Coating medium

Claim 2

A heat curable coating medium comprising an aromatic diamide diacid diamine formed as the reaction product of an aromatic diamine and an aromatic dianhydride, in the molar ratio of two-to-one respectively, at a temperature below that at which more than negligible imidization occurs, in an inert solvent for at least one of said reactants, a coating of said medium on a substrate being heat curable at imidization temperature to form a cured highly cross-linked polymeric coating thereon.

Claim 3

A coating medium comprising an aromatic diamide diacid diamine formed as the reaction product of an aromatic diamine and an aromatic dianhydride, in the molar ratio of two-to-one respectively, at a temperature below that at which more than negligible imidization occurs, a volatile base, and an aqueous-organic solvent medium wherein the organic portion of said solvent medium is a water miscible inert solvent for at least one of said reactants, said reaction product being heat curable at imidization temperature after application of said coating medium as a thin film coating on a substrate, to form a highly cross-linked polymeric coating including imide groups, amide groups and amine groups and being substantially free of carboxyl groups.

Claim 4

A coating medium comprising an aromatic diamide diacid diamine formed as the reaction product of an aromatic diamine and an aromatic dianhydride, in the molar ratio of two-to-one respectively, at a temperature below that at which more than negligible imidization occurs, a volatile base, and an aqueous-organic solvent medium wherein the organic portion of said solvent medium is a water miscible inert solvent for at least one of said reactants, said reaction product being heat curable at imidization temperature after application of said coating medium as a thin film coating on a substrate, to form a highly cross-linked polymeric coating including imide groups, amide groups and amine groups and being substantially free of carboxyl groups.

Claim 5

The coating medium defined in claim 2 wherein: said dianhydride is selected from the group consisting of: 4,4'-(2-acetoxy-1,3-glyceryl)bis-anhydro trimellitate, 3,3', 4,4'-benzophenonetetracarboxylic dianhydride, bis(3,4-dicarboxyphenyl) sulfone dianhydride, bis(2,3-dicarboxyphenyl) methane dianhydride, 2,2-bis (3,4-dicarboxyphenyl)propane dianhydride, bis (3,4-dicarboxyphenyl)ether dianhydride, 2,2-bis(2,3-dicarboxyphenylpropane dianhydride, 1,1-bis(2,3-dicarboxyphenyl)ethane dianhydride, 1,1-bis(3,4-dicarboxyphenyl)ethane dianhydride, and the like. and said diamine is selected from the group consisting of: meta-phenylene diamine, para-phenylenediamine, 4,4'-diamino-diphenyl propane, 4,4'-diamino-diphenyl methane, benzidine, 4,4'-diamino-diphenyl sulfide, 4,4'-diamino-diphenyl sulfone, 3,3'-diamino-diphenyl sulfone, 4,4'-diamino-diphenyl ether, 2,6-diamino-pyridine, bis-(4-amino-phenyl)diethyl silane, bis-(4-amino-phenyl) phosphine oxide, bis-(4-amino-phenyl)-N-methylamine, 1,5-diamino naphthalene, 3,3'-dimethyl-4,4'-diamino-biphenyl, 3,3'-dimethoxy benzidine, m-xylene diamine, p-xylene diamine, 1,3-bis-delta-amino-butyltetramethyl disiloxane, and 1,3-bis-gamma-aminopropyltetraphenyl disiloxane.

Claim 6

The coating medium defined in claim 2 wherein: said diamine is selected from the group consisting of 4,4'-diaminodiphenyl methane, 4,4'-diaminodiphenyl ether, and 1,3-diamino benzene, and said dianhydride is selected from the group consisting of 3,3',4,4'-benzophenonetetracarboxylic dianhydride and 4,4'-(2-acetoxy-1,3-glyceryl)bis-anhydro trimellitate.

Claim 7

A heat curable coating medium comprising an aromatic diamide diacid diamine formed as the reaction product of an aromatic diamine and a tetracarboxylic compound, in the molar ratio of two-to-one respectively, at a temperature below that at which more than negligible imidization occurs, in a inert solvent for at least one of said reactants, a coating of said medium on a substrate being heat curable at imidizaton temperature to form a cured highly cross-linked polymeric coating thereon.

Claim 8

A heat curable coating medium comprising an aromatic diamide diacid diamine formed as the reaction product of an aromatic diamine and a tetracarboxylic compound, in the molar ratio of two-to-one respectively, at a temperature below that at which more than negligible imidization occurs, in a inert solvent for at least one of said reactants, a coating of said medium on a substrate being heat curable at imidizaton temperature to form a cured highly cross-linked polymeric coating thereon.

Claim 9

A coating medium comprising an aromatic diamide diacid diamine formed as the reaction product of an aromatic diamine and a tetracarboxylic compound, in the molar ratio of two-to-one respectively, at a temperature below that at which more than negligible imidization occurs, a volatile base, and an aqueous-organic solvent medium wherein the organic portion of said solvent medium is a water miscible inert solvent for at least one of said reactants, said reaction product being heat curable at imidization temperature after application of said coating medium as a thin film coating on a substrate, to form a highly cross-linked polymeric coating including imide groups, amide groups and amine groups and being substantially free of carboxyl groups.

