent Al 2 O 3 and 20 and 60 mole percent B 2 O 3 or glass compositions bounded by lines connecting the compositions 28 m% Al 2 O 3 -- 72 m% P 2 O 5 -- 0 m% B 2 O 3 ; 5 m% Al 2 O 3 -- 45 m% P 2 O 5 -- 50 m% B 2 O 3 ; 10 m% Al 2 O 3 -- 30 m% P 2 O 5 -- 60 m% B 2 O 3 and 42 m% Al 2 O 3 -- 58 m% P 2 O 5 -- 0 m% B 2 O 3 . The glass compositions forming the optical fibers can contain the usual oxide modifiers.

Inventors

  • 👤 Richard M. Klein
  • 👤 Carr Lane W. Quackenbush
  • 👤 Andrew G. Kolbeck

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 01:48
CPC Classifications
C; C03; C03C; C03C13/00; C03C13/04; C03C13/048; C03C13/045; C03C13/046; G; G02; G02B; G02B6/00; G02B6/02; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10S501/903; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2916; Y10T428/2933; Y10T428/2964

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 265 words
An optical fiber comprising: a core having a refractive index of between 1.47 and 1.58 and formed from a glass composition selected from the group consisting of: a. a high phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by lines connecting the compositions 28 mole percent Al 2 O 3 -72 mole percent P 2 O 5 -0 mole percent B 2 O 3 ; 5 mole percent Al 2 O 3 -45 mole percent P 2 O 5 -50 mole percent B 2 O 3 ; 10 mole percent Al 2 O 3 -30 mole percent P 2 O 5 -60 mole percent B 2 O 3 ; and 42 mole percent Al 2 O 3 -58 mole percent P 2 O 5 -0 mole percent B 2 O 3 , and b. a low phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by the isocomposition lines 2 and 18 mole percent P 2 O 5 30 and 70 mole percent Al 2 O 3 , and 20 and 60 mole percent B 2 O 3 ; and a cladding formed from a glass composition selected from the group consisting of said high phosphate glass and said low phosphate glass and having a refractive index at least 0.007 less than that of the central portion of the core.
Claim 2
Dependent Claim 265 words
An optical fiber comprising: a core having a refractive index of between 1.47 and 1.58 and formed from a glass composition selected from the group consisting of: a. a high phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by lines connecting the compositions 28 mole percent Al 2 O 3 -72 mole percent P 2 O 5 -0 mole percent B 2 O 3 ; 5 mole percent Al 2 O 3 -45 mole percent P 2 O 5 -50 mole percent B 2 O 3 ; 10 mole percent Al 2 O 3 -30 mole percent P 2 O 5 -60 mole percent B 2 O 3 ; and 42 mole percent Al 2 O 3 -58 mole percent P 2 O 5 -0 mole percent B 2 O 3 , and b. a low phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by the isocomposition lines 2 and 18 mole percent P 2 O 5 30 and 70 mole percent Al 2 O 3 , and 20 and 60 mole percent B 2 O 3 ; and a cladding formed from a glass composition selected from the group consisting of said high phosphate glass and said low phosphate glass and having a refractive index at least 0.007 less than that of the central portion of the core.
Claim 3
Dependent Claim 16 words
The optical fiber of claim 1 having a core formed of said high phosphate glass composition.
Claim 4
Dependent Claim 16 words
The optical fiber of claim 1 having a core formed of said low phosphate glass composition.
Claim 5
Dependent Claim 26 words
The optical fiber of claim 1 wherein the core is formed from said high phosphate glass and the cladding is formed from said low phosphate glass.
Claim 6
Dependent Claim 26 words
The optical fiber of claim 1 wherein the core is formed from said low phosphate glass and the cladding is formed from said high phosphate glass.
Claim 7
Dependent Claim 318 words
An optical fiber comprising: a core having a refractive index of between 1.47 and 1.58 and formed from a material selected from the group consisting of: a. a mixture of a high phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by lines connecting the compositions 28 mole percent Al 2 O 3 -72 mole percent P 2 O 5 -0 mole percent B 2 O 3 ; 5 mole percent Al 2 O 3 -45 mole percent P 2 O 5 -50 mole percent B 2 O 3 ; 10 mole percent Al 2 O 3 -30 mole percent P 2 O 5 -60 mole percent B 2 O 3 ; 42 mole percent Al 2 O 3 -58 mole percent P 2 O 5 - 0 mole percent B 2 O 3 ; and an oxide modifier; and b. a mixture of a low phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by the isocomposition lines 2 and 18 mole percent P 2 O 5 , 30 and 70 mole percent Al 2 O 3 , 20 and 60 mole percent B 2 O 3 ; and an oxide modifier, said oxide modifier selected from the group consisting of SiO 2 , MgO, CaO, TiO 2 , ZrO 2 , Na 2 O, CdO, ZnO, SnO 2 , and CeO 2 , present in an amount less than 40 mole percent; and a cladding formed from a glass composition selected from the group consisting of said high phosphate glass and said low phosphate glass having a refractive index at least 0.007 less than that of the central portion of the core.
