US4101491A
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Ethylenically unsaturated blocked aromatic diisocyanates and polymers thereof
Assignee: Goodrich Corp
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Filing: 1976-10-22
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Granted: 1978-07-18
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Expires: 1996-10-22
Abstract
Abstract Ethylenically unsaturated blocked aromatic diisocyanates are prepared which readily polymerize to form homopolymers and interpolymers with copolymerizable vinylidene monomers. Polymers can be prepared via emulsion polymerization, and exhibit excellent stability to hydrolysis when stored in latex form. The polymers cure at temperatures as low as 80° C., and under acidic, neutral, or basic pH conditions. Homopolymers and interpolymers of the defined diisocyanates are useful as adhesives, and interpolymers of the ethylenically unsaturated blocked aromatic diisocyanates with acrylate monomers are particularly useful as binders for nonwoven fibers.
Inventors
- 👤 Harold A. Tucker
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 03:38
CPC Classifications
C; C07; C07D; C07D231/00; C07D231/02; C07D231/10; C07D231/12; C07D249/00; C07D249/16; C07D249/18; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/34; C08F20/36
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
147 words
A latex comprising (A) water and (B) a polymer comprising from about 0.1 percent to 100 percent by weight of polymerized units of an ethylenically unsaturated blocked aromatic diisocyanate of the formula ##STR33## wherein R is hydrogen or a methyl or ethyl radical; A is a carbonyloxyalkylene radical containing 2 to about 8 carbon atoms or an aralkylene radical containing 7 to about 12 carbon atoms; B is a bivalent aromatic radical selected from the group consisting or arylene, naphthalene, and the structure ##STR34## where R is defined as above; Y is O, S, or --CH 2 ) n ; n = 0 to 3; and X is the radical fragment remaining after a hydrogen atom is removed from the nitrogen atom of an oxime, benzimidazole, pyrazole, benzotriazole, caprolactam, thiocaprolactam, or p-nitroaniline, and up to 99.9 percent by weight of polymerized units of a copolymerizable vinylidene monomer.
Claim 2
Dependent Claim
147 words
A latex comprising (A) water and (B) a polymer comprising from about 0.1 percent to 100 percent by weight of polymerized units of an ethylenically unsaturated blocked aromatic diisocyanate of the formula ##STR33## wherein R is hydrogen or a methyl or ethyl radical; A is a carbonyloxyalkylene radical containing 2 to about 8 carbon atoms or an aralkylene radical containing 7 to about 12 carbon atoms; B is a bivalent aromatic radical selected from the group consisting or arylene, naphthalene, and the structure ##STR34## where R is defined as above; Y is O, S, or --CH 2 ) n ; n = 0 to 3; and X is the radical fragment remaining after a hydrogen atom is removed from the nitrogen atom of an oxime, benzimidazole, pyrazole, benzotriazole, caprolactam, thiocaprolactam, or p-nitroaniline, and up to 99.9 percent by weight of polymerized units of a copolymerizable vinylidene monomer.
Claim 3
Dependent Claim
54 words
A latex of claim 1 wherein (B) is a polymer comprising from about 1 percent to about 30 percent by weight of an ethylenically unsaturated blocked aromatic diisocyanate, from about 20 percent to about 99 percent by weight of an acrylate monomer, and up to 20 percent by weight of another copolymerizable vinylidene monomer.
Claim 4
Dependent Claim
45 words
A latex of claim 2 where in (B), in the ethylenically unsaturated blocked aromatic diisocyanate, R is hydrogen or a methyl radical, B is phenylene, tolylene, naphthalene, or the defined structure wherein Y is --CH 2 ) n , and n = 0 or 1.
Claim 5
Dependent Claim
79 words
A latex of claim 3 where in (B), in the polymer, the acrylate monomer is one or more monomers of the formula ##STR35## where R is hydrogen or a methyl or ethyl radical, and R a is selected from the group consisting of an alkyl radical containing 1 to about 24 carbon atoms, an alkoxyalkyl or alkylthioalkyl radical containing a total of 2 to about 12 carbon atoms, and a cyanoalkyl radical containing 2 to about 12 carbon atoms.
Claim 6
Dependent Claim
39 words
A latex of claim 4 where in (B), in the formula of the acrylate monomer, R a is an alkyl radical containing 1 to about 18 carbon atoms or an alkoxyalkyl radical containing 2 to about 8 carbon atoms.
Claim 7
Dependent Claim
11 words
A latex of claim 5 which additionally contains a crosslinking agent.
Claim 8
Dependent Claim
22 words
A latex of claim 5 wherein the crosslinking agent is selected from the group consisting of alkylene diols, alkylene diamines, and alkanolamines.
Claim 9
Dependent Claim
31 words
A latex of claim 5 where in (B) the acrylate monomer is ethyl acrylate and the copolymerizable vinylidene monomer is selected from the group consisting of acrylonitrile, styrene, and acrylic acid.
Claim 10
Dependent Claim
19 words
A latex of claim 8 where in (B), the ethylenically unsaturated blocked aromatic diisocyanate employed has the formula ##STR36##
Claim 11
Dependent Claim
19 words
A latex of claim 8 where in (B), the ethylenically unsaturated blocked aromatic diisocyanate employed has the formula ##STR37##
Claim 12
Dependent Claim
19 words
A latex of claim 8 where in (B), the ethylenically unsaturated blocked aromatic diisocyanate employed has the formula ##STR38##
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-17 | 1982-01-16 | 1982-07-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-17 | 1986-01-16 | 1986-07-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-17 | 1990-01-16 | 1990-07-18 | $7700.00 | Window Closed / Lapsed |