Claim 10

A coating medium comprising an aromatic diamide diacid diamine formed as the reaction product of an aromatic diamine and a tetracarboxylic compound, in the molar ratio of two-to-one respectively, at a temperature below that at which more than negligible imidization occurs, a volatile base, and an aqueous-organic solvent medium wherein the organic portion of said solvent medium is a water miscible inert solvent for at least one of said reactants, said reaction product being heat curable at imidization temperature after application of said coating medium as a thin film coating on a substrate, to form a highly cross-linked polymeric coating including imide groups, amide groups and amine groups and being substantially free of carboxyl groups.

Claim 11

The coating medium defined in claim 6 wherein: said tetracarboxylic compound is a dianhydride selected from the group consisting of: 4,4'-(2-acetoxy-1,3-glyceryl)bis-anhydro trimellitate, 3,3'-4,4'-benzophenonetetracarboxylic dianhydride, bis(3,4-dicarboxyphenyl) sulfone dianhydride, bis(2,3-dicarboxyphenyl) methane dianhydride, 2,2-bis (3,4-dicarboxyphenyl)propane dianhydride, bis (3,4-dicarboxyphenyl) ether dianhydride,

Claim 12

2-bis(2,3-carboxyphenyl)propane dianhydride, 1,1-bis(2,3-dicarboxyphenyl)ethane dianhydride, 1,1-bis(3,4-dicarboxylphenyl)ethane dianhydride, and the like, and said diamine is selected from the group consisting of: meta-phenylene diamine, para-phenylenediamine, 4,4'-diamino-diphenyl propane, 4,4'-diamino-diphenyl methane, benzidine, 4,4'diamino-diphenyl sulfide, 4,4'-diamino-diphenyl sulfone, 3,3'-diamino-diphenyl sulfone, 4,4'-diamino-diphenyl ether, 2,6-diamino-pyridine, bis-(4-amino-phenyl) diethyl silane, bis-(4-amino-phenyl) phosphine oxide, bis-(4-amino-phenyl-N-methylamine, 1,5-diamino naphthalene, 3,3'-dimethyl-4,4'-diamino-biphenyl, 3,3'-dimethoxy benzidine, m-xylylene diamine, p-xylyene diamine, 1,3-bis-delta-amino-butyltetramethyl disiloxane, and 1,3-bis-gamma-aminopropyltetraphenyl disiloxane.

Claim 13

2-bis(2,3-carboxyphenyl)propane dianhydride, 1,1-bis(2,3-dicarboxyphenyl)ethane dianhydride, 1,1-bis(3,4-dicarboxylphenyl)ethane dianhydride, and the like, and said diamine is selected from the group consisting of: meta-phenylene diamine, para-phenylenediamine, 4,4'-diamino-diphenyl propane, 4,4'-diamino-diphenyl methane, benzidine, 4,4'diamino-diphenyl sulfide, 4,4'-diamino-diphenyl sulfone, 3,3'-diamino-diphenyl sulfone, 4,4'-diamino-diphenyl ether, 2,6-diamino-pyridine, bis-(4-amino-phenyl) diethyl silane, bis-(4-amino-phenyl) phosphine oxide, bis-(4-amino-phenyl-N-methylamine, 1,5-diamino naphthalene, 3,3'-dimethyl-4,4'-diamino-biphenyl, 3,3'-dimethoxy benzidine, m-xylylene diamine, p-xylyene diamine, 1,3-bis-delta-amino-butyltetramethyl disiloxane, and 1,3-bis-gamma-aminopropyltetraphenyl disiloxane.

Claim 14

The coating medium defined in claim 7 wherein: said diamine is selected from the group consisting of 4,4'-diaminodiphenyl methane, 4,4'-diaminodiphenyl ether, and 1,3-diamino benzene, and said dianhydride is selected from the group consisting of 3,3',4,4'-benzophenonetetracarboxylic dianhydride and 4,4'-(2-acetoxy-1,3-glyceryl) bis-anhydro trimellitate.

Claim 15

A heat curable coating material as defined in claim 1 wherein said aromatic diamine is selected from the group consisting of diamine having the general formula: H.sub.2 N--R'-NH.sub.2 wherein R' is a divalent radical selected from the group consisting of ##STR12## wherein R'" and R"" are an alkyl or an aryl group having 1 to 6 carbon atoms, n is an integer of from 1 to 4 and m has a value of 0, 1 or more and ##STR13## wherein R" is selected from the group consisting of an alkylene chain having 1-3 carbon atoms, ##STR14## wherein R'" and R"" are as above-defined and x is an integer of at least 0; and said aromatic dianhydride is selected from the group consisting of dianhydrides having the general formula: ##STR15## where R is a tetravalent radical containing two benzene rings joined by a non-aromatic non-cyclic group, each pair of carboxyl groups being attached to different adjacent carbon atoms of a single separate ring.

Claim 16

A heat curable coating material as defined in claim 1 wherein said aromatic diamine is selected from the group consisting of 4,4'-diaminodiphenyl ether, and 1,3-diamino benzene and mixtures thereof, and said aromatic dianhydride is selected from the group consisting of 3,3', 4,4'-benzophenonetetracarboxylic dianhydride and 4,4'-(2-acetoxy-1,3-glyceryl)bis-anhydro trimellitate and mixtures thereof.

Claim 17

The heat curable coating medium as defined in claim 1 wherein said aromatic diamide diacid diamine reaction product is ##STR16##

Claim 18

The heat curable coating medium as defined in claim 1 wherein said aromatic diamide diacid diamine reaction product is ##STR17##