Claim 8
Dependent Claim 318 words
An optical fiber comprising: a core having a refractive index of between 1.47 and 1.58 and formed from a material selected from the group consisting of: a. a mixture of a high phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by lines connecting the compositions 28 mole percent Al 2 O 3 -72 mole percent P 2 O 5 -0 mole percent B 2 O 3 ; 5 mole percent Al 2 O 3 -45 mole percent P 2 O 5 -50 mole percent B 2 O 3 ; 10 mole percent Al 2 O 3 -30 mole percent P 2 O 5 -60 mole percent B 2 O 3 ; 42 mole percent Al 2 O 3 -58 mole percent P 2 O 5 - 0 mole percent B 2 O 3 ; and an oxide modifier; and b. a mixture of a low phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by the isocomposition lines 2 and 18 mole percent P 2 O 5 , 30 and 70 mole percent Al 2 O 3 , 20 and 60 mole percent B 2 O 3 ; and an oxide modifier, said oxide modifier selected from the group consisting of SiO 2 , MgO, CaO, TiO 2 , ZrO 2 , Na 2 O, CdO, ZnO, SnO 2 , and CeO 2 , present in an amount less than 40 mole percent; and a cladding formed from a glass composition selected from the group consisting of said high phosphate glass and said low phosphate glass having a refractive index at least 0.007 less than that of the central portion of the core.
Claim 9
Dependent Claim 301 words
An optical fiber comprising: a core having a refractive index of between 1.47 and 1.58 and formed from a glass composition selected from the group consisting of: a. a high phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by lines connecting the compositions 28 mole percent Al 2 O 3 -72 mole percent P 2 O 5 -0 mole percent B 2 O 3 ; 5 mole percent Al 2 O 3 -45 mole percent P 2 O 5 -50 mole percent B 2 O 3 ; 10 mole percent Al 2 O 3 -30 mole percent P 2 O 5 -60 mole percent B 2 O 3 ; and 42 mole percent Al 2 O 3 - 58 mole percent P 2 O 5 -0 mole percent B 2 O 3 ; and b. a low phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by the isocomposition lines 2 and 18 mole percent P 2 O 5 , 30 and 70 mole percent Al 2 O 3 , and 20 and 60 mole percent B 2 O 3 ; and a cladding formed from a material selected from the group consisting of a mixture of said high phosphate glass and an oxide modifier, a mixture of said low phosphate glass and an oxide modifier, said oxide modifier selected from the group consisting of SiO 2 , MgO, CaO, TiO 2 , ZrO 2 , Na 2 O, CdO, ZnO, SnO 2 and CeO 2 , present in an amount less than 40 mole percent.
Claim 10
Dependent Claim 301 words
An optical fiber comprising: a core having a refractive index of between 1.47 and 1.58 and formed from a glass composition selected from the group consisting of: a. a high phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by lines connecting the compositions 28 mole percent Al 2 O 3 -72 mole percent P 2 O 5 -0 mole percent B 2 O 3 ; 5 mole percent Al 2 O 3 -45 mole percent P 2 O 5 -50 mole percent B 2 O 3 ; 10 mole percent Al 2 O 3 -30 mole percent P 2 O 5 -60 mole percent B 2 O 3 ; and 42 mole percent Al 2 O 3 - 58 mole percent P 2 O 5 -0 mole percent B 2 O 3 ; and b. a low phosphate glass of a composition lying within the region of a ternary Al 2 O 3 -P 2 O 5 -B 2 O 3 composition diagram wherein said region is bounded by the isocomposition lines 2 and 18 mole percent P 2 O 5 , 30 and 70 mole percent Al 2 O 3 , and 20 and 60 mole percent B 2 O 3 ; and a cladding formed from a material selected from the group consisting of a mixture of said high phosphate glass and an oxide modifier, a mixture of said low phosphate glass and an oxide modifier, said oxide modifier selected from the group consisting of SiO 2 , MgO, CaO, TiO 2 , ZrO 2 , Na 2 O, CdO, ZnO, SnO 2 and CeO 2 , present in an amount less than 40 mole percent.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-08-28 1982-02-27 1982-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-08-28 1986-02-27 1986-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-08-28 1990-02-27 1990-08-29 $7700.00 Window Closed / Lapsed

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