US4101482A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Sealant based on mixture of unsaturated and hydrogenated block copolymers
Assignee: Phillips Petroleum Co
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Filing: 1976-10-04
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Granted: 1978-07-18
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Expires: 1996-10-04
Abstract
Abstract A mixture of an unsaturated block copolymer and a hydrogenated thermoplastic elastomer in combination with a modifying resin and a filler provides a sealant formulation having good flexibility, low tack, and low melt viscosity without a sacrifice in other properties.
Inventors
- 👤 Richard C. Doss
- 👤 Edward L. Walton
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 00:57
CPC Classifications
C; C09; C09K; C09K3/00; C09K3/10; C08; C08K; C08K3/00; C08K3/18; C08K3/24; C08K3/26; C08K3/34; C08K3/36; C08L; C08L23/00; C08L23/02; C08L23/16; C08L23/18; C08L25/00; C08L25/02; C08L25/16; C08L53/00; C08L53/02; C08L61/00; C08L61/04; C08L93/00; C08L93/04; C09J; C09J153/00; C09J153/02; C09J153/025; C08L2666/00; C08L2666/02; C08L2666/54; C09K2200/00; C09K2200/02; C09K2200/0217; C09K2200/023; C09K2200/0239; C09K2200/0243; C09K2200/0247; C09K2200/0252; C09K2200/0256; C09K2200/0265; C09K2200/06; C09K2200/0615; C09K2200/0642
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
138 words
A sealant composition comprising: 5-50 parts by weight of an unsaturated block copolymer of a conjugated diene and a monovinyl-substituted aromatic compound; 50-95 parts by weight of a teleblock copolymer of a formula selected from ABA and (AB) n Y wherein A represents a block of a polymerized monovinyl-substituted aromatic component, B represents a block of a polymerized conjugated diene before hydrogenation, said teleblock copolymer being hydrogenated to the extent that only 5 percent or less of the original olefinic unsaturation remains, and 5 percent or less of the monovinyl-substituted aromatic component unsaturation has been removed, Y represents a residue of a polyfunctional coupling agent or a polyfunctional initiator, and n is an integer having a value of from 2 to 4; 1- 300parts by weight of a modifying resin; and 25-250 parts by weight of a filler.
Claim 2
Dependent Claim
138 words
A sealant composition comprising: 5-50 parts by weight of an unsaturated block copolymer of a conjugated diene and a monovinyl-substituted aromatic compound; 50-95 parts by weight of a teleblock copolymer of a formula selected from ABA and (AB) n Y wherein A represents a block of a polymerized monovinyl-substituted aromatic component, B represents a block of a polymerized conjugated diene before hydrogenation, said teleblock copolymer being hydrogenated to the extent that only 5 percent or less of the original olefinic unsaturation remains, and 5 percent or less of the monovinyl-substituted aromatic component unsaturation has been removed, Y represents a residue of a polyfunctional coupling agent or a polyfunctional initiator, and n is an integer having a value of from 2 to 4; 1- 300parts by weight of a modifying resin; and 25-250 parts by weight of a filler.
Claim 3
Dependent Claim
15 words
A composition according to claim 1 wherein said unsaturated block copolymer is a thermoplastic elastomer.
Claim 4
Dependent Claim
31 words
A composition according to claim 2 wherein said unsaturated and said hydrogenated teleblock copolymers each have a weight ratio of monovinyl-substituted aromatic compound/conjugated diene within the range of 40/60 to 15/85.
Claim 5
Dependent Claim
49 words
A composition according to claim 3 wherein said monovinyl-substituted aromatic compound of said unsaturated block copolymer and said monovinyl-substituted aromatic compound of said hydrogenated teleblock copolymer is styrene and said conjugated diene compound of said unsaturated block copolymer and said hydrogenated teleblock copolymer is selected from 1,3-butadiene and isoprene.
Claim 6
Dependent Claim
24 words
A composition according to claim 1 wherein said hydrogenated teleblock copolymer has an unsaturation of less than 2 percent of the original olefinic unsaturation.
Claim 7
Dependent Claim
81 words
A composition according to claim 3 wherein said unsaturated block copolymer is present in an amount within the range of 25 to 40 parts by weight, said hydrogenated teleblock copolymer is present in an amount within the range of 60 to 75 parts by weight, said modifying resin is present in an amount within the range of 25 to 150 parts by weight, and said filler is present in an amount within the range of 50 to 200 parts by weight.
Claim 8
Dependent Claim
57 words
A composition according to claim 6 wherein said modifying resin is selected from the group consisting of modified rosin and rosin esters, esters of polymerized rosin, polyterpene resins, terpene-phenolic resins, coumarone-indene resins, diolefin-olefin resins, phenol-aldehyde resins, and alpha-methyl styrene copolymers, and said filler is selected from calcium carbonate, aluminum silicate, clay, talc, kaolin, barytes, mica, and silica.
Claim 9
Dependent Claim
17 words
A composition according to claim 4 comprising in addition a solvent to give a solvent-type sealant formulation.
Claim 10
Dependent Claim
26 words
A composition according to claim 8 wherein said modifying resin is a vinyl toluene/alpha-methyl styrene copolymer, said filler is calcium carbonate, and said solvent is toluene.
Claim 11
Dependent Claim
27 words
A composition according to claim 1 comprising in addition 25 to 250 parts by weight per 100 parts by weight of total block copolymers of a solvent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-17 | 1982-01-16 | 1982-07-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-17 | 1986-01-16 | 1986-07-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-17 | 1990-01-16 | 1990-07-18 | $7700.00 | Window Closed / Lapsed |