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US4101496A Expired / Lapsed US ⏱️ 0.0 years remaining

Highly pigmentable, liquid coating compositions

Assignee: Huels AG
•
Filing: 1975-12-02
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Granted: 1978-07-18
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Expires: 1995-12-02
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Abstract

Abstract Liquid, highly pigmentable coating compositions containing little or no solvent and which are suitable for spray coating employ a binder consisting either of A. 45-10% by weight of an aminoplast, a low-molecular weight precursor thereof, or a mixture thereof, and B. 55-90% of an at least bifunctional polyester, or a mixture thereof, having predominantly hydroxy end groups, a degree of condensation of between 2.5 and 10.5 and a molecular weight of up to 1,000, and prepared by condensing an alcohol component consisting of 0-30 molar percent of one or more 3-6 carbon atom polyols having 3-4 hydroxy groups and 100-70 molar percent of a mixture of diols consisting of 33-90 molar percent of ethylene glycol and 67-10 molar percent of 1,2-propanediol, or a condensation product of A and B.

Inventors

  • 👤 Jorg Dorffel
  • 👤 Werner Andrejewski
  • 👤 Uwe Biethan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 11:23
CPC Classifications
C; C09; C09D; C09D167/00

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 205 words
In a liquid coating composition containing 0-25% solvent and a binder consisting essentially of A. 45-10% by weight of an aminoplast, a low-molecular weight precursor thereof, or a mixture thereof; and B. 55-90% by weight of a polyester, or mixture thereof, whose end groups are predominantly hydroxy prepared by condensing an alcohol component consisting of: I.1 0- 30 molar percent of one or more aliphatic polyols having 3 or 4 hydroxy groups and 3-6 carbon atoms, and I.2 100-70 molar percent of a mixture of ethylene glycol and 1,2-propanediol, with an acid component whose predominant acid is hexahydroterephthalic acid; or a binder which is the condensation product of said aminoplast component, or the starting materials for the production thereof, with said polyester component, the improvement wherein (i) the polyester or mixture of polyesters of component (B) have a degree of condensation of between 2.5 and 10.5 and an average molecular weight of up to 1,000, and the (ii) the mixture of ethylene glycol and 1,2-propanediol consists of 33-90 molar percent of ethylene glycol and 67-10 molar percent of 1,2-propanediol, and (iii) the acid component mixture consists essentially of at least 80 molar percent of hexahydroterephthalic acid, one or more derivatives thereof, or a mixture thereof.
Claim 2
Dependent Claim 205 words
In a liquid coating composition containing 0-25% solvent and a binder consisting essentially of A. 45-10% by weight of an aminoplast, a low-molecular weight precursor thereof, or a mixture thereof; and B. 55-90% by weight of a polyester, or mixture thereof, whose end groups are predominantly hydroxy prepared by condensing an alcohol component consisting of: I.1 0- 30 molar percent of one or more aliphatic polyols having 3 or 4 hydroxy groups and 3-6 carbon atoms, and I.2 100-70 molar percent of a mixture of ethylene glycol and 1,2-propanediol, with an acid component whose predominant acid is hexahydroterephthalic acid; or a binder which is the condensation product of said aminoplast component, or the starting materials for the production thereof, with said polyester component, the improvement wherein (i) the polyester or mixture of polyesters of component (B) have a degree of condensation of between 2.5 and 10.5 and an average molecular weight of up to 1,000, and the (ii) the mixture of ethylene glycol and 1,2-propanediol consists of 33-90 molar percent of ethylene glycol and 67-10 molar percent of 1,2-propanediol, and (iii) the acid component mixture consists essentially of at least 80 molar percent of hexahydroterephthalic acid, one or more derivatives thereof, or a mixture thereof.
Claim 3
Dependent Claim 13 words
A coating composition of claim 1 wherein the acid component is dimethyl hexahydroterephthalate.
Claim 4
Dependent Claim 19 words
A coating compositions of claim 1 wherein the polyester component (B) has an average molecular weight of below 800.
Claim 5
Dependent Claim 7 words
A pigmented coating composition of claim 1.
Claim 6
Dependent Claim 22 words
A coating composition of claim 4 wherein the binder to pigment weight ratio is from 1 : 0.3 to 1 : 1.3.
Claim 7
Dependent Claim 9 words
A coating composition of claim 1 containing 0-15% solvent.
Claim 8
Dependent Claim 32 words
A coating composition of claim 1 wherein the acid component is a mixture of 100-90 mol-% of dimethyl hexahydroterephthalate and 0-10 mol-% of either or both of adipic acid and phthalic anhydride.
Claim 9
Dependent Claim 104 words
A coating composition of claim 1 consisting essentially of, alone or in admixture with pigment: I. solvent: 0-15%; Ii. binder: 100-85%; A. aminoplast: hexamethylolmelamine partially or completely etherified with a C 1 to C 4 alkanol or melamineformaldehyde-alkanol condensate; B. polyester: acid number: less than 10 mg. KOH/g; average molecular weight: 300 to 800; 1. alcohol component: a. 100-80 mol-% of ethylene glycol (66.7 - 90 mol-%) and propylene glycol (33.3 - 10 mol-%); b. 0-20 mol-% of another diol or polyol; 2. acid component: a. 100-90 mol-% of dimethyl hexahydroterephthalate; b. 0-10 mol-% of either or both of phthalic anhydride and adipic acid;
Claim 10
Dependent Claim 37 words
molar ratio of alcohol component to acid component: n moles of diol, m moles of polyol and about (n + m-1) moles of acid component; Iii. weight ratio of polyester component to aminoplast: component: 65:35 to 85:15.
Claim 11
Dependent Claim 37 words
molar ratio of alcohol component to acid component: n moles of diol, m moles of polyol and about (n + m-1) moles of acid component; Iii. weight ratio of polyester component to aminoplast: component: 65:35 to 85:15.
Claim 12
Dependent Claim 23 words
A coating composition of claim 8 containing pigment in a binder : pigment ratio of from 1 : 0.3 to 1 : 1.3.

References Cited (Backward Citations)

US3553284A Cited
US3678128A Cited
US3691258A Cited
US3852375A Cited
US3819757A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-17 1982-01-16 1982-07-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-17 1986-01-16 1986-07-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-17 1990-01-16 1990-07-18 $7700.00 Window Closed / Lapsed

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