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US4100136A Expired / Lapsed US ⏱️ 0.0 years remaining

Fluorocarbon siloxane compositions

Assignee: Dow Silicones Corp
•
Filing: 1977-06-03
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Granted: 1978-07-11
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Expires: 1997-06-03
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Abstract

Abstract Fluorocarbon siloxanes of the formula <IMAGE> ARE DISCLOSED. Their use as reversion resistant curing agents in curable compositions comprising reversion resistant siloxanes of the formula <IMAGE> are also disclosed.

Inventors

  • 👤 Philip L. Carter
  • 👤 Yung K. Kim
  • 👤 Michael O. Riley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 17:05
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/48; C08G77/485; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/0896; C07F7/12; C08L; C08L83/00; C08L83/14

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 230 words
A curable composition consisting essentially of a homogeneous mixture of (A) a siloxane polymer or copolymer of the formula ##STR20## (B) a curing agent of the formula ##STR21## (C) an effective amount of a platinum-containing catalyst; where, in (A) and (B), each R and R' is independently methyl, phenyl, or 3,3,3-trifluoropropyl, each R f is independently a perfluoroalkylene radical of 2 to 10 carbon atoms, a perfluorocycloalkylene radical, or a perfluoroalkylene radical of 2 to 10 carbon atoms or a perfluorocycloalkylene radical containing one or more --C--O--C-- linkages; p has a value of 0 to 2q inclusive, so that, when p = 0, siloxane (A) is a siloxane polymer, but when p has a value of from greater than 0 to q, inclusive, siloxane (A) can be either a random copolymer or an alternating copolymer and when p has a value of from greater than q to 2q, inclusive, siloxane (A) is only an alternating copolymer having no more than 2 adjacent CH 3 (CF 3 CH 2 CH 2 )SiO units, q has an average value of at least 5, each n is independently 1, 2, or 3, there being an average of greater than 2.0 silicon-bonded hydrogen atoms per molecule of (B) and the amount of (B) being such that there is, in said curable composition, from 0.5 to 3.0 silicon-bonded hydrogen atoms for every silicon-bonded vinyl radical.
Claim 2
Dependent Claim 230 words
A curable composition consisting essentially of a homogeneous mixture of (A) a siloxane polymer or copolymer of the formula ##STR20## (B) a curing agent of the formula ##STR21## (C) an effective amount of a platinum-containing catalyst; where, in (A) and (B), each R and R' is independently methyl, phenyl, or 3,3,3-trifluoropropyl, each R f is independently a perfluoroalkylene radical of 2 to 10 carbon atoms, a perfluorocycloalkylene radical, or a perfluoroalkylene radical of 2 to 10 carbon atoms or a perfluorocycloalkylene radical containing one or more --C--O--C-- linkages; p has a value of 0 to 2q inclusive, so that, when p = 0, siloxane (A) is a siloxane polymer, but when p has a value of from greater than 0 to q, inclusive, siloxane (A) can be either a random copolymer or an alternating copolymer and when p has a value of from greater than q to 2q, inclusive, siloxane (A) is only an alternating copolymer having no more than 2 adjacent CH 3 (CF 3 CH 2 CH 2 )SiO units, q has an average value of at least 5, each n is independently 1, 2, or 3, there being an average of greater than 2.0 silicon-bonded hydrogen atoms per molecule of (B) and the amount of (B) being such that there is, in said curable composition, from 0.5 to 3.0 silicon-bonded hydrogen atoms for every silicon-bonded vinyl radical.
Claim 3
Dependent Claim 11 words
The curable composition of claim 1 which further contains a filler.
Claim 4
Dependent Claim 15 words
The curable composition of claim 2 which further contains an inhibitor for the platinum-containing catalyst.
Claim 5
Dependent Claim 10 words
The curable composition of claim 3 wherein R' is methyl.
Claim 6
Dependent Claim 16 words
The curable composition of claim 4 wherein R f contains from 2 to 6 carbon atoms.
Claim 7
Dependent Claim 15 words
The curable composition of claim 5 wherein R f is --CF 2 CF 2 --.
Claim 8
Dependent Claim 23 words
The curable composition of claim 6 wherein (B) consists essentially of ##STR22## and from 0 to less than 100 mole percent of ##STR23##
Claim 9
Dependent Claim 29 words
The curable composition of claim 6 wherein (B) consists essentially of a mixture of from 40 to 60 mole percent ##STR24## and from 40 to 60 mole percent ##STR25##
Claim 10
Dependent Claim 26 words
The composition of claim 7 wherein the siloxane (A) is a siloxane polymer of the formula ##STR26## wherein q has a value of at least 5.
Claim 11
Dependent Claim 39 words
The composition of claim 7 wherein the siloxane (A) is a random siloxane of the formula ##STR27## wherein q has a value of at least 5, and p has a value of from greater than zero to q, inclusive.
Claim 12
Dependent Claim 41 words
The composition of claim 7 wherein the siloxane (A) is an alternating siloxane copolymer of the formula ##STR28## wherein a has an average value of from greater than zero to 2 inclusive, and q has a value of at least 5.
Claim 13
Dependent Claim 12 words
The cured composition obtained by heating the curable composition of claim 1.
Claim 14
Dependent Claim 12 words
The cured composition obtained by heating the curable composition of claim 1.
Claim 15
Dependent Claim 12 words
The cured composition obtained by heating the curable composition of claim 8.

References Cited (Backward Citations)

US3344160A Cited
US3542830A Cited
US3647740A Cited
US3989667A Cited
US3975362A Cited
US4057566A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-10 1982-01-09 1982-07-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-10 1986-01-09 1986-07-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-10 1990-01-09 1990-07-11 $7700.00 Window Closed / Lapsed

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