Abstract A hard sintered carbide composition and the method of making such composition for use as a cutting material or for use as wear parts or dies and the like, is disclosed. The composition consists essentially of a titanium carbide phase bound together by a binding alloy principally composed of molybdenum and nickel; the titanium carbide contains controlled amounts of dissolved vanadium carbide and/or titanium nitride. The binding alloy is characterized by the addition of aluminum in controlled amounts and chromium may be added to the binding alloy as a partial substitute for some of the aluminum. The presence of the dissolved vanadium carbide and/or titanium nitride produces a grain refinement in the carbide phase and the presence of the aluminum tends to form a nickel aluminide in the binding alloy which is of a finely divided character. The presence of two or more of the elements; vanadium carbide, titanium nitride and aluminum produce an unprecedented improvement in the deformation resistance of a TiC--Ni--Mo composition. The method requires that the binding alloy powder and the carbide powders be selected as to size (about 3-4 microns) be milled with the additive powders and the compacted charge then be sintered at about 1400° C in closed graphite trays in a furnace evacuated to less than 1 micron of mercury pressure.
A method of making a sintered compact useful as a cutting tool and having improved nose push resistance and increased grain refinement, the method comprising: (a) blending together a titanium carbide powder, nickel-coated aluminum powder, at least one of molybdenum powder and molybdenum carbide powder, an additive powder having vanadium carbide and titanium nitride, (b) milling said powders in the presence of a waxy lubricant, cemented carbide media, and acetone for a sufficient time to achieve thorough homogeneity and blending, (c) drying said blended powders and screening to -20 mesh, (d) compacting said screened blended powders under a force between 16,000 and 24,000 psi and heating to dewax said compact under a dry hydrogen atmosphere, and (e) preparing closed graphite trays and inserting said compacted powders thereinto while evacuating the furnace and holding trays to less than one micron mercury, sintering said compact and said close graphite trays at a temperature of about 1400° C for a period of about 1 hour.
Claim 2
Independent Claim
162 words
A method of making a sintered compact useful as a cutting tool and having improved nose push resistance and increased grain refinement, the method comprising: (a) blending together a titanium carbide powder, nickel-coated aluminum powder, at least one of molybdenum powder and molybdenum carbide powder, an additive powder having vanadium carbide and titanium nitride, (b) milling said powders in the presence of a waxy lubricant, cemented carbide media, and acetone for a sufficient time to achieve thorough homogeneity and blending, (c) drying said blended powders and screening to -20 mesh, (d) compacting said screened blended powders under a force between 16,000 and 24,000 psi and heating to dewax said compact under a dry hydrogen atmosphere, and (e) preparing closed graphite trays and inserting said compacted powders thereinto while evacuating the furnace and holding trays to less than one micron mercury, sintering said compact and said close graphite trays at a temperature of about 1400° C for a period of about 1 hour.