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US4104283A Expired / Lapsed US ⏱️ 0.0 years remaining

Polythioetheralkyleneoxide epoxides

Assignee: Dow Chemical Co
•
Filing: 1971-11-26
•
Granted: 1978-08-01
•
Expires: 1991-11-26
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Abstract

Abstract New compounds of the structure ##STR1## WHERE R is an aromatic, alicyclic or aliphatic group of at least 2 C atoms and up to 18 C atoms, x is an integer from 1 to 9, R' is H, a lower alkyl grup of 1-4 C atoms or --CH 2 Cl, y is an integer of from 0-10 and z is an integer of from 2 to 6 are prepared by reacting a polythioetherpolythiol with an olefinically unsaturated epoxide or by dehydrohalogenating the corresponding halohydrins. The new compounds are useful as diluents for epoxy resins to reduce their viscosity and to improve flexibility of the cured resins.

Inventors

  • 👤 Richard A. Hickner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 18:21
CPC Classifications
C; C07; C07D; C07D303/00; C07D303/02; C07D303/12; C07D303/18; C07D303/20; C07D303/22; C07D303/24; C08; C08G; C08G59/00; C08G59/02; C08G59/18; C08G59/20; C08G59/22; C08G59/30; C08G59/302

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 127 words
Compounds of the structure ##STR12## wherein x is an integer from 1 to 9, R' is H, an alkyl group of from 1 to 4 C atoms or CH 2 Cl, y is an integer from 0 to 10, z is an integer from 2 to 3 and R is --(CH 2 ) 2 O(CH 2 ) 2 , --(CH 2 ) 3 O(CH 2 ) 3 --, --(CH 2 ) 2 S(CH 2 ) 2 --, --(CH 2 ) 2 S(CH 2 ) 2 S(CH 2 ) 2 --, --(CH 2 ) 2 S(CH 2 ) 2 O(CH 2 ) 2 S(CH 2 ) 2 --, ##STR13## the reaction product of a polyallyl ether of penterythritol having an average of about 3.5 allyl groups and 1,2-ethanedithiol.
Claim 2
Dependent Claim 127 words
Compounds of the structure ##STR12## wherein x is an integer from 1 to 9, R' is H, an alkyl group of from 1 to 4 C atoms or CH 2 Cl, y is an integer from 0 to 10, z is an integer from 2 to 3 and R is --(CH 2 ) 2 O(CH 2 ) 2 , --(CH 2 ) 3 O(CH 2 ) 3 --, --(CH 2 ) 2 S(CH 2 ) 2 --, --(CH 2 ) 2 S(CH 2 ) 2 S(CH 2 ) 2 --, --(CH 2 ) 2 S(CH 2 ) 2 O(CH 2 ) 2 S(CH 2 ) 2 --, ##STR13## the reaction product of a polyallyl ether of penterythritol having an average of about 3.5 allyl groups and 1,2-ethanedithiol.
Claim 3
Dependent Claim 21 words
Compounds of claim 1 in which R is ##STR14## , x is 1 and y is 0 and z is 3.
Claim 4
Dependent Claim 9 words
Compounds of claim 1 in which R is ##STR15##
Claim 5
Dependent Claim 9 words
Compounds of claim 1 in which R is ##STR16##
Claim 6
Dependent Claim 9 words
Compounds of claim 1 in which R is ##STR17##
Claim 7
Dependent Claim 9 words
Compounds of claim 1 in which R is ##STR18##
Claim 8
Dependent Claim 17 words
Compounds of claim 1 in which R is --(CH 2 ) 2 S(CH 2 ) 2 --.
Claim 9
Dependent Claim 13 words
Compounds of claim 3 in which x is 1 and y is 0.
Claim 10
Dependent Claim 13 words
Compounds of claim 4 in which x is 1 and y is 0.
Claim 11
Dependent Claim 13 words
Compounds of claim 5 in which x is 1 and y is 0.
Claim 12
Dependent Claim 13 words
Compounds of claim 6 in which x is 1 and y is 0.
Claim 13
Dependent Claim 16 words
Compounds of claim 3 in which x is 1, R' is H and y is 0.

References Cited (Backward Citations)

US2731437A Cited
US2965652A Cited
US3454539A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-31 1982-01-30 1982-08-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-31 1986-01-30 1986-08-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-31 1990-01-30 1990-08-01 $7700.00 Window Closed / Lapsed

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