US4109043A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Low pressure melamine resin laminates
Assignee: Formica Corp
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Filing: 1977-02-11
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Granted: 1978-08-22
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Expires: 1997-02-11
Abstract
Abstract A heat and pressure consolidated structure comprising, in superimposed relationship, A a self-supporting substrate, and B a decorative α-cellulose paper sheet impregnated with a resin composition comprising A mixture of a melamine/formaldehyde resin, an elastomer comprising an ethylene/vinyl chloride copolymer containing amide groups, a butadiene/acrylonitrile copolymer containing carboxyl groups or a polyurethane resin containing carboxyl groups and an alkylene polyamine, is disclosed.
Inventors
- 👤 Darwin Fiske DeLapp
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 01:32
CPC Classifications
B; B32; B32B; B32B21/00; B32B21/04; B32B21/06; B44; B44C; B44C5/00; B44C5/04; B44C5/0469; D; D21; D21H; D21H17/00; D21H17/03; D21H17/05; D21H17/07; D21H17/20; D21H17/33; D21H17/34; D21H17/35; D21H17/37; D21H17/41; D21H17/42; D21H17/43; D21H17/46; D21H17/47; D21H17/49; D21H17/51; D21H17/54; D21H17/56; D21H17/57; B32B2317/00; B32B2317/12; B32B2317/125; B32B2451/00; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24851; Y10T428/24868; Y10T428/24876; Y10T428/24893; Y10T428/24934; Y10T428/25; Y10T428/254; Y10T428/31504; Y10T428/31855; Y10T428/31859; Y10T428/31862; Y10T428/31866; Y10T428/31942; Y10T428/31949; Y10T428/31964
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
224 words
A heat and pressure consolidated article comprising A. a self-supporting substrate and B. a decorative, cellulosic paper sheet having a basis weight of at least about 40 pounds per 3,000 square foot ream, containing at least about 60% α-cellulose and being impregnated with a composition of matter comprising a mixture of 1. an aqueous melamine/formaldehyde resin solution wherein the melamine to formaldehyde ratio thereof ranges from about 1:1.6 to about 1:2.5, 2. from about 2.5% to about 30.0%, by weight, based on the weight of the resin solids of (1), of an elastomer comprising a. an ethylene/vinyl chloride copolymer containing a comonomer supplying from about 0.5% to about 7.0%, by weight, based on the total weight of (a), of amide groups, b. a polyurethane resin containing from about 3.0% to about 10.0%, by weight, based on the total weight of (b), of carboxyl groups, or c. a butadiene/acrylonitrile polymer containing from about 1% to about 10%, by weight, based on the total weight of (c), of carboxyl groups, said elastomer having a particle size of up to about 20,000 Angstroms, and 3. from about 0.25 to about 1.25%, by weight, based on the total weight of solids in said composition, of an alkylene polyamine having the formula H.sub.2 N--CH.sub.2 CH.sub.2 NH].sub.n CH.sub.2 CH.sub.2 NH.sub.2 wherein n is a whole, positive integer of 0-3, inclusive.
Claim 2
Dependent Claim
224 words
A heat and pressure consolidated article comprising A. a self-supporting substrate and B. a decorative, cellulosic paper sheet having a basis weight of at least about 40 pounds per 3,000 square foot ream, containing at least about 60% α-cellulose and being impregnated with a composition of matter comprising a mixture of 1. an aqueous melamine/formaldehyde resin solution wherein the melamine to formaldehyde ratio thereof ranges from about 1:1.6 to about 1:2.5, 2. from about 2.5% to about 30.0%, by weight, based on the weight of the resin solids of (1), of an elastomer comprising a. an ethylene/vinyl chloride copolymer containing a comonomer supplying from about 0.5% to about 7.0%, by weight, based on the total weight of (a), of amide groups, b. a polyurethane resin containing from about 3.0% to about 10.0%, by weight, based on the total weight of (b), of carboxyl groups, or c. a butadiene/acrylonitrile polymer containing from about 1% to about 10%, by weight, based on the total weight of (c), of carboxyl groups, said elastomer having a particle size of up to about 20,000 Angstroms, and 3. from about 0.25 to about 1.25%, by weight, based on the total weight of solids in said composition, of an alkylene polyamine having the formula H.sub.2 N--CH.sub.2 CH.sub.2 NH].sub.n CH.sub.2 CH.sub.2 NH.sub.2 wherein n is a whole, positive integer of 0-3, inclusive.
Claim 3
Dependent Claim
23 words
An article according to claim 1 wherein the percentage of said (2) ranges from about 5.0% to about 25.0%, by weight, same basis.
Claim 4
Dependent Claim
19 words
An article according to claim 1 wherein said elastomer has a particle size of up to about 4,000 Angstroms.
Claim 5
Dependent Claim
19 words
An article according to claim 1 wherein said elastomer has a particle size of up to about 1,000 Angstroms.
Claim 6
Dependent Claim
11 words
An article according to claim 1 wherein said elastomer is (a).
Claim 7
Dependent Claim
12 words
An article according to claim 1 wherein said elastomer is (b) .
Claim 8
Dependent Claim
12 words
An article according to claim 1 wherein said (3) is tetraethylene pentamine.
Claim 9
Dependent Claim
12 words
An article according to claim 1 wherein said (3) is triethylene tetramine.
Claim 10
Dependent Claim
11 words
An article according to claim 1 wherein said elastomer is (c).
Claim 11
Dependent Claim
194 words
A method for the production of the article of claim 1 which comprises heat and pressure consolidating, in superimposed relationship, A. a self-supporting substrate and B. a decorative, cellulosic paper sheet having a basis weight of at least about 40 pounds per 3,000 square foot ream, containing at least about 60% α-cellulose and being impregnated with a composition of matter comprising a mixture of 1. an aqueous melamine/formaldehyde resin solution wherein the melamine to formaldehyde ratio thereof ranges from about 1:1.6 to about 1:2.5, 2. from about 2.5% to about 30.0%, by weight, based on the weight of the resin solids of (1), of an elastomer comprising a. an ethylene/vinyl chloride copolymer containing a comonomer supplying from about 0.5% to about 7.0%, by weight, based on the total weight of (a), of amide groups, b. a polyurethane resin containing from about 3.0% to about 10.0%, by weight, based on the total weight of (b) of carboxyl groups, or c. a butadiene/acrylonitrile copolymer contianing from about 1% to about 10%, by weight, based on the total weight of (c), of carboxyl groups, said elastomer having a particles size of up to about 20,000 Angstroms, and
Claim 12
Dependent Claim
47 words
from about 0.25 to about 1.25%, by weight, based on the total weight of solids in said composition, of an alkylene polyamine having the formula H.sub.2 NCH.sub.2 CH.sub.2 NH.sub.n CH.sub.2 CH.sub.2 NH.sub.2 wherein n is a whole, positive integer of 0-3, inclusive, and recovering the resultant article.
Claim 13
Dependent Claim
47 words
from about 0.25 to about 1.25%, by weight, based on the total weight of solids in said composition, of an alkylene polyamine having the formula H.sub.2 NCH.sub.2 CH.sub.2 NH.sub.n CH.sub.2 CH.sub.2 NH.sub.2 wherein n is a whole, positive integer of 0-3, inclusive, and recovering the resultant article.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-08-21 | 1982-02-20 | 1982-08-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-08-21 | 1986-02-20 | 1986-08-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-08-21 | 1990-02-20 | 1990-08-22 | $7700.00 | Window Closed / Lapsed |