Process for hydrogenation of hydrocarbon tars

Claim 2

A process for hydrogenation of hydrocarbon tars of high asphaltene content which comprises: (a) forming a fluid solution of a hydrocarbon tar having an asphaltene content at least about 50% by weight in an aromatic hydrocarbon solvent for the hydrocarbon tar, said aromatic hydrocarbon solvent having a boiling point of from about 300° to about 750° F and formed as a product during the hydrogenation of the hydrocarbon tar to a hydrogen content of from about 1.2 to about 1.5 atoms of hydrogen per atom of carbon; (b) hydrogenating the tars while maintaining a substantial portion of the solution in the liquid state in the presence of a hydrogenation catalyst and externally supplied hydrogen in an amount of at least about 3 times the amount of hydrogen consumed during hydrogenation at a temperature above about 500° F and a pressure from about 1500 to about 5000 psig for a time sufficient to react hydrogen with the tars and reduce the molecular weight of the tar constituents to form additional aromatic hydrocarbon solvent for the tars; and (c) recovering at least a portion of the aromatic hydrocarbon solvent formed during the hydrogenation from the effluent of the hydrogenation zone and using the recovered aromatic hydrocarbon solvent in preparing the solution of hydrocarbon tar for feed to the hydrogenation zone.

Claim 3

A process as claimed in claim 1 in which the hydrocarbon solvent is recovered from the effluent of the hydrogenation zone by flash vaporization.

Claim 4

A process as claimed in claim 1 in which the hydrogenation temperature is from about 500° F to the critical temperature of the hydrocarbon solvent.

Claim 5

A process as claimed in claim 1 in which the hydrogenation temperature is from about 500° to about 800° F.

Claim 6

A process as claimed in claim 1 in which the hydrogenation pressure is from about 2000 to about 3500 psig.

Claim 7

A process as claimed in claim 1 in which the amount of hydrogen consumed in the hydrogenation zone is sufficient to provide an effluent having an atomic hydrogen to carbon ratio of from about 1.2 to about 1.5.

Claim 8

A process as claimed in claim 1 in which the hydrogen fed to the hydrogenation zone is from about 3 to about 10 times the amount of hydrogen consumed in the hydrogenation zone.

Claim 9

A process as claimed in claim 7 in which the amount of hydrogen consumed in the hydrogenation zone is sufficient to provide an effluent having an atomic hydrogen to carbon ratio of from about 1.2 to about 1.5.

Claim 10

A process as claimed in claim 1 in which the weight ratio of hydrocarbon tar to hydrocarbon solvent is from about 1 to 4 to about 4 to 1.

Claim 11

A process for hydrogenation of hydrocarbon tars resulting from the coal pyrolysis which comprises: (a) generating a hydrocarbon tar containing from about 50 to about 75 weight percent asphaltenes from pyrolysis of coal; (b) forming a liquid solution as a hydrocarbon tar in an aromatic hydrocarbon solvent for the tar, said aromatic hydrocarbon solvent having a boiling point of from about 300° to about 750° F and being formed as a product during the hydrogenation of the hydrocarbon tar to a hydrogen content of from about 1.2 to about 1.5 atoms of hydrogen per atom of carbon; (c) hydrogenating the tars while maintaining a substantial portion of the solution in the liquid state in the presence of a hydrogenation catalyst and externally supplied hydrogen in an amount of at least about 3 times the amount of hydrogen consumed during hydrogenation, at a temperature from about 500° F to the critical temperature of the hydrocarbon solvent and at a pressure from about 1500 to about 5000 psig for a time sufficient to react hydrogen with the tar and reduce the molecular weight of the tar constituents to form additional aromatic hydrocarbon solvent for the tar; and (d) recovering at least a portion of the aromatic hydrocarbon solvent formed during the hydrogenation from the hydrogenation zone for direct use in preparing the solution of hydrocarbon tar for feed to the hydrogenation zone.

Claim 12

A process for hydrogenation of hydrocarbon tars resulting from the coal pyrolysis which comprises: (a) generating a hydrocarbon tar containing from about 50 to about 75 weight percent asphaltenes from pyrolysis of coal; (b) forming a liquid solution as a hydrocarbon tar in an aromatic hydrocarbon solvent for the tar, said aromatic hydrocarbon solvent having a boiling point of from about 300° to about 750° F and being formed as a product during the hydrogenation of the hydrocarbon tar to a hydrogen content of from about 1.2 to about 1.5 atoms of hydrogen per atom of carbon; (c) hydrogenating the tars while maintaining a substantial portion of the solution in the liquid state in the presence of a hydrogenation catalyst and externally supplied hydrogen in an amount of at least about 3 times the amount of hydrogen consumed during hydrogenation, at a temperature from about 500° F to the critical temperature of the hydrocarbon solvent and at a pressure from about 1500 to about 5000 psig for a time sufficient to react hydrogen with the tar and reduce the molecular weight of the tar constituents to form additional aromatic hydrocarbon solvent for the tar; and (d) recovering at least a portion of the aromatic hydrocarbon solvent formed during the hydrogenation from the hydrogenation zone for direct use in preparing the solution of hydrocarbon tar for feed to the hydrogenation zone.

Claim 13

A process as claimed in claim 10 in which the hydrocarbon solvent is recovered from the effluent of the hydrogenation zone by flash vaporization.

Claim 14

A process as claimed in claim 10 in which the hydrogenation temperature is from about 500° F to the critical temperature of the hydrocarbon solvent.

Claim 15

A process as claimed in claim 10 in which the hydrogenation temperature is from about 500° to about 800° F.

Claim 16

A process as claimed in claim 10 in which the hydrogenation pressure is from about 2000 to about 3500 psig.

Claim 17

A process as claimed in claim 10 in which the amount of hydrogen consumed in the hydrogenation zone is sufficient to provide an effluent having an atomic hydrogen to carbon ratio of from about 1.2 to about 1.5.

Claim 18

A process as claimed in claim 10 in which the hydrogen fed to the hydrogenation zone is from about 3 to about 10 times the amount of hydrogen consumed in the hydrogenation zone.

Claim 19

A process as claimed in claim 16 in which the amount of hydrogen consumed in the hydrogenation zone is sufficient to provide an effluent having an atomic hydrogen to carbon ratio of from about 1.2 to about 1.5.

Claim 20

A process as claimed in claim 10 in which the weight ratio of hydrocarbon tar to hydrocarbon solvent is from about 1 to 4 to about 4 to 1.