Patent US741966A successfully refreshed from Google Patents.
Patent US4411809A successfully refreshed from Google Patents.
US4100182A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of making adjuvant for elastomeric composition
Assignee: UNIROYAL HOLDING Inc WORLD HEADQUARTERS MIDDLEBURY CONNECTICUT 06749 A CORP OF NEW JERSEY
•
Filing: 1976-05-11
•
Granted: 1978-07-11
•
Expires: 1996-05-11
Abstract
Abstract An adjuvant for an elastomeric composition is made by mixing methacrylic acid with a suspension of zinc oxide in a liquid medium (such as water or alcohol) in the proportions required to form basic zinc methacrylate. Removal of the liquid from the reaction product and blending of the finely divided reaction product with an elastomer such as cis-polybutadiene yields a compositon which, when cured (for example with an organic peroxide), is hard yet resilient. Molding of the composition in the form of a golf ball produces a durable solid golf ball which has in large measure the play characteristics of a wound golf ball, and substantially retains such characteristics after extended play.
Inventors
- 👤 Frank Stephen Martin
- 👤 Terence Melvin
- 👤 Joseph Kirby Pieroni
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 17:09
CPC Classifications
A; A63; A63B; A63B37/00; A63B37/0003; A63B45/00; C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
159 words
A method of making an adjuvant for an elastomer comprising slurrying zinc oxide in a volatile liquid medium selected from the group consisting of water and an alkanol, the concentration of zinc oxide in the slurry being from 31 to 65 percent by weight, thereafter rapidly adding to the slurry, while agitating the slurry, methacrylic acid in an amount such as to provide a zinc oxide-methacrylate acid molar ratio of from 0.8:1 to 2:1 whereby an exothermic reaction between the zinc oxide and the methacrylic acid takes place, the said liquid medium serving to dissipate the heat liberated by the exothermic reaction, subsequently removing the volatile liquid medium from the resulting reaction product to provide a dried product, and grinding the resulting dried product at least to a fineness sufficient to pass a 200 mesh sieve, the resulting product being of white color and having zinc oxide and methacrylic acid combined in the proportions required by basic zinc methacrylate.
Claim 2
Independent Claim
159 words
A method of making an adjuvant for an elastomer comprising slurrying zinc oxide in a volatile liquid medium selected from the group consisting of water and an alkanol, the concentration of zinc oxide in the slurry being from 31 to 65 percent by weight, thereafter rapidly adding to the slurry, while agitating the slurry, methacrylic acid in an amount such as to provide a zinc oxide-methacrylate acid molar ratio of from 0.8:1 to 2:1 whereby an exothermic reaction between the zinc oxide and the methacrylic acid takes place, the said liquid medium serving to dissipate the heat liberated by the exothermic reaction, subsequently removing the volatile liquid medium from the resulting reaction product to provide a dried product, and grinding the resulting dried product at least to a fineness sufficient to pass a 200 mesh sieve, the resulting product being of white color and having zinc oxide and methacrylic acid combined in the proportions required by basic zinc methacrylate.
Claim 3
Dependent Claim
14 words
A method as in claim 1 in which the said liquid medium is water.
Claim 4
Dependent Claim
15 words
A method as in claim 1 in which the said liquid medium is an alkanol.
Claim 5
Dependent Claim
13 words
A method as in claim 3 in which the said alkanol is methanol.
Claim 6
Dependent Claim
29 words
A method as in claim 1 in which a small amount of silica is present as a dispersing aid in the dispersion of zinc oxide in the liquid medium.
Claim 7
Dependent Claim
18 words
A method as in claim 1 in which the materials are pre-cooled to serve as a heat sink.
Claim 8
Dependent Claim
56 words
A method as in claim 1 in which the said liquid medium is water, the concentration of zinc oxide in the said slurry is from 40 to 50 percent by weight, the zinc oxide and methacrylic acid are employed in approximately equimolar proportions, and the product is ground at least to a fineness of 325 mesh.
Claim 9
Dependent Claim
8 words
The product of the method of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-10 | 1982-01-09 | 1982-07-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-10 | 1986-01-09 | 1986-07-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-10 | 1990-01-09 | 1990-07-11 | $7700.00 | Window Closed / Lapsed |